data_global
_amcsd_formula_title 'Bi0.65 Gd0.35 O1.5'
loop_
_publ_author_name
'Drache M'
'Conflant P'
'Obbade S'
'Wignacourt J'
'Watanabe A'
_journal_name_full 'Journal of Solid State Chemistry'
_journal_volume 129 
_journal_year 1997
_journal_page_first 98
_journal_page_last 104
_publ_section_title
;
 Stability, thermal behaviour, and crystal structure of ion ordered
 Bi1-xLnxO1.5 phases (Ln = Sm - Dy)
 _cod_database_code 1004122
;
_database_code_amcsd 0013918
_chemical_formula_sum 'Bi5.198 Gd2.802 O12'
_cell_length_a 11.0488
_cell_length_b 11.0488
_cell_length_c 11.0488
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 90
_cell_volume 1348.793
_exptl_crystal_density_diffrn      8.465
_symmetry_space_group_name_H-M 'I 21 3'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2+y,1/2+z'
  '1/2-z,-x,1/2+y'
  '-z,1/2-x,+y'
  '-z,1/2+x,1/2-y'
  '1/2-z,+x,-y'
  '1/2+z,1/2-x,-y'
  '+z,-x,1/2-y'
  'z,x,y'
  '1/2+z,1/2+x,1/2+y'
  '1/2+y,1/2-z,-x'
  '+y,-z,1/2-x'
  '1/2-y,-z,1/2+x'
  '-y,1/2-z,+x'
  '-y,1/2+z,1/2-x'
  '1/2-y,+z,-x'
  'y,z,x'
  '1/2+y,1/2+z,1/2+x'
  '-x,1/2+y,1/2-z'
  '1/2-x,+y,-z'
  '1/2+x,1/2-y,-z'
  '+x,-y,1/2-z'
  '1/2-x,-y,1/2+z'
  '-x,1/2-y,+z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
Bi1   0.27020   0.27020   0.27020   1.00000
Bi2  -0.01630   0.00000   0.25000   1.00000
Bi3   0.49790   0.00000   0.25000   0.06600
Gd1   0.49790   0.00000   0.25000   0.93400
O1   0.37300   0.07900   0.38800   1.00000
O2   0.12700   0.34900   0.13900   1.00000