data_global
_amcsd_formula_title 'O17 P4 Pb2 V3'
loop_
_publ_author_name
'Leclaire A'
'Chardon J'
'Grandin A'
'Borel M'
'Raveau B'
_journal_name_full 'Journal of Solid State Chemistry'
_journal_volume 108 
_journal_year 1994
_journal_page_first 291
_journal_page_last 298
_publ_section_title
;
 The monophosphate Pb2V2VO(PO4)4: a tunnel structure with the
 mixed valence V(III)-V(IV)
 _cod_database_code 1001616
;
_database_code_amcsd 0013794
_chemical_formula_sum 'Pb2 V3 P4 O17'
_cell_length_a 17.74699
_cell_length_b 18.05099
_cell_length_c 9.344
_cell_angle_alpha 90
_cell_angle_beta 117.03
_cell_angle_gamma 90
_cell_volume 2666.389
_exptl_crystal_density_diffrn      4.798
_symmetry_space_group_name_H-M 'C 1 2/c 1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2+y,z'
  'x,-y,1/2+z'
  '1/2+x,1/2-y,1/2+z'
  '-x,y,1/2-z'
  '1/2-x,1/2+y,1/2-z'
  '-x,-y,-z'
  '1/2-x,1/2-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
Pb1   0.11296   0.12510   0.01898
Pb2   0.22976   0.47431   0.46871
V1   0.44720   0.21020   0.44570
V2   0.24690   0.30970   0.24740
V3   0.00000   0.06120   0.25000
V4   0.50000   0.05590   0.25000
P1   0.13850   0.19890   0.36270
P2   0.38790   0.44370   0.34190
P3   0.33240   0.16570   0.14920
P4   0.08300   0.42120   0.12950
O1   0.50410   0.27290   0.42200
O2   0.32850   0.22460   0.27000
O3   0.41310   0.24410   0.60100
O4   0.42560   0.14010   0.26100
O5   0.51470   0.13650   0.59700
O6   0.17380   0.39240   0.24000
O7   0.28990   0.33160   0.48200
O8   0.17270   0.23030   0.25100
O9   0.18040   0.29750   0.00300
O10   0.33840   0.37500   0.25100
O11   0.03640   0.07320   0.49500
O12   0.08090  -0.02040   0.27200
O13   0.08820   0.13250   0.26500
O14   0.57760  -0.01380   0.23400
O15   0.41850   0.04990   0.02300
O16   0.32900   0.49910   0.36700
O17   0.27080   0.10260   0.12300