Mo1.17 Na0.75 O11 P2 W0.83 Leclaire A, Borel M, Chardon J, Raveau B Journal of Solid State Chemistry 120 (1995) 353-357 A mixed-valent molybdenotungsten monophosphate with a tunnel structure: Nax(Mo,W)2O3(PO4)2 _cod_database_code 1001715 _database_code_amcsd 0013880 CELL PARAMETERS: 7.2000 6.3690 9.1230 90.000 106.290 90.000 SPACE GROUP: P2_1/m X-RAY WAVELENGTH: 1.541838 Cell Volume: 401.557 Density (g/cm3): 4.300 MAX. ABS. INTENSITY / VOLUME**2: 37.85263079 RIR: 2.866 RIR based on corundum from Acta Crystallographica A38 (1982) 733-739 2-THETA INTENSITY D-SPACING H K L Multiplicity 10.10 9.42 8.7568 0 0 1 2 12.81 16.47 6.9110 1 0 0 2 13.92 34.27 6.3617 -1 0 1 2 17.22 5.62 5.1507 0 1 1 4 18.45 20.32 4.8085 1 0 1 2 18.95 100.00 4.6835 1 1 0 4 19.72 33.76 4.5010 -1 1 1 4 20.28 26.41 4.3784 0 0 2 2 20.75 7.35 4.2811 -1 0 2 2 23.18 5.14 3.8376 1 1 1 4 24.67 23.53 3.6080 0 1 2 4 24.91 70.85 3.5748 -2 0 1 2 25.06 19.03 3.5530 -1 1 2 4 26.99 63.99 3.3033 1 0 2 2 28.02 76.28 3.1845 0 2 0 2 28.05 2.34 3.1809 -2 0 2 2 29.41 6.92 3.0373 2 1 0 4 29.70 49.08 3.0083 -1 0 3 2 29.85 1.86 2.9927 0 2 1 4 30.35 10.20 2.9446 2 0 1 2 30.48 2.93 2.9324 1 1 2 4 30.92 4.27 2.8922 1 2 0 4 31.41 7.75 2.8477 -1 2 1 4 32.93 2.99 2.7201 -1 1 3 4 33.53 5.72 2.6728 2 1 1 4 33.76 9.26 2.6551 1 2 1 4 33.78 6.23 2.6535 0 1 3 4 34.20 5.30 2.6216 -2 0 3 2 34.84 12.90 2.5754 0 2 2 4 37.08 8.42 2.4243 -2 1 3 4 37.84 18.59 2.3779 -2 2 1 4 38.44 1.13 2.3417 2 2 0 4 39.30 14.98 2.2926 1 2 2 4 39.54 1.48 2.2791 -1 0 4 2 40.07 3.14 2.2505 -2 2 2 4 40.09 7.58 2.2493 2 1 2 4 40.16 22.72 2.2455 -3 1 1 4 41.24 2.42 2.1892 0 0 4 2 41.28 15.58 2.1868 -1 2 3 4 41.34 10.41 2.1841 -3 1 2 4 41.69 2.65 2.1663 3 1 0 4 41.78 6.77 2.1620 2 2 1 4 42.11 1.77 2.1459 -1 1 4 4 42.22 1.11 2.1406 -2 0 4 2 42.64 1.93 2.1206 -3 0 3 2 43.33 11.68 2.0884 3 0 1 2 43.72 6.23 2.0703 0 1 4 4 44.65 18.19 2.0294 1 3 0 4 44.66 1.17 2.0290 -2 1 4 4 44.78 5.11 2.0240 -2 2 3 4 45.02 7.43 2.0138 -1 3 1 4 45.06 2.72 2.0120 -3 1 3 4 45.72 1.94 1.9844 3 1 1 4 45.99 1.80 1.9736 2 0 3 2 46.77 1.25 1.9421 1 3 1 4 46.92 4.25 1.9365 1 0 4 2 47.60 8.08 1.9103 0 3 2 4 47.82 4.49 1.9020 -1 3 2 4 48.28 1.27 1.8851 2 1 3 4 48.68 8.86 1.8704 -3 0 4 2 49.18 3.97 1.8527 1 1 4 4 50.01 3.32 1.8239 -1 0 5 2 50.45 1.99 1.8089 2 3 0 4 50.60 1.40 1.8040 0 2 4 4 50.88 1.18 1.7946 -3 1 4 4 50.92 1.14 1.7933 -4 0 1 2 51.10 7.19 1.7874 -4 0 2 2 51.46 1.60 1.7759 -2 0 5 2 51.79 1.06 1.7654 3 1 2 4 52.17 4.40 1.7534 -1 1 5 4 52.23 8.45 1.7514 0 0 5 2 52.39 5.99 1.7463 3 2 1 4 53.00 1.98 1.7277 4 0 0 2 53.05 1.25 1.7262 -4 1 1 4 53.19 2.78 1.7221 2 3 1 4 53.36 3.72 1.7169 0 3 3 4 53.57 4.89 1.7106 -2 1 5 4 54.33 1.81 1.6887 0 1 5 4 54.72 2.18 1.6775 2 2 3 4 55.07 4.24 1.6675 4 1 0 4 55.54 4.74 1.6546 1 2 4 4 55.65 6.19 1.6517 2 0 4 2 55.71 5.60 1.6499 -2 3 3 4 57.11 7.09 1.6128 -3 2 4 4 57.50 2.96 1.6028 3 0 3 2 57.66 2.26 1.5988 2 1 4 4 57.92 10.68 1.5922 0 4 0 2 57.95 5.57 1.5914 2 3 2 4 58.00 11.38 1.5900 -3 3 1 4 58.30 4.11 1.5827 -1 2 5 4 58.91 3.56 1.5678 -3 3 2 4 59.14 8.39 1.5622 4 1 1 4 59.29 6.15 1.5587 -4 2 2 4 59.47 2.19 1.5544 3 1 3 4 59.79 1.23 1.5468 1 1 5 4 59.88 1.19 1.5446 -1 4 1 4 59.95 9.63 1.5431 -4 1 4 4 60.31 4.70 1.5346 0 2 5 4 60.77 3.05 1.5240 0 3 4 4 61.01 2.05 1.5186 4 2 0 4 61.33 1.18 1.5115 1 4 1 4 61.66 4.38 1.5042 -2 0 6 2 61.84 1.48 1.5003 -3 3 3 4 62.02 2.05 1.4964 0 4 2 4 63.44 3.33 1.4662 2 2 4 4 63.56 1.39 1.4639 -2 1 6 4 64.01 5.62 1.4545 -2 4 1 4 65.02 1.09 1.4345 4 1 2 4 65.02 5.75 1.4343 1 4 2 4 65.16 3.13 1.4317 3 2 3 4 65.21 2.42 1.4307 1 3 4 4 65.40 1.30 1.4270 -3 0 6 2 65.61 1.44 1.4229 -4 2 4 4 66.43 5.61 1.4073 -1 4 3 4 66.63 3.99 1.4037 -5 1 2 4 66.79 1.75 1.4006 2 4 1 4 67.23 2.32 1.3925 -3 1 6 4 67.73 2.93 1.3834 -1 3 5 4 67.80 1.91 1.3822 5 0 0 2 68.02 1.87 1.3783 -5 1 3 4 68.50 1.91 1.3698 3 1 4 4 68.94 2.74 1.3622 -2 3 5 4 69.01 1.30 1.3609 -2 4 3 4 69.06 4.13 1.3601 -2 2 6 4 70.24 1.89 1.3401 4 3 0 4 71.24 1.79 1.3237 1 1 6 4 71.28 1.17 1.3230 -5 1 4 4 72.50 1.04 1.3038 4 1 3 4 72.60 1.87 1.3023 -3 2 6 4 73.80 1.65 1.2839 -4 1 6 4 73.83 5.95 1.2835 4 3 1 4 74.12 1.32 1.2792 3 3 3 4 74.41 1.26 1.2750 1 3 5 4 74.55 5.97 1.2729 -4 3 4 4 74.73 2.39 1.2703 -1 1 7 4 74.89 2.02 1.2679 5 2 0 4 75.01 2.47 1.2662 3 4 1 4 75.96 1.26 1.2527 1 5 0 4 76.09 1.06 1.2510 0 0 7 2 77.63 1.57 1.2299 1 4 4 4 77.87 1.49 1.2268 2 0 6 2 78.82 2.02 1.2143 3 1 5 4 78.97 2.64 1.2124 -3 4 4 4 79.84 2.34 1.2013 5 1 2 4 79.99 1.43 1.1995 -1 4 5 4 80.66 3.23 1.1912 -5 3 2 4 80.84 2.23 1.1889 -4 4 2 4 81.22 1.89 1.1843 -3 3 6 4 81.74 2.75 1.1781 0 4 5 4 82.41 2.01 1.1702 3 3 4 4 82.80 1.28 1.1658 -6 1 1 4 82.92 1.63 1.1643 0 2 7 4 84.52 2.04 1.1463 2 4 4 4 84.66 2.09 1.1448 2 2 6 4 85.00 1.36 1.1412 1 3 6 4 85.71 1.68 1.1334 6 1 0 4 86.07 1.48 1.1296 3 4 3 4 86.50 1.65 1.1251 -3 5 1 4 87.45 1.15 1.1153 -4 3 6 4 88.34 1.83 1.1064 -1 3 7 4 88.91 1.60 1.1008 -3 1 8 4 88.98 2.48 1.1001 -6 1 5 4 89.67 2.16 1.0934 -2 4 6 4 ================================================================================ XPOW Copyright 1993 Bob Downs, Ranjini Swaminathan and Kurt Bartelmehs For reference, see Downs et al. (1993) American Mineralogist 78, 1104-1107.