data_global
_amcsd_formula_title 'Ba Cu O5 Tm2'
loop_
_publ_author_name
'Salinas-Sanchez A'
'Garcia-Munoz J'
'Rodriguez-Carvajal J'
'Saez-Puche R'
'Martinez J'
_journal_name_full 'Journal of Solid State Chemistry'
_journal_volume 100 
_journal_year 1992
_journal_page_first 201
_journal_page_last 211
_publ_section_title
;
 Structural characterization of R2BaCuO5
 (R=Y,Lu,Yb,Tm,Er,Ho,Dy,Gd,Eu and Sm) oxides by X-ray and neutron diffraction
 _cod_database_code 1006055
;
_database_code_amcsd 0013746
_chemical_formula_sum 'Ba Tm2 Cu O5'
_cell_length_a 12.1011
_cell_length_b 5.6275
_cell_length_c 7.0793
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 90
_cell_volume 482.093
_exptl_crystal_density_diffrn      8.525
_symmetry_space_group_name_H-M 'P n m a'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  'x,1/2-y,z'
  '-x,1/2+y,-z'
  '1/2-x,1/2+y,1/2+z'
  '1/2+x,1/2-y,1/2-z'
  '1/2+x,y,1/2-z'
  '1/2-x,-y,1/2+z'
  '-x,-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
Ba1   0.90450   0.25000   0.92980
Tm1   0.28850   0.25000   0.11770
Tm2   0.07380   0.25000   0.39690
Cu1   0.65970   0.25000   0.71200
O1   0.43330  -0.00710   0.16440
O2   0.22760   0.50140   0.35790
O3   0.10100   0.25000   0.08300