data_global
_amcsd_formula_title 'Cd5V3P6O25'
loop_
_publ_author_name
'Crespoa P'
'Grandin A'
'Borel M'
'Leclaire A'
'Raveau B'
_journal_name_full 'Journal of Solid State Chemistry'
_journal_volume 105 
_journal_year 1993
_journal_page_first 307
_journal_page_last 312
_publ_section_title
;
 A new mixed-valent vanadium phosphate with a tunnel structure Cd5V3P6O25
 _cod_database_code 1001568
;
_database_code_amcsd 0013782
_chemical_formula_sum 'Cd5 V3 P6 O25'
_cell_length_a 16.861
_cell_length_b 4.710
_cell_length_c 24.160
_cell_angle_alpha 90
_cell_angle_beta 103.07
_cell_angle_gamma 90
_cell_volume 1868.970
_exptl_crystal_density_diffrn      4.623
_symmetry_space_group_name_H-M 'C 1 2/c 1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2+y,z'
  'x,-y,1/2+z'
  '1/2+x,1/2-y,1/2+z'
  '-x,y,1/2-z'
  '1/2-x,1/2+y,1/2-z'
  '-x,-y,-z'
  '1/2-x,1/2-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
Cd1   0.00000   0.00000   0.00000
Cd2   0.16719   0.47810   0.20952
Cd3   0.44023  -0.02370   0.11704
V1   0.00000  -0.06050   0.25000
V2   0.26883   0.49430   0.41304
P1   0.32368   0.51120   0.17458
P2   0.07178  -0.04500   0.14065
P3   0.15001   0.47240   0.00305
O1   0.00000   0.27700   0.25000
O2   0.06270   0.80300   0.19670
O3   0.09500   0.84700   0.31180
O4   0.16810   0.27100   0.36220
O5   0.36530   0.70500   0.46360
O6   0.28910   0.16180   0.45790
O7   0.34360   0.36000   0.36440
O8   0.24520   0.81390   0.35380
O9   0.18340   0.62420   0.45120
O10   0.30050   0.61200   0.23000
O11   0.06440   0.27500   0.14830
O12   0.00320   0.85900   0.09180
O13   0.06930   0.62500  -0.02210