data_global
_amcsd_formula_title 'Bi26.4 Mo9.6 O68.4'
loop_
_publ_author_name
'Vannier R'
'Abraham F'
'Nowogrocki G'
'Mairesse G'
_journal_name_full 'Journal of Solid State Chemistry'
_journal_volume 142 
_journal_year 1999
_journal_page_first 294
_journal_page_last 304
_publ_section_title
;
 New structural and electrical data on Bi-Mo mixed oxides with a
 structure based on (B12 O14)(infinite) columns
 _cod_database_code 1004134
;
_database_code_amcsd 0013958
_chemical_formula_sum 'Bi13.2 Mo4.8 O34.2'
_cell_length_a 11.7525
_cell_length_b 5.8005
_cell_length_c 24.8024
_cell_angle_alpha 90
_cell_angle_beta 102.867
_cell_angle_gamma 90
_cell_volume 1648.333
_exptl_crystal_density_diffrn      7.588
_symmetry_space_group_name_H-M 'P 1 2/c 1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  'x,-y,1/2+z'
  '-x,y,1/2-z'
  '-x,-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
Bi1   0.04090   0.41600   0.32610   1.00000
Bi2   0.15840   0.92000   0.24560   1.00000
Bi3   0.24830   0.00800   0.40130   1.00000
Bi4   0.36070   0.50200   0.32410   1.00000
Bi5   0.26980   0.50100   0.15970   1.00000
Bi6   0.07610   0.00400   0.09080   1.00000
Bi7   0.52200   0.53600   0.00900   0.50000
Mo1   0.41620  -0.00700   0.07820   0.96000
Bi8   0.41620  -0.00700   0.07820   0.04000
Mo2   0.83290   0.51200   0.01050   0.96000
Bi9   0.83290   0.51200   0.01050   0.04000
Mo3   0.50000   0.00600   0.25000   0.96000
Bi10   0.50000   0.00600   0.25000   0.04000
O1   0.00000   0.71300   0.25000   1.00000
O2   0.14380   0.25800   0.15840   1.00000
O3   0.12640   0.75500   0.15390   1.00000
O4   0.23700   0.76600   0.33680   1.00000
O5   0.25290   0.59100   0.24240   1.00000
O6   0.06100   0.06800   0.36700   1.00000
O7   0.00000   0.22200   0.25000   1.00000
O8   0.23500   0.26500   0.33620   1.00000
O9   0.51400  -0.25400   0.08510   1.00000
O10   0.38400   0.10600   0.01000   1.00000
O11   0.30400  -0.00900   0.10800   1.00000
O12   0.53100   0.21600   0.09670   1.00000
O13   0.93200   0.29300   0.02840   1.00000
O14   0.79900   0.56100  -0.05830   1.00000
O15   0.88500   0.75700   0.04630   1.00000
O16   0.70800   0.42300   0.03770   1.00000
O17   0.37500   0.17200   0.24230   1.00000
O18   0.47800  -0.16700   0.19050   1.00000
O19   0.48500   0.39000   0.18200   0.10000