As Cr3 Cs2 H O13 Goreaud M Journal of Solid State Chemistry 102 (1993) 236-241 Structures comparees de (NH4)2AsCr3O12(OH) et Cs2AsCr3O12(OH): tendance a la formation d'une charpente tridimensionelle par association d'heteropolyanions _cod_database_code 1001560 _database_code_amcsd 0013762 CELL PARAMETERS: 10.5440 8.0980 15.3620 90.000 94.006 90.000 SPACE GROUP: P2_1/c X-RAY WAVELENGTH: 1.541838 Cell Volume: 1308.484 Density (g/cm3): 3.577 MAX. ABS. INTENSITY / VOLUME**2: 17.17606953 RIR: 1.564 RIR based on corundum from Acta Crystallographica A38 (1982) 733-739 2-THETA INTENSITY D-SPACING H K L Multiplicity 8.41 5.48 10.5182 1 0 0 2 11.55 8.79 7.6622 0 0 2 2 12.36 2.16 7.1598 0 1 1 4 13.82 2.10 6.4100 -1 0 2 2 14.74 8.06 6.0107 -1 1 1 4 15.20 1.85 5.8308 1 1 1 4 16.86 2.10 5.2591 2 0 0 2 17.65 22.54 5.0260 -1 1 2 4 18.41 1.85 4.8194 1 1 2 4 19.80 10.81 4.4847 -2 0 2 2 21.15 48.16 4.2012 2 0 2 2 21.29 12.64 4.1740 2 1 1 4 21.77 16.63 4.0821 -1 1 3 4 21.95 14.44 4.0490 0 2 0 2 22.66 5.77 3.9232 -2 1 2 4 22.72 35.05 3.9147 0 2 1 4 23.22 29.78 3.8311 0 0 4 2 23.86 3.82 3.7292 2 1 2 4 24.16 6.84 3.6835 -1 0 4 2 24.40 60.08 3.6476 1 2 1 4 24.87 7.81 3.5799 0 2 2 4 25.29 67.56 3.5215 1 0 4 2 25.40 90.79 3.5061 3 0 0 2 25.90 1.41 3.4395 -2 1 3 4 26.59 18.09 3.3529 -1 1 4 4 27.22 2.37 3.2759 -3 0 2 2 27.48 8.42 3.2456 2 1 3 4 27.62 10.59 3.2294 1 1 4 4 27.73 7.17 3.2175 3 1 0 4 27.81 4.81 3.2083 2 2 0 4 27.84 68.08 3.2050 -2 0 4 2 27.97 2.88 3.1902 -3 1 1 4 28.12 100.00 3.1731 0 2 3 4 28.17 82.33 3.1674 -2 2 1 4 28.67 12.05 3.1137 2 2 1 4 28.73 4.09 3.1071 3 0 2 2 29.04 1.96 3.0750 -1 2 3 4 29.41 5.38 3.0369 -3 1 2 4 29.73 3.90 3.0053 -2 2 2 4 30.67 8.07 2.9154 2 2 2 4 30.82 4.34 2.9009 3 1 2 4 31.82 4.33 2.8119 2 1 4 4 32.17 2.05 2.7828 0 2 4 4 32.31 6.29 2.7706 -2 2 3 4 32.92 1.92 2.7209 1 1 5 4 33.42 15.91 2.6814 -3 0 4 2 33.61 7.92 2.6662 2 2 3 4 33.72 1.42 2.6584 0 3 1 4 33.73 4.25 2.6571 1 2 4 4 33.82 2.81 2.6505 3 2 0 4 34.02 31.10 2.6352 -3 2 1 4 34.30 8.48 2.6146 1 3 0 4 34.70 8.68 2.5848 -1 3 1 4 34.91 2.74 2.5700 1 3 1 4 35.14 5.42 2.5541 0 0 6 2 35.26 1.30 2.5455 -3 1 4 4 35.30 5.90 2.5423 -4 0 2 2 35.91 4.06 2.5010 4 1 0 4 35.91 13.84 2.5009 3 0 4 2 36.50 15.81 2.4615 1 3 2 4 36.67 9.41 2.4505 2 1 5 4 36.78 1.95 2.4437 0 2 5 4 36.79 5.26 2.4431 1 0 6 2 36.79 9.21 2.4427 4 1 1 4 36.90 1.60 2.4358 0 1 6 4 37.06 5.66 2.4256 -4 1 2 4 37.31 1.82 2.4101 -1 2 5 4 37.34 9.90 2.4085 -1 1 6 4 37.39 12.26 2.4051 -3 2 3 4 37.64 1.18 2.3896 3 1 4 4 37.73 1.27 2.3842 -2 3 1 4 38.08 8.89 2.3633 -2 0 6 2 38.12 3.07 2.3610 2 3 1 4 38.27 14.57 2.3516 1 2 5 4 38.40 13.99 2.3440 -1 3 3 4 38.49 2.02 2.3390 1 1 6 4 38.60 1.01 2.3323 4 1 2 4 39.03 4.54 2.3076 -4 1 3 4 39.11 34.88 2.3034 3 2 3 4 39.28 1.27 2.2938 -3 1 5 4 39.69 2.41 2.2710 2 3 2 4 39.80 27.60 2.2649 -2 2 5 4 40.22 4.90 2.2423 -4 0 4 2 40.32 1.00 2.2369 2 0 6 2 40.90 2.25 2.2066 0 3 4 4 40.92 1.26 2.2053 4 2 0 4 41.80 5.60 2.1610 -4 1 4 4 41.82 2.71 2.1602 0 2 6 4 41.96 1.56 2.1531 -4 2 2 4 42.08 3.13 2.1471 2 3 3 4 42.42 1.39 2.1308 -3 3 1 4 42.79 1.88 2.1133 0 1 7 4 43.00 1.42 2.1036 5 0 0 2 43.06 2.46 2.1006 4 0 4 2 43.09 3.58 2.0995 -1 1 7 4 43.36 1.57 2.0870 4 2 2 4 43.44 1.69 2.0832 -3 3 2 4 43.75 1.00 2.0693 -4 2 3 4 43.82 2.07 2.0658 -5 0 2 2 43.97 1.64 2.0593 -3 2 5 4 44.46 1.08 2.0377 3 3 2 4 44.56 5.14 2.0333 4 1 4 4 44.77 5.40 2.0245 0 4 0 2 45.20 1.62 2.0062 2 3 4 4 45.30 1.21 2.0017 -5 1 2 4 45.33 1.82 2.0007 5 1 1 4 45.37 6.88 1.9990 3 0 6 2 45.50 6.86 1.9933 5 0 2 2 46.39 1.53 1.9573 0 4 2 4 47.20 10.39 1.9258 0 2 7 4 47.40 1.17 1.9181 1 4 2 4 47.43 1.02 1.9167 2 1 7 4 47.47 1.91 1.9152 -1 2 7 4 47.66 1.71 1.9082 -1 0 8 2 47.81 2.49 1.9024 -3 3 4 4 47.85 2.03 1.9008 -5 0 4 2 48.16 1.43 1.8893 2 4 0 4 48.32 2.83 1.8836 4 3 0 4 48.58 4.82 1.8740 1 2 7 4 48.78 11.44 1.8670 -5 2 1 4 48.86 5.27 1.8641 0 1 8 4 48.92 2.31 1.8618 1 0 8 2 49.27 1.07 1.8494 -4 1 6 4 49.39 3.05 1.8453 -2 2 7 4 49.39 9.21 1.8452 -2 4 2 4 49.45 1.55 1.8431 -1 3 6 4 49.48 2.20 1.8420 -4 2 5 4 49.49 5.16 1.8417 -2 0 8 2 49.56 8.19 1.8394 5 2 1 4 50.01 1.52 1.8238 2 4 2 4 50.47 2.07 1.8083 4 3 2 4 50.82 1.88 1.7967 -4 3 3 4 50.95 3.33 1.7925 3 2 6 4 50.96 1.10 1.7919 5 0 4 2 51.02 13.20 1.7900 0 4 4 4 51.04 4.95 1.7895 -5 2 3 4 51.07 2.04 1.7884 5 2 2 4 51.39 1.45 1.7781 -2 3 6 4 52.11 5.33 1.7551 1 4 4 4 52.17 11.81 1.7532 3 4 0 4 52.18 1.50 1.7530 6 0 0 2 52.52 1.06 1.7423 4 2 5 4 52.81 3.23 1.7334 -3 2 7 4 52.91 1.50 1.7304 4 1 6 4 53.18 3.84 1.7224 2 3 6 4 53.24 1.98 1.7206 2 1 8 4 53.28 2.17 1.7193 5 2 3 4 53.40 1.21 1.7157 -6 1 1 4 53.48 1.47 1.7134 6 1 0 4 53.54 4.57 1.7116 -2 4 4 4 53.79 1.84 1.7044 -4 1 7 4 53.92 1.11 1.7003 0 3 7 4 54.04 1.68 1.6969 -6 1 2 4 54.06 5.12 1.6962 3 4 2 4 54.13 3.02 1.6944 -3 1 8 4 54.17 1.72 1.6931 -1 3 7 4 54.23 1.04 1.6915 1 2 8 4 54.51 1.58 1.6835 6 0 2 2 54.54 3.94 1.6825 -5 0 6 2 54.70 1.38 1.6779 2 4 4 4 54.79 1.66 1.6753 -3 3 6 4 55.86 12.50 1.6458 3 2 7 4 56.07 8.95 1.6401 -5 2 5 4 56.15 1.28 1.6380 -6 0 4 2 57.00 4.02 1.6157 -3 4 4 4 57.19 1.86 1.6107 -6 2 1 4 57.56 4.04 1.6013 -4 2 7 4 57.58 5.48 1.6007 1 5 0 4 57.90 1.36 1.5928 2 3 7 4 58.67 6.46 1.5735 3 4 4 4 58.93 1.46 1.5672 -1 2 9 4 59.08 2.46 1.5636 1 5 2 4 59.08 1.22 1.5636 -3 3 7 4 59.56 1.72 1.5521 5 2 5 4 59.80 1.18 1.5465 -3 1 9 4 60.17 2.10 1.5380 1 2 9 4 60.19 2.09 1.5375 -2 4 6 4 60.41 1.11 1.5324 0 0 10 2 60.42 1.65 1.5321 -1 5 3 4 60.43 2.23 1.5318 -1 0 10 2 60.46 3.60 1.5313 -2 2 9 4 61.40 2.09 1.5101 4 2 7 4 61.54 7.19 1.5070 6 2 3 4 61.62 1.24 1.5051 -1 1 10 4 61.89 1.98 1.4993 4 0 8 2 62.23 1.49 1.4918 0 5 4 4 62.91 3.90 1.4774 7 1 0 4 63.34 3.44 1.4683 -5 0 8 2 63.53 1.50 1.4645 -4 3 7 4 63.86 2.11 1.4577 4 4 4 4 64.44 1.05 1.4460 -7 1 3 4 64.44 8.39 1.4459 -5 4 2 4 65.08 1.82 1.4333 -7 0 4 2 65.64 1.37 1.4224 3 4 6 4 65.66 5.05 1.4220 2 1 10 4 65.74 1.79 1.4204 5 4 2 4 66.80 4.15 1.4004 6 0 6 2 67.46 1.45 1.3883 6 2 5 4 67.50 1.27 1.3876 -4 2 9 4 67.57 2.24 1.3863 -3 5 4 4 67.60 1.36 1.3857 -5 4 4 4 67.63 1.40 1.3853 -4 4 6 4 67.84 1.54 1.3814 -7 2 3 4 67.98 1.33 1.3790 4 5 0 4 68.32 1.02 1.3730 0 1 11 4 68.46 10.57 1.3704 1 4 8 4 68.52 1.17 1.3695 3 0 10 2 68.71 2.34 1.3662 -4 0 10 2 68.93 4.93 1.3623 -2 4 8 4 69.98 1.02 1.3445 0 6 1 4 70.14 2.31 1.3418 5 4 4 4 71.14 3.39 1.3252 6 4 0 4 71.62 1.62 1.3176 -6 4 2 4 71.98 1.29 1.3118 2 5 6 4 72.02 1.52 1.3112 -8 0 2 2 72.43 3.42 1.3049 0 6 3 4 72.45 2.79 1.3045 -2 6 1 4 72.83 1.27 1.2987 -5 2 9 4 72.86 1.47 1.2982 -2 2 11 4 72.96 4.39 1.2966 1 2 11 4 73.11 1.27 1.2944 6 4 2 4 73.14 2.46 1.2940 -5 4 6 4 73.93 1.25 1.2820 -5 0 10 2 75.03 1.02 1.2659 -7 3 4 4 75.56 2.54 1.2584 6 2 7 4 75.64 1.17 1.2573 1 0 12 2 75.93 1.61 1.2531 -8 2 1 4 76.80 1.86 1.2411 5 4 6 4 76.90 2.57 1.2397 8 2 1 4 77.03 1.15 1.2380 0 3 11 4 77.35 1.90 1.2337 -8 2 3 4 78.17 1.14 1.2228 1 6 5 4 78.26 2.38 1.2216 -7 2 7 4 78.55 1.18 1.2177 8 0 4 2 78.70 4.12 1.2159 3 6 3 4 79.15 1.29 1.2101 -2 6 5 4 79.42 1.88 1.2066 7 4 0 4 79.56 2.25 1.2048 4 4 8 4 80.69 1.03 1.1908 -3 3 11 4 81.05 1.28 1.1865 5 1 10 4 84.29 1.57 1.1489 0 6 7 4 84.39 2.76 1.1478 4 2 11 4 85.47 1.38 1.1360 -5 6 1 4 85.63 2.53 1.1343 3 4 10 4 85.86 1.06 1.1318 8 2 5 4 86.06 1.06 1.1297 5 6 1 4 ================================================================================ XPOW Copyright 1993 Bob Downs, Ranjini Swaminathan and Kurt Bartelmehs For reference, see Downs et al. (1993) American Mineralogist 78, 1104-1107.