Pb3.45Sb2.55S6.55Cl1.45 Doussier C, Moelo Y, Meerschaut A, Leone P, Guillot-Deudon C Journal of Solid State Chemistry 181 (2008) 920-934 Crystal structure of the new compound Pb3+xSb3 xS7 xCl1+x(x~0.45): The homologous series Pb(2+2N)(Sb,Pb)(2+2N)S(2+2N)(S,Cl)(4+2N)ClN and its polychalcogenide derivatives (N = 1-3) Locality: synthetic _database_code_amcsd 0019220 CELL PARAMETERS: 15.1940 23.0350 4.0591 90.000 90.000 90.000 SPACE GROUP: Pbam X-RAY WAVELENGTH: 1.541838 Cell Volume: 1420.660 Density (g/cm3): 6.015 MAX. ABS. INTENSITY / VOLUME**2: 118.0439016 RIR: 6.390 RIR based on corundum from Acta Crystallographica A38 (1982) 733-739 2-THETA INTENSITY D-SPACING H K L Multiplicity 9.64 100.00 9.1785 1 2 0 4 12.27 29.13 7.2148 2 1 0 4 13.96 5.67 6.3417 2 2 0 4 16.41 8.62 5.4004 2 3 0 4 16.46 18.77 5.3849 1 4 0 4 19.14 8.99 4.6362 3 2 0 4 19.34 2.91 4.5893 2 4 0 4 20.14 2.38 4.4088 1 5 0 4 21.01 17.69 4.2278 3 3 0 4 21.90 33.29 4.0591 0 0 1 2 22.57 11.46 3.9393 2 5 0 4 23.01 8.16 3.8659 1 1 1 8 23.17 7.35 3.8392 0 6 0 2 23.74 2.85 3.7479 4 1 0 4 23.91 25.46 3.7222 1 6 0 4 23.97 67.17 3.7123 1 2 1 8 24.68 1.01 3.6074 4 2 0 4 24.87 12.59 3.5801 2 0 1 4 25.50 18.97 3.4924 1 3 1 8 26.00 1.24 3.4265 2 6 0 4 26.06 1.99 3.4188 2 2 1 8 26.17 31.73 3.4047 4 3 0 4 26.87 19.05 3.3178 0 4 1 4 27.49 2.87 3.2447 2 3 1 8 27.52 7.09 3.2414 1 4 1 8 27.74 6.34 3.2161 1 7 0 4 28.44 2.25 3.1379 3 1 1 8 29.24 1.38 3.0540 3 2 1 8 29.38 4.34 3.0405 2 4 1 8 29.58 4.48 3.0196 2 7 0 4 29.92 3.00 2.9862 1 5 1 8 30.42 4.56 2.9383 5 2 0 4 30.53 20.10 2.9280 3 3 1 8 31.67 17.39 2.8256 5 3 0 4 32.09 20.24 2.7892 0 6 1 4 32.26 3.45 2.7753 3 4 1 8 32.52 24.12 2.7536 4 1 1 8 32.64 4.91 2.7434 1 6 1 8 33.23 2.91 2.6964 4 2 1 8 33.28 3.89 2.6925 2 8 0 4 33.34 3.52 2.6876 5 4 0 4 34.25 1.30 2.6183 2 6 1 8 34.38 6.22 2.6085 4 3 1 8 36.11 3.72 2.4872 4 7 0 4 36.79 11.35 2.4432 3 6 1 8 37.06 2.41 2.4255 2 9 0 4 37.17 4.03 2.4192 5 1 1 8 37.80 1.34 2.3801 5 2 1 8 37.86 8.28 2.3761 4 5 1 8 38.33 7.51 2.3485 0 8 1 4 38.83 1.32 2.3190 5 3 1 8 39.45 8.35 2.2843 3 9 0 4 39.49 1.37 2.2820 3 7 1 8 40.24 2.08 2.2409 5 4 1 8 40.66 2.33 2.2192 6 5 0 4 42.05 4.30 2.1485 6 0 1 4 42.16 4.45 2.1433 1 9 1 8 42.37 5.39 2.1330 7 2 0 4 42.59 3.53 2.1226 4 9 0 4 42.63 15.56 2.1207 4 7 1 8 43.14 8.05 2.0968 3 10 0 4 43.46 17.39 2.0821 2 9 1 8 44.07 4.61 2.0549 5 6 1 8 44.65 18.22 2.0296 0 0 2 2 44.90 2.81 2.0188 2 11 0 4 45.04 2.74 2.0130 6 4 1 8 45.18 1.16 2.0069 6 7 0 4 45.57 5.54 1.9907 3 9 1 8 45.79 2.99 1.9817 1 2 2 8 46.38 3.72 1.9576 5 9 0 4 46.48 1.88 1.9537 2 1 2 8 46.95 1.60 1.9352 3 11 0 4 47.36 1.54 1.9196 0 12 0 2 47.68 1.03 1.9075 7 1 1 8 47.83 2.63 1.9016 6 8 0 4 47.90 7.98 1.8993 8 0 0 2 47.90 1.36 1.8991 1 4 2 8 48.16 2.40 1.8895 7 6 0 4 48.19 5.65 1.8882 7 2 1 8 48.94 1.06 1.8611 2 12 0 4 48.99 1.43 1.8592 3 2 2 8 49.02 1.07 1.8582 5 8 1 8 49.05 1.71 1.8573 7 3 1 8 49.66 2.98 1.8357 5 10 0 4 49.84 3.10 1.8297 3 3 2 8 50.36 1.11 1.8119 7 7 0 4 50.59 2.13 1.8042 2 5 2 8 50.71 1.08 1.8001 6 9 0 4 50.89 1.04 1.7943 0 6 2 4 51.27 5.78 1.7819 1 6 2 8 51.72 1.37 1.7676 7 5 1 8 51.85 3.73 1.7633 5 9 1 8 51.96 1.74 1.7600 1 13 0 4 52.38 2.32 1.7468 3 11 1 8 52.49 7.93 1.7433 4 3 2 8 53.25 7.04 1.7203 8 0 1 4 53.38 1.56 1.7164 1 7 2 8 53.49 5.09 1.7130 7 6 1 8 53.85 2.53 1.7023 8 6 0 4 54.22 7.44 1.6917 2 12 1 8 54.47 1.17 1.6844 2 7 2 8 54.94 2.62 1.6712 4 11 1 8 54.99 1.32 1.6699 5 2 2 8 55.77 5.39 1.6484 5 3 2 8 55.77 3.27 1.6483 8 4 1 8 55.87 2.58 1.6456 6 9 1 8 56.81 1.44 1.6207 2 8 2 8 56.85 1.12 1.6196 5 4 2 8 57.38 1.16 1.6058 4 13 0 4 57.85 1.07 1.5940 7 8 1 8 58.12 3.18 1.5871 5 11 1 8 58.72 1.07 1.5725 4 7 2 8 58.82 1.54 1.5699 8 6 1 8 59.43 1.18 1.5552 9 1 1 8 59.85 1.33 1.5454 9 6 0 4 59.88 3.03 1.5447 9 2 1 8 60.39 1.37 1.5328 7 9 1 8 61.08 1.83 1.5172 1 14 1 8 61.08 3.52 1.5172 3 9 2 8 61.76 1.78 1.5021 9 7 0 4 61.96 1.06 1.4977 6 5 2 8 62.94 2.53 1.4768 8 8 1 8 63.24 2.30 1.4703 7 2 2 8 63.41 1.76 1.4669 4 9 2 8 63.83 3.63 1.4583 3 10 2 8 65.17 3.82 1.4315 6 12 1 8 65.18 1.48 1.4313 2 11 2 8 66.22 1.88 1.4113 2 15 1 8 66.34 2.03 1.4090 5 9 2 8 67.12 1.07 1.3946 0 12 2 4 67.50 1.55 1.3876 6 8 2 8 67.55 4.11 1.3868 8 0 2 4 67.76 1.53 1.3829 7 6 2 8 68.98 1.61 1.3614 5 10 2 8 70.33 1.76 1.3386 1 2 3 8 72.47 1.30 1.3043 8 6 2 8 74.39 1.12 1.2752 1 18 0 4 74.57 1.14 1.2726 4 1 3 8 76.61 2.19 1.2437 10 9 1 8 77.66 1.09 1.2295 9 6 2 8 78.64 1.07 1.2166 1 18 1 8 79.36 1.23 1.2074 9 7 2 8 80.88 1.20 1.1885 4 7 3 8 81.45 1.50 1.1816 2 9 3 8 85.79 1.05 1.1326 5 18 1 8 86.60 1.05 1.1241 8 12 2 8 89.57 1.28 1.0944 2 12 3 8 ================================================================================ XPOW Copyright 1993 Bob Downs, Ranjini Swaminathan and Kurt Bartelmehs For reference, see Downs et al. (1993) American Mineralogist 78, 1104-1107.