Mo1.04 O11 P2 W0.96 Leclaire A, Borel M, Chardon J, Raveau B Journal of Solid State Chemistry 128 (1997) 191-196 The molybdenotungsten monophosphate Mo W O3 (P O4)2: an original three- dimensional framework built up of "M P O8" chains (M = Mo, W) _cod_database_code 1001804 _database_code_amcsd 0013915 CELL PARAMETERS: 7.8270 12.5380 7.8330 90.000 92.360 90.000 SPACE GROUP: P2_1/m X-RAY WAVELENGTH: 1.541838 Cell Volume: 768.039 Density (g/cm3): 4.446 MAX. ABS. INTENSITY / VOLUME**2: 33.22209139 RIR: 2.433 RIR based on corundum from Acta Crystallographica A38 (1982) 733-739 2-THETA INTENSITY D-SPACING H K L Multiplicity 11.31 3.40 7.8264 0 0 1 2 11.31 2.46 7.8204 1 0 0 2 15.69 8.38 5.6495 -1 0 1 2 16.35 5.17 5.4215 1 0 1 2 17.22 8.85 5.1508 -1 1 1 4 18.13 14.56 4.8929 0 2 1 4 18.14 100.00 4.8914 1 2 0 4 21.17 83.69 4.1968 -1 2 1 4 21.67 55.82 4.1007 1 2 1 4 22.72 58.85 3.9132 0 0 2 2 22.74 18.63 3.9102 2 0 0 2 23.82 3.31 3.7355 0 1 2 4 25.02 35.70 3.5587 -1 0 2 2 25.03 69.91 3.5570 -2 0 1 2 25.88 37.23 3.4432 1 0 2 2 25.89 59.79 3.4417 2 0 1 2 26.04 2.91 3.4219 -2 1 1 4 26.53 2.17 3.3599 -1 3 1 4 26.85 2.13 3.3203 1 1 2 4 26.87 4.09 3.3177 2 2 0 4 28.48 98.08 3.1345 0 4 0 2 28.85 5.87 3.0948 -1 2 2 4 28.86 1.19 3.0937 -2 2 1 4 29.60 33.19 3.0180 1 2 2 4 29.61 1.95 3.0169 2 2 1 4 31.31 4.58 2.8565 0 3 2 4 32.67 1.56 2.7409 -1 4 1 4 33.05 1.04 2.7107 2 0 2 2 33.07 1.52 2.7087 -2 3 1 4 33.73 1.10 2.6575 1 3 2 4 34.84 27.44 2.5754 -2 2 2 4 35.83 4.46 2.5059 -1 0 3 2 35.86 2.11 2.5043 -3 0 1 2 36.10 16.54 2.4881 2 2 2 4 36.74 11.75 2.4464 0 4 2 4 36.75 6.53 2.4457 2 4 0 4 36.76 4.88 2.4447 1 0 3 2 36.79 2.84 2.4432 3 0 1 2 37.33 13.62 2.4086 0 2 3 4 37.36 17.86 2.4070 3 2 0 4 38.26 13.56 2.3522 -1 4 2 4 38.27 20.14 2.3517 -2 4 1 4 38.70 6.28 2.3269 -1 2 3 4 38.72 3.59 2.3256 -3 2 1 4 38.85 10.95 2.3179 1 4 2 4 38.86 16.88 2.3174 2 4 1 4 39.57 3.31 2.2776 1 2 3 4 39.59 2.36 2.2764 3 2 1 4 40.78 5.46 2.2126 -2 0 3 2 40.79 1.90 2.2119 -3 0 2 2 42.44 9.12 2.1300 2 0 3 2 43.38 13.36 2.0859 -3 2 2 4 44.90 2.62 2.0189 0 6 1 4 44.90 13.85 2.0188 1 6 0 4 44.96 14.70 2.0163 3 2 2 4 46.33 17.09 1.9599 -1 6 1 4 46.39 1.66 1.9573 -1 4 3 4 46.41 1.23 1.9565 -3 4 1 4 46.45 7.21 1.9551 4 0 0 2 46.58 12.90 1.9498 1 6 1 4 47.15 2.41 1.9277 1 4 3 4 47.16 1.25 1.9270 3 4 1 4 47.43 8.62 1.9168 -1 0 4 2 47.47 2.84 1.9154 -4 0 1 2 48.33 10.85 1.8832 -3 0 3 2 48.42 7.73 1.8799 1 0 4 2 48.45 2.47 1.8787 4 0 1 2 49.78 7.47 1.8318 -4 2 1 4 50.49 2.42 1.8076 -2 4 3 4 50.50 1.15 1.8073 -3 4 2 4 50.50 9.14 1.8072 3 0 3 2 50.66 3.15 1.8020 -1 6 2 4 50.70 1.36 1.8007 1 2 4 4 50.73 1.82 1.7996 4 2 1 4 51.13 7.59 1.7864 1 6 2 4 51.38 5.24 1.7785 -4 0 2 2 51.90 5.10 1.7617 2 4 3 4 53.23 5.86 1.7209 4 0 2 2 53.54 12.16 1.7117 -2 2 4 4 54.63 9.05 1.6799 -2 6 2 4 55.34 17.22 1.6602 2 2 4 4 55.39 4.00 1.6589 4 4 0 4 55.53 6.47 1.6550 2 6 2 4 56.26 6.62 1.6353 -1 4 4 4 56.29 2.23 1.6344 -4 4 1 4 56.42 7.83 1.6310 0 6 3 4 56.44 9.48 1.6305 3 6 0 4 57.05 9.29 1.6142 -3 4 3 4 57.13 3.83 1.6122 1 4 4 4 57.16 1.49 1.6114 4 4 1 4 57.42 3.32 1.6049 -1 6 3 4 57.43 2.01 1.6045 -3 6 1 4 57.74 1.10 1.5967 -3 0 4 2 58.07 2.10 1.5884 1 6 3 4 58.08 1.66 1.5880 3 6 1 4 58.93 11.59 1.5673 0 8 0 2 59.00 5.45 1.5656 3 4 3 4 59.77 2.88 1.5471 -1 0 5 2 59.78 9.11 1.5470 -4 2 3 4 59.79 3.54 1.5468 -4 4 2 4 60.30 1.02 1.5348 3 0 4 2 60.83 1.89 1.5228 1 0 5 2 61.00 5.53 1.5190 -3 6 2 4 61.01 11.07 1.5186 0 2 5 4 61.47 4.94 1.5085 4 4 2 4 61.81 9.59 1.5011 -5 2 1 4 62.25 7.41 1.4915 3 6 2 4 62.29 5.03 1.4905 4 2 3 4 62.84 10.52 1.4788 5 2 1 4 63.10 1.59 1.4734 -5 0 2 2 63.99 3.65 1.4549 0 8 2 4 64.00 1.31 1.4547 2 8 0 4 64.98 1.56 1.4351 -2 2 5 4 65.02 2.95 1.4343 -1 8 2 4 65.03 6.52 1.4342 -2 8 1 4 65.13 1.25 1.4322 5 0 2 2 65.43 2.56 1.4264 1 8 2 4 65.43 5.60 1.4263 2 8 1 4 66.18 2.76 1.4120 -4 6 1 4 66.98 1.11 1.3971 4 6 1 4 67.52 2.01 1.3873 -1 4 5 4 68.01 1.04 1.3784 3 4 4 4 68.50 1.95 1.3697 1 4 5 4 68.66 3.66 1.3670 -3 0 5 2 69.37 6.20 1.3547 -2 6 4 4 70.64 1.78 1.3334 -5 4 2 4 70.93 1.08 1.3288 -1 8 3 4 70.93 9.35 1.3287 2 6 4 4 71.58 2.23 1.3182 3 0 5 2 73.05 1.21 1.2953 -1 0 6 2 74.26 2.57 1.2772 6 0 1 2 74.85 4.64 1.2686 -4 6 3 4 74.91 1.24 1.2676 -6 2 1 4 75.28 1.63 1.2624 2 8 3 4 75.94 4.44 1.2530 -3 4 5 4 75.96 7.33 1.2528 0 6 5 4 76.37 2.46 1.2470 -5 0 4 2 76.67 5.41 1.2429 -5 6 1 4 77.03 1.02 1.2380 1 10 0 4 77.12 3.63 1.2368 4 6 3 4 77.61 6.16 1.2301 5 6 1 4 77.73 2.45 1.2286 -2 2 6 4 78.07 1.62 1.2240 -1 10 1 4 78.16 1.77 1.2228 4 8 0 4 78.76 1.44 1.2151 3 4 5 4 78.90 2.50 1.2133 -1 8 4 4 79.58 3.42 1.2046 -3 8 3 4 79.64 1.93 1.2038 1 8 4 4 79.97 2.19 1.1998 2 2 6 4 80.12 1.61 1.1979 5 0 4 2 80.18 1.39 1.1971 -1 4 6 4 81.25 2.53 1.1840 3 8 3 4 81.35 3.09 1.1828 6 4 1 4 81.86 1.89 1.1768 4 2 5 4 81.94 1.36 1.1758 -4 8 2 4 82.86 1.79 1.1650 -6 2 3 4 83.06 1.04 1.1628 -6 4 2 4 83.41 2.50 1.1587 4 8 2 4 83.42 3.48 1.1587 -5 4 4 4 84.55 1.55 1.1460 -2 10 2 4 86.03 1.21 1.1301 0 10 3 4 86.05 1.50 1.1299 3 10 0 4 87.10 1.48 1.1190 5 4 4 4 88.88 1.12 1.1010 -1 8 5 4 89.00 3.09 1.0999 7 2 0 4 89.39 1.59 1.0961 -1 2 7 4 89.80 1.08 1.0922 1 8 5 4 ================================================================================ XPOW Copyright 1993 Bob Downs, Ranjini Swaminathan and Kurt Bartelmehs For reference, see Downs et al. (1993) American Mineralogist 78, 1104-1107.