data_global _amcsd_formula_title 'Mo4 O22 P4 Rb3' loop_ _publ_author_name 'Borel M' 'Leclaire A' 'Guesdon A' 'Grandin A' 'Raveau B' _journal_name_full 'Journal of Solid State Chemistry' _journal_volume 112 _journal_year 1994 _journal_page_first 15 _journal_page_last 21 _publ_section_title ; Mixed valent molybdenum monophosphates with an intersecting tunnel structure: A3O2(MoO)4(PO4)4 (A=Rb, Tl) _cod_database_code 1001610 ; _database_code_amcsd 0013821 _chemical_formula_sum 'Rb3 Mo4 P4 O22' _cell_length_a 14.222 _cell_length_b 14.223 _cell_length_c 19.22699 _cell_angle_alpha 90 _cell_angle_beta 90 _cell_angle_gamma 90 _cell_volume 3889.226 _exptl_crystal_density_diffrn 3.812 _symmetry_space_group_name_H-M 'C 2 2 21' loop_ _space_group_symop_operation_xyz 'x,y,z' '1/2+x,1/2+y,z' '-x,y,1/2-z' '1/2-x,1/2+y,1/2-z' 'x,-y,-z' '1/2+x,1/2-y,-z' '-x,-y,1/2+z' '1/2-x,1/2-y,1/2+z' loop_ _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z Rb1 0.05358 0.44118 0.12649 Rb2 0.20810 0.00000 0.50000 Rb3 0.44128 0.44653 0.37644 Rb4 0.50000 0.20840 0.25000 Mo1 0.19029 0.32595 0.31033 Mo2 0.17406 0.19026 0.06031 Mo3 0.42511 0.18052 0.06374 Mo4 0.18057 0.07492 0.31366 P1 0.05260 0.20870 0.41960 P2 0.34510 0.19960 0.41000 P3 0.30050 0.34500 0.16010 P4 0.29170 0.05300 0.16960 O1 0.10260 0.37340 0.26370 O2 0.17830 0.20080 0.28700 O3 0.10980 0.29290 0.39500 O4 0.29590 0.34360 0.24030 O5 0.21920 0.45350 0.35760 O6 0.30270 0.28690 0.37730 O7 0.12620 0.10340 0.01350 O8 0.04790 0.21900 0.10730 O9 0.20650 0.10990 0.14450 O10 0.15580 0.29540 -0.00940 O11 0.29900 0.17800 0.03660 O12 0.21170 0.30320 0.12760 O13 0.46850 0.09660 0.01270 O14 0.44840 0.29100 0.00040 O15 0.55090 0.19670 0.11420 O16 0.38690 0.09560 0.14650 O17 0.38960 0.29440 0.13760 O18 0.09590 0.03070 0.26280 O19 0.09350 0.11330 0.39670 O20 0.19540 -0.04990 0.36320 O21 0.29190 0.05070 0.25020 O22 0.29450 0.11050 0.38760