data_global
_amcsd_formula_title 'H1.8 Mo2 O10.9 P2 Rb'
loop_
_publ_author_name
'Leclaire A'
'Borel M'
'Grandin A'
'Raveau B'
_journal_name_full 'Journal of Solid State Chemistry'
_journal_volume 108 
_journal_year 1994
_journal_page_first 177
_journal_page_last 183
_publ_section_title
;
 The mixed valent molybdenum monophosphate RbMo2P2O10.(1-x)H2O:
 an intersecting tunnel structure isotypic with leucophosphite
 _cod_database_code 1001614
;
_database_code_amcsd 0013791
_chemical_formula_sum 'Mo4 P4 Rb2 O21.8'
_cell_length_a 9.789
_cell_length_b 9.752
_cell_length_c 12.347
_cell_angle_alpha 90
_cell_angle_beta 128.81
_cell_angle_gamma 90
_cell_volume 918.456
_exptl_crystal_density_diffrn      3.715
_symmetry_space_group_name_H-M 'P 1 21/c 1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  'x,1/2-y,1/2+z'
  '-x,1/2+y,1/2-z'
  '-x,-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
Mo1   0.24602   0.19660   0.16663   1.00000
Mo2  -0.01442   0.03190   0.39763   1.00000
P1   0.15260   0.30840   0.35930   1.00000
P2   0.63130   0.01420   0.34030   1.00000
Rb1   0.64750   0.32150   0.12640   0.85000
Rb2   0.66200   0.18200   0.03800   0.10000
Rb3   0.50000   0.00000   0.00000   0.10000
O1   0.11400   0.06600   0.12730   1.00000
O2   0.28180   0.25240   0.33940   1.00000
O3   0.26390   0.16080   0.01500   1.00000
O4   0.06470   0.35010   0.05890   1.00000
O5   0.47590   0.09860   0.30000   1.00000
O6   0.42510   0.37090   0.21650   1.00000
O7   0.00630   0.20660   0.31440   1.00000
O8  -0.06930  -0.06100   0.22540   1.00000
O9   0.23910  -0.00870   0.49710   1.00000
O10  -0.26760   0.08220   0.29430   1.00000
O11   0.75300   0.33800   0.48800   0.90000