data_global
_amcsd_formula_title 'Mo1.17 Na0.75 O11 P2 W0.83'
loop_
_publ_author_name
'Leclaire A'
'Borel M'
'Chardon J'
'Raveau B'
_journal_name_full 'Journal of Solid State Chemistry'
_journal_volume 120 
_journal_year 1995
_journal_page_first 353
_journal_page_last 357
_publ_section_title
;
 A mixed-valent molybdenotungsten monophosphate with a tunnel structure:
 Nax(Mo,W)2O3(PO4)2
 _cod_database_code 1001715
;
_database_code_amcsd 0013880
_chemical_formula_sum '(W.83 Mo1.17) P2 Na.75 O11'
_cell_length_a 7.200
_cell_length_b 6.369
_cell_length_c 9.123
_cell_angle_alpha 90
_cell_angle_beta 106.29
_cell_angle_gamma 90
_cell_volume 401.557
_exptl_crystal_density_diffrn      4.301
_symmetry_space_group_name_H-M 'P 1 21/m 1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  'x,1/2-y,z'
  '-x,1/2+y,-z'
  '-x,-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
W1   0.10990   0.25000   0.20000   0.58000
Mo1   0.10990   0.25000   0.20000   0.42000
W2   0.31150   0.25000   0.63450   0.25000
Mo2   0.31150   0.25000   0.63450   0.75000
P1   0.41170   0.75000   0.61060   1.00000
P2   0.01670   0.75000   0.17380   1.00000
Na1   0.48100   0.59400   0.95900   0.18750
Na2   0.39100   0.49600   0.01800   0.18750
O1   0.86400   0.25000   0.12800   1.00000
O2   0.13200   0.25000   0.39400   1.00000
O3   0.14900   0.55600   0.18400   1.00000
O4   0.14400   0.25000  -0.02600   1.00000
O5   0.41900   0.25000   0.24700   1.00000
O6   0.45400   0.25000   0.81600   1.00000
O7   0.06700   0.25000   0.69000   1.00000
O8   0.28300   0.55700   0.60700   1.00000
O9   0.52300   0.25000   0.53500   1.00000