data_global
_amcsd_formula_title 'KV4P7O24'
loop_
_publ_author_name
'Benhamada L'
'Grandin A'
'Borel M'
'Leclaire A'
'Raveau B'
_journal_name_full 'Journal of Solid State Chemistry'
_journal_volume 104 
_journal_year 1993
_journal_page_first 193
_journal_page_last 201
_publ_section_title
;
 A vanadium(III) phosphate with V2O10 octahedral units: KV4P7O24
 _cod_database_code 1001564
;
_database_code_amcsd 0013776
_chemical_formula_sum 'V4 P7 K O24'
_cell_length_a 10.0846
_cell_length_b 10.2309
_cell_length_c 10.8283
_cell_angle_alpha 112.757
_cell_angle_beta 109.226
_cell_angle_gamma 104.675
_cell_volume 874.860
_exptl_crystal_density_diffrn      3.203
_symmetry_space_group_name_H-M 'P -1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '-x,-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
V1   0.75498   0.14970   0.25561
V2   0.37412   0.22301   0.88604
V3   0.07363   0.68772   0.07401
V4   0.42673   0.58143   0.41113
P1   0.38321   0.93742   0.11691
P2   0.50103   0.27387   0.24211
P3   0.24365   0.81280   0.43424
P4   0.30263   0.51073   0.05170
P5   0.99840   0.00662   0.22450
P6   0.06493   0.32096   0.26257
P7   0.27241   0.13098   0.52037
K1   0.86440   0.57356   0.32447
O1   0.96500   0.32230   0.34130
O2   0.55370  -0.04510   0.17390
O3   0.69060   0.10850   0.04730
O4   0.67070   0.30160   0.29720
O5   0.82750   0.18100   0.46060
O6   0.83300  -0.02110   0.19790
O7   0.26770   0.35300  -0.07900
O8   0.43230   0.26820   0.09490
O9   0.58680   0.36150  -0.04650
O10   0.27700   0.17810   0.67010
O11   0.11060   0.71260   0.27130
O12   0.29040   0.83870   0.15800
O13   0.00220   0.66500   0.87460
O14   0.86200   0.48850  -0.01020
O15   0.01540   0.87140   0.12770
O16   0.22990   0.44090   0.37450
O17   0.48980   0.39450   0.37260
O18   0.37490   0.76710   0.46230
O19   0.64000   0.73910   0.49340
O20   0.36820   0.52740   0.20670
O21   0.40200   0.10990   0.21800
O22   0.31770   0.99120   0.46710
O23   0.06680   0.14820   0.20400
O24   0.09220   0.06350   0.40020