Cd5V3P6O25 Crespoa P, Grandin A, Borel M, Leclaire A, Raveau B Journal of Solid State Chemistry 105 (1993) 307-312 A new mixed-valent vanadium phosphate with a tunnel structure Cd5V3P6O25 _cod_database_code 1001568 _database_code_amcsd 0013782 CELL PARAMETERS: 16.8610 4.7100 24.1600 90.000 103.070 90.000 SPACE GROUP: C2/c X-RAY WAVELENGTH: 1.541838 Cell Volume: 1868.970 Density (g/cm3): 4.622 MAX. ABS. INTENSITY / VOLUME**2: 28.41644134 RIR: 2.002 RIR based on corundum from Acta Crystallographica A38 (1982) 733-739 2-THETA INTENSITY D-SPACING H K L Multiplicity 7.51 5.44 11.7671 0 0 2 2 10.77 7.12 8.2121 2 0 0 2 11.66 7.71 7.5875 -2 0 2 2 14.48 7.51 6.1164 2 0 2 2 16.43 13.18 5.3951 -2 0 4 2 19.61 2.90 4.5275 1 1 0 4 20.46 2.58 4.3405 2 0 4 2 20.58 5.33 4.3167 -1 1 2 4 21.64 1.59 4.1061 4 0 0 2 22.67 2.85 3.9224 0 0 6 2 22.81 24.21 3.8988 -2 0 6 2 24.04 100.00 3.7014 -1 1 4 4 24.52 21.51 3.6299 4 0 2 2 24.94 24.03 3.5705 3 1 0 4 24.97 13.74 3.5659 -3 1 2 4 25.56 10.13 3.4847 1 1 4 4 25.78 1.82 3.4553 3 1 1 4 27.15 13.20 3.2847 3 1 2 4 27.24 42.67 3.2741 -3 1 4 4 27.32 4.98 3.2639 2 0 6 2 27.67 6.23 3.2236 -4 0 6 2 28.96 1.80 3.0828 3 1 3 4 29.18 11.16 3.0605 -1 1 6 4 29.86 11.40 2.9926 -2 0 8 2 30.38 9.92 2.9418 0 0 8 2 31.08 42.23 2.8771 1 1 6 4 31.16 48.31 2.8704 3 1 4 4 31.29 1.87 2.8586 -3 1 6 4 31.85 4.44 2.8101 -6 0 2 2 32.69 56.59 2.7392 -5 1 2 4 32.71 4.96 2.7374 6 0 0 2 32.75 1.50 2.7348 -5 1 1 4 32.82 20.97 2.7291 -6 0 4 2 33.21 21.27 2.6976 -4 0 8 2 33.25 4.89 2.6943 5 1 0 4 33.93 1.37 2.6422 -5 1 4 4 34.64 18.32 2.5897 2 0 8 2 35.03 1.35 2.5616 4 0 6 2 35.49 3.66 2.5292 -6 0 6 2 35.53 8.75 2.5264 5 1 2 4 36.44 11.50 2.4656 3 1 6 4 36.60 1.63 2.4551 -3 1 8 4 37.24 5.49 2.4143 5 1 3 4 38.22 23.93 2.3550 0 2 0 2 38.24 5.14 2.3534 0 0 10 2 38.41 5.95 2.3433 0 2 1 4 38.68 2.42 2.3281 -1 1 9 4 38.76 1.77 2.3233 -5 1 7 4 39.28 1.44 2.2939 5 1 4 4 39.32 14.72 2.2916 6 0 4 2 39.60 4.81 2.2759 -4 0 10 2 39.76 1.16 2.2669 -2 2 1 4 40.09 1.68 2.2492 -2 2 2 4 40.26 1.29 2.2401 2 2 1 4 40.79 1.15 2.2121 -2 2 3 4 41.07 4.84 2.1977 2 2 2 4 41.60 1.55 2.1711 5 1 5 4 41.61 1.09 2.1703 4 0 8 2 41.85 4.02 2.1583 -2 2 4 4 42.15 1.45 2.1439 -7 1 2 4 42.16 3.16 2.1436 -1 1 10 4 42.23 1.01 2.1398 -7 1 3 4 42.68 1.09 2.1183 -7 1 4 4 42.79 23.84 2.1134 -3 1 10 4 42.94 1.58 2.1061 0 2 5 4 42.97 1.68 2.1047 -8 0 2 2 44.11 2.67 2.0530 8 0 0 2 44.63 5.88 2.0304 -7 1 6 4 44.97 1.68 2.0158 -8 0 6 2 44.97 8.13 2.0158 -2 2 6 4 45.38 3.39 1.9987 7 1 2 4 45.53 1.46 1.9921 2 2 5 4 45.94 15.37 1.9756 4 2 2 4 46.09 2.30 1.9693 -7 1 7 4 46.28 5.92 1.9619 -5 1 10 4 46.59 2.06 1.9492 8 0 2 2 47.85 13.60 1.9009 -7 1 8 4 48.76 2.40 1.8677 4 0 10 2 48.91 3.23 1.8622 7 1 4 4 49.24 3.53 1.8507 -2 2 8 4 49.48 10.34 1.8420 -1 1 12 4 49.58 2.86 1.8385 0 2 8 4 49.96 13.75 1.8254 5 1 8 4 50.21 1.27 1.8170 2 0 12 2 50.27 7.25 1.8149 8 0 4 2 50.57 3.60 1.8050 -6 2 2 4 51.17 2.03 1.7852 6 2 0 4 51.24 13.00 1.7830 -6 2 4 4 51.51 8.89 1.7741 -4 2 8 4 51.95 5.98 1.7600 1 1 12 4 52.36 11.40 1.7473 -5 1 12 4 52.52 12.45 1.7423 2 2 8 4 53.14 6.56 1.7235 -6 2 6 4 53.50 3.76 1.7128 7 1 6 4 53.88 15.63 1.7016 9 1 0 4 54.50 7.68 1.6836 -10 0 4 2 54.97 1.40 1.6703 8 0 6 2 55.18 8.49 1.6647 0 2 10 4 55.99 5.99 1.6424 6 2 4 4 56.21 2.27 1.6366 -4 2 10 4 56.38 5.59 1.6320 4 0 12 2 56.48 1.13 1.6294 -9 1 8 4 57.01 1.22 1.6155 -3 1 14 4 57.09 2.46 1.6133 6 0 10 2 57.15 4.76 1.6118 -8 0 12 2 57.48 2.28 1.6032 -6 0 14 2 57.77 1.35 1.5959 4 2 8 4 59.14 1.32 1.5623 -5 1 14 4 60.00 3.15 1.5419 -9 1 10 4 60.45 2.05 1.5314 -8 2 6 4 60.50 1.02 1.5302 -2 2 12 4 61.01 4.94 1.5186 -1 3 4 4 61.44 1.04 1.5092 3 3 0 4 61.48 7.32 1.5082 -2 0 16 2 61.78 1.54 1.5016 8 2 2 4 61.85 1.14 1.5001 3 3 1 4 62.58 2.28 1.4843 -3 3 4 4 63.49 1.38 1.4651 3 3 3 4 63.50 3.82 1.4650 -7 1 14 4 63.58 2.19 1.4634 4 2 10 4 64.08 1.02 1.4532 9 1 6 4 64.67 6.93 1.4413 -11 1 6 4 64.67 3.90 1.4412 1 3 6 4 64.68 8.04 1.4412 3 1 14 4 64.72 4.81 1.4404 3 3 4 4 64.86 4.35 1.4376 8 2 4 4 65.34 3.42 1.4281 -10 0 12 2 65.61 8.22 1.4229 -5 3 2 4 66.53 1.05 1.4055 -11 1 8 4 66.54 1.33 1.4053 -5 1 16 4 67.35 1.25 1.3904 5 3 2 4 67.92 2.38 1.3800 3 3 6 4 68.03 1.37 1.3780 11 1 2 4 68.51 2.18 1.3696 -10 2 4 4 68.56 2.22 1.3687 12 0 0 2 69.39 1.80 1.3544 9 1 8 4 69.87 1.15 1.3462 -9 1 14 4 70.16 1.59 1.3414 4 2 12 4 70.79 2.10 1.3309 6 2 10 4 70.84 2.15 1.3301 -8 2 12 4 71.14 3.17 1.3253 -6 2 14 4 71.47 1.53 1.3200 -12 0 10 2 72.23 2.02 1.3080 -3 3 10 4 74.01 1.97 1.2808 8 0 12 2 74.36 1.60 1.2756 -10 2 10 4 74.74 6.12 1.2701 -2 2 16 4 75.54 4.35 1.2587 9 1 10 4 75.97 1.46 1.2526 -7 3 8 4 76.29 1.42 1.2481 2 0 18 2 77.19 1.18 1.2358 1 1 18 4 77.23 1.54 1.2353 -1 3 12 4 77.85 2.16 1.2269 -7 1 18 4 78.29 2.13 1.2211 -10 2 12 4 79.18 1.33 1.2096 1 3 12 4 79.38 1.62 1.2072 10 2 6 4 80.40 1.69 1.1943 -14 0 2 2 80.74 2.58 1.1902 9 3 0 4 80.97 2.52 1.1874 13 1 2 4 81.17 1.73 1.1850 11 1 8 4 81.31 1.33 1.1833 12 2 0 4 81.80 1.77 1.1775 0 4 0 2 82.43 3.49 1.1701 -3 1 20 4 83.76 3.08 1.1548 -11 1 16 4 84.06 2.15 1.1514 -12 2 10 4 85.29 1.09 1.1379 -8 0 20 2 86.30 1.44 1.1272 -2 4 6 4 86.50 1.96 1.1252 8 2 12 4 86.80 1.33 1.1220 1 1 20 4 88.55 1.79 1.1043 7 1 16 4 88.70 1.52 1.1028 2 2 18 4 ================================================================================ XPOW Copyright 1993 Bob Downs, Ranjini Swaminathan and Kurt Bartelmehs For reference, see Downs et al. (1993) American Mineralogist 78, 1104-1107.