Bi9 Cl O18 V2 Mentre O, Abraham F Journal of Solid State Chemistry 136 (1998) 34-45 Synthesis, crystal structure, infrared characterization, and electrical properties of the new Bi9 (V(1-x) P(x))2 Cl O18 series (0 <= x <= 1) _cod_database_code 1004152 _database_code_amcsd 0013948 CELL PARAMETERS: 11.6710 5.4630 14.7920 90.000 93.670 90.000 SPACE GROUP: P2_1/m X-RAY WAVELENGTH: 1.541838 Cell Volume: 941.184 Density (g/cm3): 8.136 MAX. ABS. INTENSITY / VOLUME**2: 144.3398058 RIR: 5.776 RIR based on corundum from Acta Crystallographica A38 (1982) 733-739 2-THETA INTENSITY D-SPACING H K L Multiplicity 7.59 2.82 11.6471 1 0 0 2 9.97 52.60 8.8717 1 0 1 2 11.99 1.19 7.3808 0 0 2 2 13.79 2.50 6.4231 -1 0 2 2 14.61 12.85 6.0615 1 0 2 2 17.31 2.16 5.1234 0 1 1 4 17.93 1.27 4.9460 1 1 0 4 18.77 2.51 4.7286 -1 1 1 4 18.80 2.14 4.7211 -2 0 2 2 19.08 3.25 4.6518 1 1 1 4 20.22 3.95 4.3911 0 1 2 4 21.35 8.94 4.1614 -1 1 2 4 21.90 5.44 4.0581 1 1 2 4 22.31 2.31 3.9843 2 1 0 4 23.38 1.07 3.8049 2 1 1 4 24.07 1.38 3.6969 3 0 1 2 24.12 1.86 3.6904 0 0 4 2 24.35 6.98 3.6561 0 1 3 4 24.84 2.63 3.5847 -1 0 4 2 24.93 1.02 3.5721 -2 1 2 4 25.18 26.60 3.5367 -1 1 3 4 25.89 9.17 3.4418 1 1 3 4 27.78 12.30 3.2115 -2 0 4 2 28.20 2.27 3.1650 -2 1 3 4 28.20 94.60 3.1646 3 1 0 4 28.36 2.84 3.1474 -3 0 3 2 28.54 34.33 3.1279 -3 1 1 4 29.17 29.32 3.0617 3 1 1 4 29.20 100.00 3.0580 0 1 4 4 29.47 15.62 3.0307 2 0 4 2 29.81 11.11 2.9971 -1 1 4 4 30.22 13.05 2.9572 3 0 3 2 30.62 18.93 2.9200 1 1 4 4 30.71 1.54 2.9118 4 0 0 2 30.92 2.63 2.8921 -4 0 1 2 31.33 1.72 2.8551 3 1 2 4 32.32 3.60 2.7698 -4 0 2 2 32.38 29.99 2.7646 -3 0 4 2 32.79 55.10 2.7315 0 2 0 2 33.81 2.85 2.6513 4 0 2 2 34.35 1.25 2.6106 1 2 1 4 34.49 1.62 2.6006 3 1 3 4 34.53 2.75 2.5973 0 1 5 4 34.59 12.26 2.5932 3 0 4 2 34.78 6.04 2.5793 -4 0 3 2 34.92 7.30 2.5696 4 1 0 4 35.84 1.26 2.5053 1 1 5 4 36.07 1.49 2.4903 1 2 2 4 36.37 2.75 2.4704 -4 1 2 4 36.42 1.44 2.4667 -3 1 4 4 36.86 3.34 2.4384 4 0 3 2 37.06 3.63 2.4260 -3 0 5 2 37.71 5.28 2.3852 4 1 2 4 37.86 1.07 2.3766 1 0 6 2 38.06 1.74 2.3643 -2 2 2 4 39.51 3.09 2.2807 3 0 5 2 40.37 1.09 2.2340 3 2 0 4 40.51 2.73 2.2267 4 1 3 4 40.68 1.83 2.2179 4 0 4 2 41.09 1.08 2.1969 3 2 1 4 41.30 1.75 2.1859 2 2 3 4 41.43 1.78 2.1793 1 1 6 4 41.68 1.75 2.1669 -4 1 4 4 41.83 1.08 2.1595 -5 0 3 2 42.17 1.45 2.1428 -4 0 5 2 42.32 1.01 2.1356 -2 1 6 4 42.89 3.68 2.1088 0 0 7 2 42.97 1.32 2.1047 3 1 5 4 43.10 4.80 2.0988 -1 0 7 2 43.27 1.32 2.0910 -5 1 2 4 43.49 6.70 2.0807 -2 2 4 4 43.89 2.78 2.0630 -3 2 3 4 44.13 4.40 2.0522 1 0 7 2 44.66 11.68 2.0290 2 2 4 4 44.76 2.70 2.0247 -2 0 7 2 45.11 1.09 2.0098 4 0 5 2 45.19 10.88 2.0065 3 2 3 4 45.50 1.29 1.9934 -3 1 6 4 45.53 1.58 1.9921 4 2 0 4 45.69 1.09 1.9858 -4 2 1 4 46.70 5.81 1.9449 -4 2 2 4 46.75 27.35 1.9431 -3 2 4 4 46.81 8.66 1.9407 -6 0 1 2 47.25 1.12 1.9235 5 1 3 4 47.64 5.35 1.9089 6 0 1 2 47.81 1.87 1.9025 4 2 2 4 47.81 3.87 1.9023 -5 1 4 4 48.25 1.16 1.8862 4 1 5 4 48.40 8.07 1.8807 3 2 4 4 48.55 7.37 1.8753 -4 2 3 4 49.30 1.61 1.8485 6 0 2 2 49.39 1.19 1.8452 0 0 8 2 49.52 3.97 1.8408 -1 0 8 2 49.85 3.06 1.8294 -4 1 6 4 50.15 3.74 1.8190 4 2 3 4 50.30 2.34 1.8139 -3 2 5 4 50.50 4.28 1.8074 5 1 4 4 50.58 5.23 1.8047 1 0 8 2 52.21 1.41 1.7520 -1 3 2 4 52.25 4.60 1.7507 3 2 5 4 52.30 4.29 1.7493 -6 1 3 4 52.96 2.31 1.7289 4 1 6 4 53.20 2.01 1.7218 4 2 4 4 53.46 2.20 1.7141 3 1 7 4 53.47 1.38 1.7136 1 1 8 4 53.83 11.30 1.7030 -2 1 8 4 54.10 2.45 1.6951 -1 3 3 4 54.36 1.17 1.6876 5 1 5 4 54.42 1.36 1.6860 -4 2 5 4 54.57 6.27 1.6817 6 1 3 4 54.64 2.85 1.6797 -6 1 4 4 54.73 5.60 1.6772 -4 1 7 4 55.01 1.65 1.6692 0 2 7 4 55.19 2.98 1.6642 -1 2 7 4 55.20 1.40 1.6639 7 0 0 2 55.76 12.24 1.6487 3 3 0 4 55.82 8.62 1.6471 2 1 8 4 55.95 4.29 1.6434 -3 3 1 4 56.05 3.16 1.6407 1 2 7 4 56.32 4.86 1.6336 3 3 1 4 56.34 13.36 1.6330 0 3 4 4 56.40 4.11 1.6315 -3 1 8 4 56.58 2.11 1.6266 -2 2 7 4 56.67 1.37 1.6244 3 2 6 4 56.70 2.27 1.6235 -1 3 4 4 56.88 1.97 1.6188 4 2 5 4 57.18 2.33 1.6109 1 3 4 4 57.66 6.95 1.5987 -6 1 5 4 57.89 1.29 1.5929 -7 1 1 4 57.94 2.44 1.5917 7 1 0 4 58.14 5.63 1.5868 4 1 7 4 58.32 7.09 1.5821 -6 2 1 4 58.57 2.01 1.5759 -7 1 2 4 58.79 1.27 1.5707 5 1 6 4 59.04 4.28 1.5647 6 2 1 4 59.68 1.29 1.5493 -5 1 7 4 60.22 3.46 1.5366 7 1 2 4 60.47 1.25 1.5309 6 2 2 4 60.56 1.08 1.5290 0 2 8 4 60.67 2.92 1.5265 -1 2 8 4 61.20 2.02 1.5145 6 1 5 4 61.59 4.66 1.5057 1 2 8 4 61.81 1.25 1.5010 4 3 2 4 62.07 4.04 1.4952 -7 1 4 4 62.14 2.45 1.4937 -5 0 8 2 62.41 1.54 1.4880 7 1 3 4 65.37 1.02 1.4275 6 2 4 4 65.39 1.26 1.4273 6 1 6 4 65.70 1.36 1.4211 -7 0 6 2 65.71 1.05 1.4210 7 2 0 4 65.80 1.02 1.4194 -4 1 9 4 66.64 1.13 1.4033 5 0 8 2 67.79 1.14 1.3823 -6 0 8 2 68.69 1.07 1.3665 7 1 5 4 68.73 6.39 1.3657 0 4 0 2 69.74 2.22 1.3484 4 1 9 4 70.30 1.34 1.3391 7 0 6 2 70.96 1.36 1.3282 -4 3 6 4 71.49 1.27 1.3197 5 3 4 4 72.07 2.59 1.3105 -5 2 8 4 72.53 1.11 1.3032 0 1 11 4 72.97 1.63 1.2966 -6 3 3 4 73.12 1.19 1.2942 -3 0 11 2 73.47 1.76 1.2890 -2 1 11 4 73.64 1.85 1.2863 1 1 11 4 74.24 3.36 1.2774 -2 3 8 4 74.87 2.11 1.2683 6 3 3 4 75.00 1.72 1.2664 -4 3 7 4 75.35 1.84 1.2614 -9 1 1 4 75.40 1.53 1.2607 -7 2 6 4 75.85 1.39 1.2544 -9 1 2 4 75.92 3.05 1.2533 2 3 8 4 76.28 1.38 1.2482 5 2 8 4 76.42 1.38 1.2464 -3 3 8 4 76.51 1.78 1.2452 2 4 4 4 76.89 1.07 1.2399 3 4 3 4 77.51 2.30 1.2315 -6 3 5 4 77.92 2.11 1.2261 4 3 7 4 78.01 1.03 1.2249 -4 4 2 4 78.04 3.40 1.2245 -3 4 4 4 78.42 1.61 1.2195 -2 0 12 2 79.28 1.36 1.2084 3 4 4 4 79.75 1.03 1.2025 7 3 2 4 79.76 1.19 1.2024 7 2 6 4 79.83 1.00 1.2014 -1 1 12 4 80.74 1.01 1.1901 4 0 11 2 81.07 1.49 1.1862 1 1 12 4 81.39 1.41 1.1823 -7 3 4 4 82.46 1.15 1.1697 9 1 4 4 82.47 1.74 1.1695 -3 2 11 4 87.30 2.05 1.1169 -6 4 1 4 87.63 2.08 1.1135 -2 2 12 4 87.91 1.46 1.1107 6 4 1 4 88.03 1.20 1.1095 -9 2 5 4 88.17 1.10 1.1081 5 2 10 4 89.31 1.31 1.0968 -1 4 8 4 89.50 1.63 1.0950 -5 1 12 4 89.91 1.44 1.0911 4 2 11 4 ================================================================================ XPOW Copyright 1993 Bob Downs, Ranjini Swaminathan and Kurt Bartelmehs For reference, see Downs et al. (1993) American Mineralogist 78, 1104-1107.