As5 K6 Sn3 Klein J, Eisenmann B Materials Research Bulletin 23 (1988) 587-594 Zintl-Phasen mit komplexen Anionen: Darstellung und Einkristallstrukturbestimmung von KSnAs und K6Sn3As5 _cod_database_code 1008519 _database_code_amcsd 0016412 CELL PARAMETERS: 14.8000 10.7280 10.9340 90.000 90.000 90.000 SPACE GROUP: Pmmn X-RAY WAVELENGTH: 1.541838 Cell Volume: 1736.039 Density (g/cm3): 3.693 MAX. ABS. INTENSITY / VOLUME**2: 20.28835357 RIR: 1.789 RIR based on corundum from Acta Crystallographica A38 (1982) 733-739 2-THETA INTENSITY D-SPACING H K L Multiplicity 8.09 6.82 10.9340 0 0 1 2 10.06 52.70 8.7943 1 0 1 4 10.18 31.25 8.6861 1 1 0 4 11.56 1.95 7.6576 0 1 1 4 11.96 34.94 7.4000 2 0 0 2 13.02 47.35 6.8012 1 1 1 8 14.45 11.20 6.1284 2 0 1 4 16.53 8.55 5.3640 0 2 0 2 16.66 13.31 5.3213 2 1 1 8 17.29 87.12 5.1283 1 0 2 4 18.21 13.38 4.8710 0 1 2 4 18.42 24.82 4.8157 0 2 1 4 19.18 5.76 4.6268 1 1 2 8 19.74 1.35 4.4968 3 0 1 4 19.81 58.27 4.4821 3 1 0 4 21.84 7.46 4.0687 2 1 2 8 22.02 6.64 4.0363 2 2 1 8 23.23 5.49 3.8288 0 2 2 4 24.01 3.97 3.7068 1 2 2 8 24.05 2.05 3.7000 4 0 0 2 24.30 1.76 3.6626 3 0 2 4 25.63 9.72 3.4760 1 3 0 4 25.82 13.76 3.4510 0 1 3 4 26.21 11.89 3.4006 2 2 2 8 26.22 1.38 3.3988 0 3 1 4 26.76 10.51 3.3315 4 1 1 8 28.54 5.73 3.1276 2 1 3 8 28.91 14.56 3.0886 2 3 1 8 29.14 10.24 3.0642 4 0 2 4 29.32 3.66 3.0457 4 2 0 4 29.53 39.88 3.0247 3 2 2 8 29.63 6.79 3.0146 0 2 3 4 29.86 6.40 2.9926 0 3 2 4 30.26 100.00 2.9540 1 2 3 8 30.34 64.50 2.9464 4 1 2 8 30.47 10.34 2.9340 4 2 1 8 30.47 9.18 2.9333 1 3 2 8 30.49 26.07 2.9314 3 0 3 4 30.88 8.35 2.8954 3 3 0 4 31.35 25.34 2.8534 5 1 0 4 31.64 1.70 2.8278 3 1 3 8 31.98 90.31 2.7989 3 3 1 8 32.27 26.17 2.7744 2 3 2 8 32.43 5.63 2.7609 5 1 1 8 32.76 22.72 2.7335 0 0 4 2 33.33 5.70 2.6880 1 0 4 4 33.41 30.05 2.6820 0 4 0 2 33.69 6.11 2.6607 4 2 2 8 33.84 3.63 2.6489 0 1 4 4 34.43 3.08 2.6048 0 4 1 4 34.88 7.36 2.5724 3 2 3 8 35.07 7.75 2.5587 3 3 2 8 35.49 6.64 2.5296 5 1 2 8 35.57 14.20 2.5236 4 1 3 8 35.69 2.89 2.5154 1 3 3 8 35.88 14.73 2.5031 4 3 1 8 36.42 14.56 2.4667 6 0 0 2 36.91 2.82 2.4355 0 2 4 4 37.26 12.54 2.4130 2 3 3 8 37.35 1.06 2.4079 0 4 2 4 37.37 2.91 2.4062 6 0 1 4 37.42 10.78 2.4032 1 2 4 8 38.34 8.60 2.3479 6 1 1 8 38.44 23.23 2.3418 5 2 2 8 38.58 3.15 2.3337 3 1 4 8 38.93 8.38 2.3134 2 2 4 8 39.21 3.63 2.2977 5 0 3 4 39.35 2.77 2.2897 2 4 2 8 39.52 5.50 2.2802 5 3 0 4 39.76 7.03 2.2671 3 3 3 8 40.10 2.39 2.2484 6 0 2 4 40.24 15.52 2.2411 6 2 0 4 40.41 7.34 2.2322 5 3 1 8 41.01 2.28 2.2006 6 1 2 8 41.59 5.13 2.1717 0 3 4 4 41.59 2.47 2.1715 4 4 0 4 41.74 6.41 2.1639 3 4 2 8 41.75 1.79 2.1633 1 0 5 4 41.82 1.02 2.1602 0 4 3 4 41.95 2.77 2.1538 4 1 4 8 42.17 5.23 2.1427 0 1 5 4 42.28 14.75 2.1375 1 4 3 8 42.58 1.42 2.1234 1 5 0 4 42.63 8.58 2.1206 1 1 5 8 42.82 7.04 2.1121 5 2 3 8 42.98 5.62 2.1045 5 3 2 8 43.05 64.62 2.1011 4 3 3 8 43.14 1.92 2.0971 2 0 5 4 43.41 1.08 2.0845 1 5 1 8 43.43 1.54 2.0838 2 3 4 8 44.75 2.67 2.0251 2 5 1 8 44.75 2.02 2.0250 0 2 5 4 44.91 2.78 2.0181 4 4 2 8 45.19 2.77 2.0063 1 2 5 8 45.36 2.45 1.9992 3 0 5 4 45.41 9.21 1.9973 0 5 2 4 45.43 1.42 1.9963 6 3 1 8 45.86 4.63 1.9788 3 4 3 8 46.03 8.01 1.9720 7 0 2 4 46.13 4.56 1.9676 3 5 0 4 46.92 3.87 1.9365 3 5 1 8 46.93 7.35 1.9359 7 2 1 8 47.01 2.47 1.9331 5 3 3 8 47.63 1.86 1.9090 6 2 3 8 48.35 2.87 1.8826 4 0 5 4 48.60 1.41 1.8733 3 2 5 8 48.75 9.09 1.8679 5 4 2 8 48.82 1.18 1.8656 0 3 5 4 49.13 3.40 1.8542 4 1 5 8 49.16 4.01 1.8534 2 4 4 8 49.23 2.13 1.8510 1 3 5 8 49.25 16.36 1.8500 8 0 0 2 49.28 2.37 1.8490 0 5 3 4 49.79 7.98 1.8313 6 0 4 4 49.83 5.43 1.8299 4 5 1 8 50.05 15.02 1.8223 0 0 6 2 50.46 5.06 1.8087 1 0 6 4 50.90 2.36 1.7938 2 5 3 8 51.08 20.43 1.7880 0 6 0 2 51.44 3.36 1.7764 4 2 5 8 51.52 10.49 1.7738 6 3 3 8 51.99 1.71 1.7589 5 0 5 4 52.03 23.44 1.7576 4 5 2 8 52.21 1.39 1.7522 1 6 1 8 52.24 1.73 1.7510 5 3 4 8 52.44 36.15 1.7450 3 3 5 8 52.44 1.56 1.7449 5 4 3 8 52.66 2.40 1.7380 2 6 0 4 52.69 4.80 1.7372 5 5 0 4 52.82 1.75 1.7331 6 2 4 8 52.89 25.97 1.7310 7 2 3 8 52.94 2.15 1.7295 8 1 2 8 53.03 1.99 1.7270 8 2 1 8 53.40 2.86 1.7157 5 5 1 8 54.11 2.67 1.6948 0 4 5 4 54.34 8.27 1.6883 1 6 2 8 54.34 3.04 1.6881 3 1 6 8 54.50 1.75 1.6838 1 4 5 8 54.90 4.41 1.6724 7 0 4 4 54.94 1.71 1.6713 5 2 5 8 55.13 1.71 1.6658 4 3 5 8 55.50 1.65 1.6556 5 5 2 8 55.56 1.53 1.6540 4 5 3 8 55.62 1.22 1.6524 7 1 4 8 56.02 2.68 1.6416 7 4 1 8 56.21 1.27 1.6363 6 0 5 4 56.98 3.06 1.6161 4 1 6 8 57.30 4.98 1.6078 9 1 1 8 57.50 1.08 1.6029 3 4 5 8 57.55 1.77 1.6014 6 5 1 8 57.73 1.22 1.5969 3 5 4 8 57.74 1.60 1.5966 7 2 4 8 57.77 1.61 1.5959 1 6 3 8 58.48 5.10 1.5783 5 3 5 8 58.54 1.46 1.5768 8 2 3 8 58.62 2.08 1.5747 9 0 2 4 59.02 1.63 1.5651 6 2 5 8 59.15 1.32 1.5620 0 0 7 2 59.51 1.27 1.5534 1 0 7 4 59.56 4.45 1.5522 6 5 2 8 59.57 1.11 1.5518 5 0 6 4 59.89 1.93 1.5443 4 6 2 8 60.04 1.89 1.5409 4 4 5 8 60.26 1.92 1.5358 5 1 6 8 60.27 1.38 1.5356 4 5 4 8 60.42 4.87 1.5321 8 0 4 4 60.45 2.16 1.5315 0 5 5 4 60.80 1.06 1.5234 1 5 5 8 60.83 2.74 1.5229 8 4 0 4 61.36 3.66 1.5110 7 4 3 8 61.36 1.02 1.5110 9 2 2 8 61.41 1.93 1.5098 1 7 1 8 61.52 3.27 1.5073 0 4 6 4 61.90 1.62 1.4989 9 0 3 4 62.02 3.41 1.4963 0 6 4 4 62.22 1.28 1.4921 1 2 7 8 62.36 1.36 1.4891 3 0 7 4 62.41 1.19 1.4880 6 3 5 8 62.99 1.05 1.4757 0 7 2 4 63.22 1.16 1.4708 5 4 5 8 63.47 1.43 1.4657 6 0 6 4 63.57 3.13 1.4636 3 7 0 4 63.61 5.40 1.4627 3 5 5 8 64.14 1.24 1.4519 7 5 2 8 64.20 1.88 1.4506 3 7 1 8 64.35 1.63 1.4477 6 6 0 4 64.79 2.27 1.4390 4 0 7 4 64.98 1.06 1.4352 6 6 1 8 65.00 1.26 1.4349 3 2 7 8 65.17 1.04 1.4314 0 3 7 4 65.42 3.43 1.4267 10 2 0 4 66.02 1.61 1.4151 4 5 5 8 66.08 3.06 1.4139 6 2 6 8 66.23 1.71 1.4111 5 6 3 8 66.54 2.02 1.4054 2 3 7 8 67.90 3.91 1.3804 7 0 6 4 68.48 1.62 1.3701 5 1 7 8 69.01 2.09 1.3610 5 7 0 4 69.01 1.47 1.3610 1 0 8 4 69.05 1.17 1.3602 5 5 5 8 69.05 1.18 1.3602 10 1 3 8 69.22 2.79 1.3572 8 5 2 8 69.24 4.56 1.3569 10 3 1 8 69.64 1.10 1.3501 1 1 8 8 70.43 2.12 1.3370 3 5 6 8 70.55 4.04 1.3350 4 3 7 8 70.68 1.02 1.3327 3 6 5 8 71.06 3.19 1.3266 10 3 2 8 71.18 4.53 1.3246 7 6 2 8 71.48 3.10 1.3198 4 7 3 8 71.53 1.27 1.3190 7 5 4 8 72.11 1.35 1.3098 6 1 7 8 72.20 1.83 1.3085 9 4 3 8 72.45 5.88 1.3045 9 1 5 8 72.72 1.47 1.3004 4 5 6 8 72.86 3.52 1.2983 8 0 6 4 73.00 3.67 1.2960 9 5 1 8 73.22 1.65 1.2926 6 7 1 8 73.55 1.48 1.2878 7 3 6 8 73.69 6.04 1.2857 8 6 0 4 74.04 1.44 1.2803 10 3 3 8 74.11 2.50 1.2793 6 6 4 8 74.32 5.50 1.2763 0 6 6 4 74.54 2.40 1.2730 4 1 8 8 74.61 1.47 1.2720 1 3 8 8 74.64 2.22 1.2716 1 6 6 8 75.29 3.07 1.2622 11 0 3 4 75.50 1.37 1.2592 3 8 2 8 75.58 2.13 1.2581 2 3 8 8 75.87 4.87 1.2540 1 8 3 8 75.98 1.18 1.2525 4 8 1 8 76.08 6.99 1.2510 11 3 1 8 76.12 3.71 1.2506 1 7 5 8 76.38 3.22 1.2470 4 2 8 8 78.13 4.85 1.2232 7 2 7 8 78.27 1.56 1.2214 7 6 4 8 78.67 2.11 1.2163 3 7 5 8 79.24 2.47 1.2089 5 2 8 8 79.38 1.55 1.2071 6 6 5 8 79.95 1.37 1.2000 1 8 4 8 79.98 1.82 1.1996 11 1 4 8 80.59 2.59 1.1921 5 8 2 8 80.74 1.34 1.1902 11 3 3 8 80.83 1.19 1.1891 10 5 2 8 80.90 1.09 1.1883 2 8 4 8 81.74 1.82 1.1782 6 8 0 4 82.36 1.03 1.1709 10 4 4 8 83.00 2.44 1.1634 8 6 4 8 83.17 1.09 1.1615 5 5 7 8 83.36 1.21 1.1594 12 3 1 8 83.46 1.00 1.1582 5 8 3 8 83.59 1.86 1.1567 4 4 8 8 83.70 1.27 1.1554 10 5 3 8 83.94 1.18 1.1527 0 5 8 4 83.99 1.44 1.1522 3 9 1 8 84.91 2.42 1.1420 11 4 3 8 85.09 1.18 1.1401 10 6 0 4 86.38 1.01 1.1264 7 8 1 8 86.40 1.64 1.1262 5 4 8 8 86.60 1.18 1.1241 6 5 7 8 86.67 1.20 1.1234 10 2 6 8 86.89 1.05 1.1210 4 6 7 8 86.92 5.79 1.1207 9 5 5 8 86.97 3.99 1.1203 3 3 9 8 87.93 2.94 1.1105 12 3 3 8 88.93 3.06 1.1006 4 5 8 8 88.96 1.43 1.1003 12 2 4 8 89.15 1.80 1.0985 4 3 9 8 89.67 1.84 1.0934 0 0 10 2 89.75 2.76 1.0926 7 6 6 8 89.79 1.25 1.0922 4 8 5 8 89.89 5.12 1.0913 11 3 5 8 89.90 1.90 1.0912 13 2 2 8 ================================================================================ XPOW Copyright 1993 Bob Downs, Ranjini Swaminathan and Kurt Bartelmehs For reference, see Downs et al. (1993) American Mineralogist 78, 1104-1107.