data_global _amcsd_formula_title 'Cl9 Cs3 Tl2' loop_ _publ_author_name 'Powell H' 'Wells A' _journal_name_full 'Journal of the Chemical Society' _journal_volume 1935 _journal_year 1935 _journal_page_first 1008 _journal_page_last 1012 _publ_section_title ; Complex-anion Formation by Tervalent Elements: The Structure of Caesium Thallic Enneachloride _cod_database_code 1010209 ; _database_code_amcsd 0017145 _chemical_formula_sum 'Cs3 Cl6 Tl' _cell_length_a 9.58 _cell_length_b 9.58 _cell_length_c 9.58 _cell_angle_alpha 83.93 _cell_angle_beta 83.93 _cell_angle_gamma 83.93 _cell_volume 865.402 _exptl_crystal_density_diffrn 6.262 _symmetry_space_group_name_H-M 'R -3 c' loop_ _space_group_symop_operation_xyz 'x,y,z' '1/2-x,1/2-z,1/2-y' '-z,-x,-y' '1/2+y,1/2+x,1/2+z' 'y,z,x' '1/2-z,1/2-y,1/2-x' '-x,-y,-z' '1/2+x,1/2+z,1/2+y' 'z,x,y' '1/2-y,1/2-x,1/2-z' '-y,-z,-x' '1/2+z,1/2+y,1/2+x' loop_ _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z Cs1 0.66670 -0.66670 0.00000 Cl1 0.16670 -0.16670 0.00000 Cl2 0.33330 0.16670 0.00000 Tl1 0.10000 0.10000 0.10000