data_global
_amcsd_formula_title 'Na3Eu(CO3)3'
loop_
_publ_author_name
'Mercier N'
'Leblanc M'
'Antic-Fidancev E'
'Lemaitre-Blaise M'
_journal_name_full 'Journal of Solid State Chemistry'
_journal_volume 132 
_journal_year 1997
_journal_page_first 33
_journal_page_last 40
_publ_section_title
;
 Structural and optical investigations of sodium europium carbonate Na3Eu(CO3)3
 _cod_database_code 1000450
;
_database_code_amcsd 0013932
_chemical_formula_sum 'Na3 Eu C3 O9'
_cell_length_a 9.942
_cell_length_b 11.024
_cell_length_c 7.147
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 90
_cell_volume 783.316
_exptl_crystal_density_diffrn      3.400
_symmetry_space_group_name_H-M 'A m a 2'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  'x,1/2+y,1/2+z'
  '1/2+x,-y,z'
  '1/2+x,1/2-y,1/2+z'
  '1/2-x,y,z'
  '1/2-x,1/2+y,1/2+z'
  '-x,-y,z'
  '-x,1/2-y,1/2+z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
Na1   0.25000   0.79260   0.00190
Na2   0.00000   0.00000   0.06670
Na3   0.25000   0.01800   0.38740
Eu1   0.25000   0.72838   0.50000
C1  -0.00110   0.20390   0.32590
C2   0.25000   0.01220   0.77140
O1   0.25000   0.11580   0.69240
O2   0.11310   0.16480   0.26620
O3   0.10930   0.85860   0.29910
O4   0.25000   0.41330   0.17900
O5   0.01010   0.19690  -0.08300
O6   0.25000   0.00960  -0.04440
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
Na1 0.01180 0.00670 0.00940 0.00000 0.00000 0.00240
Na2 0.01660 0.01240 0.02090 -0.00120 0.00000 0.00000
Na3 0.01370 0.01020 0.01700 0.00000 0.00000 0.00220
Eu1 0.00700 0.00610 0.00770 0.00000 0.00000 0.00045
C1 0.00930 0.01040 0.00860 -0.00070 0.00160 0.00000
C2 0.01370 0.00700 0.01250 0.00000 0.00000 -0.00220
O1 0.02850 0.00940 0.01180 0.00000 0.00000 0.00200
O2 0.00750 0.01580 0.01420 0.00240 0.00280 0.00150
O3 0.00950 0.01190 0.02170 -0.00290 -0.00340 0.00460
O4 0.02760 0.01110 0.01480 0.00000 0.00000 -0.00400
O5 0.01400 0.01640 0.02220 -0.00340 -0.00460 0.01080
O6 0.02060 0.01140 0.00970 0.00000 0.00000 0.00190