data_global
_amcsd_formula_title 'K6.6Mo2.36W3.64O15(PO4)4'
loop_
_publ_author_name
'Leclaire A'
'Borel M'
'Chardon J'
'Raveau B'
_journal_name_full 'Journal of Solid State Chemistry'
_journal_volume 127 
_journal_year 1996
_journal_page_first 1
_journal_page_last 8
_publ_section_title
;
 A molybdenotungsten monophosphate with an opened structure
 K6.6Mo2.36W3.64O15(PO4)4
 _cod_database_code 1001733
;
_database_code_amcsd 0013902
_chemical_formula_sum '(W3.66 Mo2.34) P4 K6.595 O31'
_cell_length_a 17.545
_cell_length_b 17.545
_cell_length_c 15.714
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 120
_cell_volume 4189.133
_exptl_crystal_density_diffrn      4.222
_symmetry_space_group_name_H-M 'R -3'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '2/3+x,1/3+y,1/3+z'
  '1/3+x,2/3+y,2/3+z'
  'y,-x+y,-z'
  '2/3+y,1/3-x+y,1/3-z'
  '1/3+y,2/3-x+y,2/3-z'
  '-x+y,-x,z'
  '2/3-x+y,1/3-x,1/3+z'
  '1/3-x+y,2/3-x,2/3+z'
  '-x,-y,-z'
  '2/3-x,1/3-y,1/3-z'
  '1/3-x,2/3-y,2/3-z'
  '-y,x-y,z'
  '2/3-y,1/3+x-y,1/3+z'
  '1/3-y,2/3+x-y,2/3+z'
  'x-y,x,-z'
  '2/3+x-y,1/3+x,1/3-z'
  '1/3+x-y,2/3+x,2/3-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
W1   0.46896   0.17281   0.00563   0.74000
Mo1   0.46896   0.17281   0.00563   0.26000
W2   0.22700   0.27650   0.13100   0.48000
Mo2   0.22700   0.27650   0.13100   0.52000
P1   0.15040   0.41540   0.15590   1.00000
P2   0.66667   0.33333   0.05220   1.00000
K1   0.00000   0.00000   0.00000   0.19000
K2   0.00000   0.00000   0.50000   1.00000
K3   0.46330   0.38730   0.02300   1.00000
K4   0.16600   0.03200   0.09800   0.44000
K5   0.21400   0.04800   0.09500   0.56000
O1   0.45200   0.23900   0.07700   1.00000
O2   0.60000   0.24700   0.01300   1.00000
O3   0.47000   0.09200   0.08200   1.00000
O4   0.35400   0.09400  -0.02900   1.00000
O5   0.47900   0.25600  -0.09400   1.00000
O6   0.51300   0.11200  -0.08300   1.00000
O7   0.14300   0.18300   0.08300   1.00000
O8   0.31000   0.25600   0.12600   1.00000
O9   0.31400   0.39700   0.19800   1.00000
O10   0.13400   0.32000   0.14700   1.00000
O11   0.66667   0.33333   0.14700   1.00000