data_global
_chemical_name_mineral 'Ferronigerite-2N1S'
loop_
_publ_author_name
'Arakcheeva A V'
'Pushcharovskii D Y'
'Rastsvetaeva R K'
'Kashaev A A'
'Nadezhina T N'
_journal_name_full 'Kristallografiya'
_journal_volume 40 
_journal_year 1995
_journal_page_first 639
_journal_page_last 644
_publ_section_title
;
 Crystal structure of nigerite-6H
;
_database_code_amcsd 0018796
_chemical_compound_source 'Eastern Siberia, Irkutsk, Russia'
_chemical_formula_sum 'Al8.435 Fe.83 Zn.36 Sn O15 H'
_cell_length_a 5.717
_cell_length_b 5.717
_cell_length_c 13.80
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 120
_cell_volume 390.612
_exptl_crystal_density_diffrn      5.588
_symmetry_space_group_name_H-M 'P -3 m 1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '-y,-x,z'
  'y,-x+y,-z'
  '-x,-x+y,-z'
  '-x+y,-x,z'
  '-x+y,y,z'
  '-x,-y,-z'
  'y,x,-z'
  '-y,x-y,z'
  'x,x-y,z'
  'x-y,x,-z'
  'x-y,-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
AlM1   0.00000   0.00000   0.50000   1.00000   0.00443
AlM2   0.16910   0.33770   0.33060   1.00000   0.00456
AlT1   0.66667   0.33333   0.45380   0.20000   0.00646
FeT1   0.66667   0.33333   0.45380   0.44000   0.00646
ZnT1   0.66667   0.33333   0.45380   0.36000   0.00646
AlT2   0.00000   0.00000   0.12350   0.61000   0.00532
FeT2   0.00000   0.00000   0.12350   0.39000   0.00532
AlM3   0.50000   0.00000   0.00000   0.75000   0.00773
Sn   0.66667   0.33333   0.18720   1.00000   0.00507
O1   0.29380   0.14710   0.41280   1.00000   0.00811
O2   0.33333   0.66667   0.40270   1.00000   0.00659
O3   0.00000   0.00000   0.25920   1.00000   0.00545
O4   0.01210   0.50610   0.26040   1.00000   0.00659
O5   0.33333   0.66667   0.07010   1.00000   0.00785
O6   0.35180   0.17590   0.08460   1.00000   0.01254
H   0.33333   0.66667   0.14000   1.00000   0.01267