data_global
_amcsd_formula_title 'O5 Pb0.304 V2'
loop_
_publ_author_name
'Mentre O'
'Huve M'
'Abraham F'
_journal_name_full 'Journal of Solid State Chemistry'
_journal_volume 145 
_journal_year 1999
_journal_page_first 186
_journal_page_last 196
_publ_section_title
;
 Bidimensional cationic ordering and thermal dependence
 in beta- Pb(x)V2O5 bronzes
 _cod_database_code 1004148
;
_database_code_amcsd 0013976
_chemical_formula_sum 'Pb.608 V4 O10'
_cell_length_a 15.478
_cell_length_b 7.288
_cell_length_c 10.123
_cell_angle_alpha 90
_cell_angle_beta 109.29
_cell_angle_gamma 90
_cell_volume 1077.803
_exptl_crystal_density_diffrn      4.527
_symmetry_space_group_name_H-M 'P 1 21/m 1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  'x,1/2-y,z'
  '-x,1/2+y,-z'
  '-x,-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
Pb1   0.50400   0.00320   0.39480   0.46600
Pb2   0.00453   0.75000   0.39440   0.89200
V1   0.83140   0.50120   0.09640   1.00000
V2   0.33910   0.75000   0.10080   1.00000
V3   0.33810   0.25000   0.09840   1.00000
V4   0.61150   0.49920   0.11120   1.00000
V5   0.12130   0.75000   0.11550   1.00000
V6   0.12590   0.25000   0.12600   1.00000
V7   0.78000   0.50170   0.40360   1.00000
V8   0.28740   0.75000   0.41120   1.00000
V9   0.29060   0.25000   0.41440   1.00000
O1  -0.00020   0.25000  -0.00500   1.00000
O2   0.50000   0.00000   0.00000   1.00000
O3   0.31500   0.00100   0.05400   1.00000
O4   0.80700   0.75000   0.04600   1.00000
O5   0.81500   0.25000   0.04500   1.00000
O6   0.13000   0.00300   0.07500   1.00000
O7   0.63700   0.75000   0.08000   1.00000
O8   0.63700   0.25000   0.07900   1.00000
O9   0.93900  -0.01000   0.21700   1.00000
O10   0.43200   0.75000   0.21500   1.00000
O11   0.43000   0.25000   0.21500   1.00000
O12   0.76000   0.00300   0.22200   1.00000
O13   0.26700   0.75000   0.22100   1.00000
O14   0.26400   0.25000   0.22200   1.00000
O15   0.61400   0.00300   0.27800   1.00000
O16   0.10800   0.75000   0.26900   1.00000
O17   0.10100   0.25000   0.26500   1.00000
O18   0.25100   0.00000   0.42300   1.00000
O19   0.75600   0.75000   0.42100   1.00000
O20   0.76600   0.25000   0.43100   1.00000
O21   0.89200   0.01400   0.46800   1.00000
O22   0.39500   0.75000   0.47100   1.00000
O23   0.39700   0.25000   0.47200   1.00000