Cs3Mo4P4O22 Borel M, Leclaire A, Grandin A, Raveau B Journal of Solid State Chemistry 108 (1994) 336-339 Cs3Mo4P4O22: A mixed valent monophosphate isotypic with K2Mo2P2O11 _cod_database_code 1001617 _database_code_amcsd 0013795 CELL PARAMETERS: 10.1340 10.1040 9.9520 90.000 100.440 90.000 SPACE GROUP: P2_1/c X-RAY WAVELENGTH: 1.541838 Cell Volume: 1002.155 Density (g/cm3): 4.170 MAX. ABS. INTENSITY / VOLUME**2: 21.89968522 RIR: 1.710 RIR based on corundum from Acta Crystallographica A38 (1982) 733-739 2-THETA INTENSITY D-SPACING H K L Multiplicity 8.87 2.21 9.9662 1 0 0 2 12.48 6.41 7.0954 1 1 0 4 12.59 6.06 7.0299 0 1 1 4 14.44 5.65 6.1329 -1 1 1 4 16.35 14.80 5.4218 1 1 1 4 17.80 2.54 4.9831 2 0 0 2 18.13 26.19 4.8936 0 0 2 2 18.70 4.04 4.7461 -1 0 2 2 19.70 48.05 4.5061 1 2 0 4 19.78 8.81 4.4892 0 2 1 4 20.16 19.37 4.4043 0 1 2 4 20.46 53.10 4.3406 -2 1 1 4 21.02 5.64 4.2268 -1 2 1 4 21.63 32.80 4.1080 1 0 2 2 23.05 19.34 3.8585 -2 0 2 2 23.18 11.51 3.8366 2 1 1 4 23.38 48.03 3.8055 1 1 2 4 25.10 8.21 3.5477 2 2 0 4 25.34 31.34 3.5150 0 2 2 4 25.76 10.38 3.4591 -1 2 2 4 27.77 14.13 3.2126 2 0 2 2 27.83 81.20 3.2055 2 2 1 4 27.96 34.72 3.1907 1 3 0 4 27.99 5.38 3.1873 1 2 2 4 28.18 30.42 3.1670 -3 1 1 4 28.28 76.49 3.1559 3 1 0 4 28.60 74.89 3.1209 -1 1 3 4 28.76 3.14 3.1046 0 1 3 4 28.92 100.00 3.0868 -1 3 1 4 29.12 34.98 3.0664 -2 2 2 4 29.95 4.19 2.9830 1 3 1 4 30.96 33.55 2.8883 -3 1 2 4 31.21 13.24 2.8662 -2 1 3 4 31.24 15.35 2.8631 3 1 1 4 31.63 2.63 2.8288 1 1 3 4 32.08 2.96 2.7904 2 3 0 4 32.16 2.08 2.7833 -3 2 1 4 32.54 1.05 2.7518 -1 2 3 4 32.67 1.67 2.7406 0 2 3 4 33.04 4.87 2.7109 2 2 2 4 34.30 3.65 2.6144 2 3 1 4 34.43 17.02 2.6045 1 3 2 4 34.66 6.98 2.5884 -3 2 2 4 34.88 9.40 2.5724 -2 2 3 4 35.26 6.23 2.5453 1 2 3 4 35.30 1.30 2.5428 3 0 2 2 35.38 2.52 2.5373 -2 3 2 4 35.54 1.66 2.5260 0 4 0 2 36.03 1.71 2.4928 -3 1 3 4 36.05 2.30 2.4916 4 0 0 2 36.44 8.78 2.4659 3 1 2 4 36.73 1.98 2.4468 0 0 4 2 37.17 1.89 2.4191 4 1 0 4 37.30 18.98 2.4110 -1 1 4 4 37.83 4.00 2.3781 0 1 4 4 37.92 1.18 2.3730 -2 0 4 2 37.97 1.55 2.3698 -3 3 1 4 38.05 1.71 2.3651 3 3 0 4 38.29 1.27 2.3509 1 4 1 4 38.30 2.78 2.3503 -1 3 3 4 38.41 9.82 2.3433 0 3 3 4 38.74 1.09 2.3247 2 3 2 4 39.48 5.02 2.2824 1 0 4 2 39.88 9.24 2.2605 2 2 3 4 39.90 3.26 2.2597 -4 2 1 4 39.93 3.96 2.2577 4 1 1 4 40.02 1.31 2.2531 2 4 0 4 40.34 7.55 2.2360 -2 4 1 4 40.34 1.99 2.2356 -2 3 3 4 40.37 7.47 2.2341 3 3 1 4 40.45 1.76 2.2298 -1 4 2 4 40.48 2.24 2.2282 -1 2 4 4 40.52 15.22 2.2263 1 1 4 4 40.68 3.46 2.2177 1 3 3 4 41.61 6.48 2.1703 -4 2 2 4 41.69 3.50 2.1665 -3 0 4 2 41.87 2.40 2.1573 2 4 1 4 42.07 14.79 2.1479 -2 2 4 4 43.18 2.63 2.0952 3 1 3 4 43.65 9.02 2.0736 4 0 2 2 44.31 23.49 2.0443 -3 3 3 4 44.61 3.65 2.0313 4 1 2 4 44.65 16.75 2.0294 3 3 2 4 44.83 3.26 2.0216 2 3 3 4 45.04 2.35 2.0128 2 1 4 4 45.09 2.38 2.0107 3 4 0 4 45.31 2.44 2.0016 -1 4 3 4 45.31 2.63 2.0015 -4 2 3 4 45.41 21.56 1.9973 0 4 3 4 45.51 4.29 1.9932 5 0 0 2 45.56 4.67 1.9911 -3 2 4 4 45.69 2.17 1.9857 2 4 2 4 45.85 7.09 1.9791 0 5 1 4 45.94 2.22 1.9753 -5 0 2 2 46.03 6.20 1.9719 3 2 3 4 46.43 2.88 1.9556 5 1 0 4 46.45 4.16 1.9549 -1 5 1 4 46.83 3.11 1.9399 -2 3 4 4 46.87 6.75 1.9386 -5 1 2 4 47.10 1.28 1.9293 -2 4 3 4 47.11 13.83 1.9293 -4 0 4 2 47.13 3.80 1.9284 3 4 1 4 47.15 8.06 1.9277 1 5 1 4 47.30 4.50 1.9217 0 1 5 4 47.39 2.37 1.9183 4 2 2 4 47.65 3.32 1.9085 4 3 1 4 47.80 6.81 1.9028 2 2 4 4 48.01 3.28 1.8950 -4 1 4 4 48.89 1.77 1.8629 -2 5 1 4 48.99 1.74 1.8593 -1 5 2 4 49.10 8.11 1.8553 5 1 1 4 49.14 1.73 1.8541 5 2 0 4 49.21 1.18 1.8517 -1 2 5 4 49.55 3.27 1.8396 -5 2 2 4 49.90 2.99 1.8275 1 1 5 4 49.97 1.09 1.8252 0 2 5 4 50.15 3.49 1.8190 3 0 4 2 50.32 4.15 1.8133 1 5 2 4 50.50 2.29 1.8073 3 3 3 4 50.65 4.07 1.8023 -3 4 3 4 51.12 1.70 1.7867 2 4 3 4 51.13 27.61 1.7863 -4 4 1 4 51.52 4.28 1.7738 4 4 0 4 52.04 4.62 1.7575 0 4 4 4 52.16 2.65 1.7536 2 3 4 4 52.72 1.19 1.7363 -5 3 1 4 52.94 1.06 1.7295 -2 4 4 4 53.00 1.46 1.7276 -3 2 5 4 53.24 2.84 1.7207 -1 5 3 4 53.48 1.08 1.7134 -1 3 5 4 53.55 1.40 1.7114 3 2 4 4 53.69 2.57 1.7072 4 4 1 4 54.20 2.51 1.6924 0 3 5 4 54.46 4.14 1.6849 -2 3 5 4 54.62 2.07 1.6802 -5 1 4 4 54.68 1.38 1.6785 -3 5 2 4 55.07 4.50 1.6676 -6 0 2 2 55.31 1.23 1.6610 6 0 0 2 55.36 4.33 1.6596 0 6 1 4 55.40 1.64 1.6584 -1 0 6 2 55.70 4.51 1.6503 -4 4 3 4 55.84 3.83 1.6465 5 3 1 4 56.05 3.67 1.6407 -2 0 6 2 56.21 2.92 1.6365 -1 1 6 4 57.08 4.98 1.6137 -3 3 5 4 57.20 4.93 1.6104 0 1 6 4 57.31 1.17 1.6076 -4 2 5 4 57.36 8.81 1.6063 4 0 4 2 57.38 1.73 1.6059 4 3 3 4 57.79 1.18 1.5954 2 6 0 4 58.03 1.62 1.5893 -2 6 1 4 58.15 1.13 1.5864 4 1 4 4 58.31 3.39 1.5825 -6 1 3 4 58.33 2.06 1.5820 3 5 2 4 58.33 4.27 1.5820 -3 0 6 2 58.47 1.11 1.5784 2 5 3 4 58.49 12.41 1.5779 6 2 0 4 58.58 1.19 1.5757 -1 2 6 4 59.10 1.09 1.5633 -1 4 5 4 59.22 5.39 1.5603 2 6 1 4 59.55 2.94 1.5523 0 2 6 4 59.77 11.17 1.5473 0 4 5 4 59.79 1.12 1.5468 1 1 6 4 59.93 9.88 1.5434 -2 6 2 4 60.14 1.04 1.5385 -2 5 4 4 60.63 5.57 1.5273 -6 2 3 4 60.70 1.19 1.5257 -5 1 5 4 60.93 3.34 1.5204 -5 3 4 4 61.31 2.68 1.5120 5 4 1 4 61.76 2.06 1.5020 3 6 0 4 62.00 4.01 1.4968 1 4 5 4 62.02 1.56 1.4964 0 6 3 4 62.11 4.44 1.4945 -4 0 6 2 62.11 1.54 1.4944 -6 3 2 4 62.19 2.16 1.4927 6 0 2 2 62.42 1.91 1.4878 -1 3 6 4 62.69 3.14 1.4820 -4 5 3 4 63.10 2.17 1.4733 2 0 6 2 63.27 6.70 1.4698 3 5 3 4 64.24 1.19 1.4499 4 3 4 4 64.71 1.32 1.4405 2 5 4 4 64.82 1.13 1.4384 6 3 1 4 65.09 2.38 1.4331 -4 2 6 4 65.14 1.76 1.4322 -7 1 1 4 65.15 3.74 1.4319 -3 3 6 4 65.28 5.50 1.4292 5 3 3 4 65.57 1.24 1.4237 7 0 0 2 65.70 1.68 1.4211 2 4 5 4 65.73 5.02 1.4206 3 3 5 4 65.81 1.21 1.4191 5 5 0 4 66.06 1.95 1.4144 2 2 6 4 66.15 1.38 1.4125 -5 5 2 4 66.61 1.73 1.4040 3 6 2 4 66.66 2.20 1.4031 -5 3 5 4 66.75 1.96 1.4015 2 6 3 4 67.08 1.05 1.3952 4 6 0 4 67.17 2.50 1.3936 -1 6 4 4 67.68 1.56 1.3844 -6 1 5 4 67.96 2.83 1.3794 5 5 1 4 68.45 1.12 1.3707 5 2 4 4 68.51 2.56 1.3696 6 1 3 4 68.63 1.87 1.3675 -1 2 7 4 68.63 1.16 1.3674 -5 5 3 4 68.79 1.03 1.3647 6 3 2 4 68.94 3.45 1.3621 -2 2 7 4 68.96 2.18 1.3618 1 7 2 4 69.07 5.60 1.3599 -3 5 5 4 69.35 1.21 1.3551 1 6 4 4 69.79 1.09 1.3475 0 2 7 4 69.83 2.27 1.3470 -6 2 5 4 70.64 1.43 1.3334 6 2 3 4 70.69 1.00 1.3326 -4 6 3 4 70.89 2.86 1.3293 -7 3 1 4 70.91 1.53 1.3291 -7 1 4 4 71.18 2.61 1.3247 -3 7 1 4 71.23 2.82 1.3239 3 7 0 4 71.23 1.13 1.3238 3 6 3 4 71.28 1.66 1.3231 -7 3 2 4 71.37 3.84 1.3216 3 2 6 4 71.39 1.29 1.3212 -1 7 3 4 71.99 1.08 1.3117 5 3 4 4 72.57 1.61 1.3027 -5 5 4 4 72.77 1.05 1.2995 3 7 1 4 72.99 2.06 1.2963 1 7 3 4 73.11 2.20 1.2943 7 1 2 4 73.15 3.32 1.2938 -7 3 3 4 74.20 1.95 1.2780 -3 3 7 4 74.30 3.31 1.2766 2 1 7 4 74.52 1.19 1.2734 -2 6 5 4 74.60 1.43 1.2721 7 3 1 4 75.19 1.77 1.2636 7 2 2 4 75.22 2.43 1.2632 -8 0 2 2 75.24 1.99 1.2630 0 8 0 2 75.53 2.72 1.2588 -3 7 3 4 75.80 1.18 1.2551 -8 1 1 4 75.86 3.04 1.2542 1 3 7 4 75.97 1.31 1.2526 0 8 1 4 76.37 2.43 1.2471 -5 1 7 4 76.47 1.22 1.2456 -7 3 4 4 77.33 1.89 1.2340 -4 3 7 4 78.05 1.45 1.2243 2 8 0 4 78.12 2.55 1.2234 0 0 8 2 78.39 1.23 1.2199 1 7 4 4 78.90 1.51 1.2132 -3 1 8 4 79.17 1.10 1.2098 5 6 2 4 79.64 1.73 1.2039 3 1 7 4 79.81 1.64 1.2017 -8 0 4 2 80.55 1.17 1.1925 -6 6 1 4 80.71 1.06 1.1905 2 5 6 4 81.37 1.20 1.1826 6 6 0 4 81.89 2.37 1.1764 -7 5 1 4 81.91 2.51 1.1761 -7 1 6 4 81.95 2.04 1.1756 -5 7 1 4 83.12 1.52 1.1621 -1 5 7 4 83.17 2.52 1.1615 4 5 5 4 83.23 2.01 1.1608 -6 6 3 4 83.41 1.14 1.1588 6 1 5 4 83.69 1.47 1.1556 5 1 6 4 85.01 1.05 1.1410 6 5 3 4 85.42 1.02 1.1366 6 2 5 4 86.70 1.64 1.1230 -6 6 4 4 88.09 2.07 1.1089 2 6 6 4 88.91 1.62 1.1008 9 1 0 4 90.00 2.46 1.0903 8 4 1 4 ================================================================================ XPOW Copyright 1993 Bob Downs, Ranjini Swaminathan and Kurt Bartelmehs For reference, see Downs et al. (1993) American Mineralogist 78, 1104-1107.