Mo4 O22 P4 Rb3 Borel M, Leclaire A, Guesdon A, Grandin A, Raveau B Journal of Solid State Chemistry 112 (1994) 15-21 Mixed valent molybdenum monophosphates with an intersecting tunnel structure: A3O2(MoO)4(PO4)4 (A=Rb, Tl) _cod_database_code 1001610 _database_code_amcsd 0013821 CELL PARAMETERS: 14.2220 14.2230 19.2270 90.000 90.000 90.000 SPACE GROUP: C222_1 X-RAY WAVELENGTH: 1.541838 Cell Volume: 3889.226 Density (g/cm3): 3.811 MAX. ABS. INTENSITY / VOLUME**2: 24.56432893 RIR: 2.098 RIR based on corundum from Acta Crystallographica A38 (1982) 733-739 2-THETA INTENSITY D-SPACING H K L Multiplicity 12.45 11.75 7.1115 0 2 0 2 12.45 11.47 7.1110 2 0 0 2 13.27 1.07 6.6699 0 2 1 4 13.28 1.06 6.6695 2 0 1 4 15.50 13.30 5.7172 0 2 2 4 15.50 13.22 5.7170 2 0 2 4 18.46 14.27 4.8067 0 0 4 2 18.64 10.80 4.7609 0 2 3 4 18.64 10.65 4.7607 2 0 3 4 19.74 10.00 4.4977 1 3 0 4 19.74 9.83 4.4974 3 1 0 4 19.93 3.78 4.4557 2 2 2 4 20.28 27.57 4.3794 1 3 1 4 20.28 27.35 4.3792 3 1 1 4 20.48 40.16 4.3368 1 1 4 4 21.82 1.53 4.0739 1 3 2 4 21.82 1.60 4.0737 3 1 2 4 22.32 2.53 3.9824 0 2 4 4 22.32 2.55 3.9823 2 0 4 4 22.47 5.63 3.9561 2 2 3 4 24.17 6.27 3.6816 1 3 3 4 24.18 6.23 3.6814 3 1 3 4 24.79 4.24 3.5918 1 1 5 4 25.64 10.02 3.4746 2 2 4 4 26.35 22.05 3.3826 0 2 5 4 26.35 22.27 3.3825 2 0 5 4 26.73 1.57 3.3349 0 4 2 4 26.73 1.60 3.3347 4 0 2 4 27.15 1.27 3.2842 1 3 4 4 27.15 1.31 3.2841 3 1 4 4 28.06 1.19 3.1803 2 4 0 4 28.06 1.22 3.1802 4 2 0 4 28.45 49.96 3.1377 2 4 1 4 28.45 50.04 3.1376 4 2 1 4 28.71 41.78 3.1093 0 4 3 4 28.71 41.76 3.1091 4 0 3 4 29.24 3.88 3.0546 2 2 5 4 29.59 35.04 3.0194 2 4 2 4 29.59 35.15 3.0193 4 2 2 4 30.59 4.64 2.9228 1 3 5 4 30.59 4.61 2.9227 3 1 5 4 30.60 12.21 2.9216 0 2 6 4 30.60 12.30 2.9216 2 0 6 4 31.40 3.04 2.8488 2 4 3 4 31.40 3.00 2.8488 4 2 3 4 32.43 1.41 2.7605 1 5 1 4 32.44 1.44 2.7603 5 1 1 4 33.45 1.68 2.6789 1 5 2 4 33.45 1.62 2.6787 5 1 2 4 33.79 7.40 2.6523 2 4 4 4 33.80 7.50 2.6522 4 2 4 4 33.83 1.23 2.6497 1 1 7 4 34.35 8.30 2.6107 0 4 5 4 34.35 8.45 2.6106 4 0 5 4 34.36 2.92 2.6098 1 3 6 4 34.36 2.93 2.6098 3 1 6 4 35.02 2.17 2.5622 0 2 7 4 35.02 2.22 2.5622 2 0 7 4 35.09 3.24 2.5576 1 5 3 4 35.09 3.26 2.5575 5 1 3 4 35.53 2.18 2.5269 3 3 5 4 36.67 4.69 2.4507 2 4 5 4 36.67 4.65 2.4507 4 2 5 4 38.40 3.67 2.3442 1 3 7 4 38.40 3.70 2.3441 3 1 7 4 38.46 1.36 2.3406 4 4 3 4 38.51 4.49 2.3376 1 1 8 4 38.88 4.39 2.3164 3 3 6 4 39.14 1.34 2.3016 0 6 2 4 39.14 1.38 2.3014 6 0 2 4 39.53 1.12 2.2797 3 5 3 4 39.53 1.13 2.2796 5 3 3 4 39.58 5.96 2.2769 0 2 8 4 39.58 6.00 2.2768 2 0 8 4 40.10 1.73 2.2488 2 6 0 4 40.10 1.67 2.2487 6 2 0 4 40.38 1.16 2.2336 2 6 1 4 40.38 1.14 2.2335 6 2 1 4 41.54 5.70 2.1737 0 4 7 4 41.55 5.73 2.1736 4 0 7 4 42.52 1.99 2.1260 0 6 4 4 42.52 1.98 2.1259 6 0 4 4 42.55 2.13 2.1246 3 3 7 4 42.98 1.15 2.1043 4 4 5 4 43.30 3.73 2.0897 1 1 9 4 44.27 1.35 2.0460 0 2 9 4 44.27 1.35 2.0460 2 0 9 4 44.92 9.91 2.0179 0 6 5 4 44.92 9.91 2.0178 6 0 5 4 45.56 1.33 1.9912 0 4 8 4 45.56 1.29 1.9911 4 0 8 4 45.88 28.98 1.9780 4 4 6 4 46.11 9.35 1.9687 5 5 2 4 46.27 1.67 1.9620 4 6 1 4 46.27 1.72 1.9620 6 4 1 4 46.40 5.65 1.9571 1 5 7 4 46.40 5.61 1.9571 5 1 7 4 46.81 3.75 1.9409 3 5 6 4 46.81 3.82 1.9408 5 3 6 4 47.03 2.79 1.9321 4 6 2 4 47.03 2.85 1.9320 6 4 2 4 47.09 1.27 1.9297 1 3 9 4 47.09 1.25 1.9297 3 1 9 4 47.37 2.09 1.9191 1 7 3 4 47.37 2.09 1.9190 7 1 3 4 49.10 3.22 1.8555 1 7 4 4 49.10 3.21 1.8554 7 1 4 4 49.12 1.46 1.8546 4 4 7 4 49.73 1.66 1.8333 3 7 2 4 49.74 1.62 1.8332 7 3 2 4 49.79 1.17 1.8312 0 4 9 4 49.79 1.15 1.8312 4 0 9 4 49.98 3.07 1.8247 4 6 4 4 49.99 3.11 1.8247 6 4 4 4 50.67 1.95 1.8016 3 3 9 4 51.39 7.98 1.7779 0 8 0 2 51.40 8.18 1.7778 8 0 0 2 51.63 2.47 1.7703 0 8 1 4 51.63 2.43 1.7702 8 0 1 4 52.12 2.41 1.7550 4 6 5 4 52.12 2.42 1.7549 6 4 5 4 53.19 1.51 1.7221 1 1 11 4 54.02 1.21 1.6974 0 2 11 4 54.02 1.24 1.6974 2 0 11 4 54.07 3.22 1.6960 1 5 9 4 54.07 3.21 1.6960 5 1 9 4 54.36 1.67 1.6877 0 6 8 4 54.36 1.68 1.6876 6 0 8 4 54.99 2.13 1.6698 6 6 1 4 55.06 5.23 1.6678 3 3 10 4 55.07 1.63 1.6675 0 8 4 4 55.08 1.65 1.6674 8 0 4 4 55.66 3.11 1.6512 6 6 2 4 56.53 1.14 1.6280 4 4 9 4 56.70 1.79 1.6234 2 8 4 4 56.71 1.74 1.6233 8 2 4 4 57.57 1.16 1.6009 5 7 3 4 57.57 1.14 1.6009 7 5 3 4 58.13 1.06 1.5870 0 6 9 4 58.13 1.04 1.5869 6 0 9 4 58.32 4.95 1.5823 1 1 12 4 58.66 1.88 1.5737 2 8 5 4 58.67 1.87 1.5737 8 2 5 4 58.86 2.04 1.5688 4 8 2 4 58.87 1.99 1.5688 8 4 2 4 59.66 1.37 1.5499 3 3 11 4 59.93 8.59 1.5434 4 8 3 4 59.94 8.57 1.5433 8 4 3 4 60.63 15.22 1.5273 4 4 10 4 60.66 2.59 1.5266 2 2 12 4 61.40 2.96 1.5100 3 5 10 4 61.40 2.96 1.5100 5 3 10 4 61.41 1.20 1.5097 4 8 4 4 61.42 1.18 1.5096 8 4 4 4 62.10 1.45 1.4947 3 9 1 4 62.10 1.44 1.4946 9 3 1 4 62.18 2.29 1.4930 1 9 4 4 62.18 2.30 1.4929 9 1 4 4 62.54 1.08 1.4852 6 6 6 4 63.71 1.50 1.4607 2 8 7 4 63.71 1.47 1.4606 8 2 7 4 66.46 2.09 1.4068 0 6 11 4 66.46 2.12 1.4068 6 0 11 4 66.72 1.04 1.4019 7 7 3 4 66.76 2.67 1.4013 2 8 8 4 66.76 2.66 1.4012 8 2 8 4 68.04 1.20 1.3779 5 9 1 4 68.04 1.18 1.3778 9 5 1 4 68.14 1.43 1.3762 4 8 7 4 68.14 1.43 1.3761 8 4 7 4 68.74 2.01 1.3656 0 4 13 4 68.74 2.01 1.3656 4 0 13 4 68.94 1.55 1.3622 5 7 8 4 68.94 1.55 1.3621 7 5 8 4 70.12 1.11 1.3420 2 8 9 4 70.13 1.11 1.3420 8 2 9 4 71.63 2.67 1.3175 4 10 1 4 71.63 2.71 1.3174 10 4 1 4 72.31 1.34 1.3067 1 5 13 4 72.31 1.35 1.3067 5 1 13 4 75.65 2.51 1.2571 8 8 0 4 75.84 1.00 1.2544 8 8 1 4 77.42 1.17 1.2327 1 3 15 4 77.42 1.17 1.2327 3 1 15 4 79.81 1.67 1.2017 0 0 16 2 80.85 1.27 1.1889 2 4 15 4 80.85 1.28 1.1889 4 2 15 4 82.82 1.07 1.1655 0 12 3 4 82.83 1.08 1.1654 12 0 3 4 86.84 1.01 1.1216 1 9 12 4 86.84 1.01 1.1216 9 1 12 4 ================================================================================ XPOW Copyright 1993 Bob Downs, Ranjini Swaminathan and Kurt Bartelmehs For reference, see Downs et al. (1993) American Mineralogist 78, 1104-1107.