data_global _amcsd_formula_title 'Cd3V4(PO4)6' loop_ _publ_author_name 'Boudin S' 'Grandin A' 'Borel M' 'Leclaire A' 'Raveau B' _journal_name_full 'Journal of Solid State Chemistry' _journal_volume 110 _journal_year 1994 _journal_page_first 43 _journal_page_last 49 _publ_section_title ; A trivalent vanadium monophosphate with a tunnel structure: Cd3V4(PO4)6 _cod_database_code 1001600 ; _database_code_amcsd 0013807 _chemical_formula_sum 'Cd1.5 V2 P3 O12' _cell_length_a 12.446 _cell_length_b 12.547 _cell_length_c 6.487 _cell_angle_alpha 90 _cell_angle_beta 115.66 _cell_angle_gamma 90 _cell_volume 913.106 _exptl_crystal_density_diffrn 4.040 _symmetry_space_group_name_H-M 'C 1 2/c 1' loop_ _space_group_symop_operation_xyz 'x,y,z' '1/2+x,1/2+y,z' 'x,-y,1/2+z' '1/2+x,1/2-y,1/2+z' '-x,y,1/2-z' '1/2-x,1/2+y,1/2-z' '-x,-y,-z' '1/2-x,1/2-y,-z' loop_ _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_occupancy Cd1 0.50000 0.25198 0.25000 1.00000 Cd2 0.02080 -0.00030 0.46370 0.25000 V1 0.27756 0.15402 0.36760 1.00000 P1 0.24780 0.39270 0.13950 1.00000 P2 0.00000 0.21890 0.25000 1.00000 O1 0.32000 0.16150 0.09500 1.00000 O2 0.23180 0.32130 0.32040 1.00000 O3 0.29880 0.00520 0.35800 1.00000 O4 0.44570 0.20960 0.53460 1.00000 O5 0.09450 0.14570 0.22900 1.00000 O6 0.38210 0.39790 0.20200 1.00000