Camaraite Camara F, Sokolova E, Nieto F Mineralogical Magazine 73 (2009) 855-870 Camaraite, Ba3NaTi4(Fe2+,Mn)8(Si2O7)4O4(OH,F)7. II. The crystal structure and crystal chemistry of a new group-II Ti-disilicate mineral Locality: the Verkhnee Espe alkaline deposit, Akjailyautas Mountains, Kazakhstan _database_code_amcsd 0014596 10.6965 13.7861 21.478 99.345 92.315 89.993 C-1 atom x y z occ Uiso U(1,1) U(2,2) U(3,3) U(1,2) U(1,3) U(2,3) Fe2+MO1 .43483 .93864 .74206 .55 .0116 .0078 .0135 .0140 -.0021 -.0030 .0049 Fe3+MO1 .43483 .93864 .74206 .08 .0116 .0078 .0135 .0140 -.0021 -.0030 .0049 MnMO1 .43483 .93864 .74206 .32 .0116 .0078 .0135 .0140 -.0021 -.0030 .0049 MgMO1 .43483 .93864 .74206 .01 .0116 .0078 .0135 .0140 -.0021 -.0030 .0049 ZrMO1 .43483 .93864 .74206 .01 .0116 .0078 .0135 .0140 -.0021 -.0030 .0049 CaMO1 .43483 .93864 .74206 .01 .0116 .0078 .0135 .0140 -.0021 -.0030 .0049 Fe2+MO2 .43694 .18505 .74447 .55 .0106 .0082 .0102 .0132 .0011 -.0007 .0019 Fe3+MO2 .43694 .18505 .74447 .08 .0106 .0082 .0102 .0132 .0011 -.0007 .0019 MnMO2 .43694 .18505 .74447 .32 .0106 .0082 .0102 .0132 .0011 -.0007 .0019 MgMO2 .43694 .18505 .74447 .01 .0106 .0082 .0102 .0132 .0011 -.0007 .0019 ZrMO2 .43694 .18505 .74447 .01 .0106 .0082 .0102 .0132 .0011 -.0007 .0019 CaMO2 .43694 .18505 .74447 .01 .0106 .0082 .0102 .0132 .0011 -.0007 .0019 Fe2+MO3 .18444 .31156 .73935 .55 .0097 .0080 .0099 .0110 .0003 -.0008 .0018 Fe3+MO3 .18444 .31156 .73935 .08 .0097 .0080 .0099 .0110 .0003 -.0008 .0018 MnMO3 .18444 .31156 .73935 .32 .0097 .0080 .0099 .0110 .0003 -.0008 .0018 MgMO3 .18444 .31156 .73935 .01 .0097 .0080 .0099 .0110 .0003 -.0008 .0018 ZrMO3 .18444 .31156 .73935 .01 .0097 .0080 .0099 .0110 .0003 -.0008 .0018 CaMO3 .18444 .31156 .73935 .01 .0097 .0080 .0099 .0110 .0003 -.0008 .0018 Fe2+MO4 .68883 .06102 .74836 .55 .0094 .0083 .0095 .0105 -.0001 -.0005 .0017 Fe3+MO4 .68883 .06102 .74836 .08 .0094 .0083 .0095 .0105 -.0001 -.0005 .0017 MnMO4 .68883 .06102 .74836 .32 .0094 .0083 .0095 .0105 -.0001 -.0005 .0017 MgMO4 .68883 .06102 .74836 .01 .0094 .0083 .0095 .0105 -.0001 -.0005 .0017 ZrMO4 .68883 .06102 .74836 .01 .0094 .0083 .0095 .0105 -.0001 -.0005 .0017 CaMO4 .68883 .06102 .74836 .01 .0094 .0083 .0095 .0105 -.0001 -.0005 .0017 Fe2+MO5 .43850 .43667 .74667 .55 .0120 .0076 .0142 .0152 -.0024 -.0035 .0068 Fe3+MO5 .43850 .43667 .74667 .08 .0120 .0076 .0142 .0152 -.0024 -.0035 .0068 MnMO5 .43850 .43667 .74667 .32 .0120 .0076 .0142 .0152 -.0024 -.0035 .0068 MgMO5 .43850 .43667 .74667 .01 .0120 .0076 .0142 .0152 -.0024 -.0035 .0068 ZrMO5 .43850 .43667 .74667 .01 .0120 .0076 .0142 .0152 -.0024 -.0035 .0068 CaMO5 .43850 .43667 .74667 .01 .0120 .0076 .0142 .0152 -.0024 -.0035 .0068 Fe2+MO6 .93645 .18536 .74390 .55 .0161 .0091 .0157 .0207 .0034 -.0060 -.0039 Fe3+MO6 .93645 .18536 .74390 .08 .0161 .0091 .0157 .0207 .0034 -.0060 -.0039 MnMO6 .93645 .18536 .74390 .32 .0161 .0091 .0157 .0207 .0034 -.0060 -.0039 MgMO6 .93645 .18536 .74390 .01 .0161 .0091 .0157 .0207 .0034 -.0060 -.0039 ZrMO6 .93645 .18536 .74390 .01 .0161 .0091 .0157 .0207 .0034 -.0060 -.0039 CaMO6 .93645 .18536 .74390 .01 .0161 .0091 .0157 .0207 .0034 -.0060 -.0039 Fe2+MO7 .18740 .06414 .74976 .55 .0091 .0072 .0103 .0096 .0005 -.0002 .0013 Fe3+MO7 .18740 .06414 .74976 .08 .0091 .0072 .0103 .0096 .0005 -.0002 .0013 MnMO7 .18740 .06414 .74976 .32 .0091 .0072 .0103 .0096 .0005 -.0002 .0013 MgMO7 .18740 .06414 .74976 .01 .0091 .0072 .0103 .0096 .0005 -.0002 .0013 ZrMO7 .18740 .06414 .74976 .01 .0091 .0072 .0103 .0096 .0005 -.0002 .0013 CaMO7 .18740 .06414 .74976 .01 .0091 .0072 .0103 .0096 .0005 -.0002 .0013 Fe2+MO8 .18618 .80846 .73804 .55 .0101 .0077 .0106 .0119 -.0002 -.0006 .0017 Fe3+MO8 .18618 .80846 .73804 .08 .0101 .0077 .0106 .0119 -.0002 -.0006 .0017 MnMO8 .18618 .80846 .73804 .32 .0101 .0077 .0106 .0119 -.0002 -.0006 .0017 MgMO8 .18618 .80846 .73804 .01 .0101 .0077 .0106 .0119 -.0002 -.0006 .0017 ZrMO8 .18618 .80846 .73804 .01 .0101 .0077 .0106 .0119 -.0002 -.0006 .0017 CaMO8 .18618 .80846 .73804 .01 .0101 .0077 .0106 .0119 -.0002 -.0006 .0017 TiMH1 .13405 .91975 .10904 .93 .0087 .0046 .0152 .0068 -.0005 -.0004 .0032 NbMH1 .13405 .91975 .10904 .06 .0087 .0046 .0152 .0068 -.0005 -.0004 .0032 AlMH1 .13405 .91975 .10904 .01 .0087 .0046 .0152 .0068 -.0005 -.0004 .0032 TiMH2 .36611 .11651 .88994 .93 .0092 .0049 .0156 .0066 -.0001 -.0005 .0002 NbMH2 .36611 .11651 .88994 .06 .0092 .0049 .0156 .0066 -.0001 -.0005 .0002 AlMH2 .36611 .11651 .88994 .01 .0092 .0049 .0156 .0066 -.0001 -.0005 .0002 TiMH3 .50856 .79405 .59882 .93 .0048 .0025 .0081 .0034 -.0002 -.0009 .0003 NbMH3 .50856 .79405 .59882 .06 .0048 .0025 .0081 .0034 -.0002 -.0009 .0003 AlMH3 .50856 .79405 .59882 .01 .0048 .0025 .0081 .0034 -.0002 -.0009 .0003 TiMH4 .00852 .75532 .59945 .93 .0038 .0032 .0051 .0029 .0001 -.0009 .0001 NbMH4 .00852 .75532 .59945 .06 .0038 .0032 .0051 .0029 .0001 -.0009 .0001 AlMH4 .00852 .75532 .59945 .01 .0038 .0032 .0051 .0029 .0001 -.0009 .0001 Si1 .2306 .08018 .38341 .0082 .0097 .0077 .0072 -.0001 -.0001 .0014 Si2 .2296 .86253 .38407 .0079 .0098 .0076 .0061 .0006 .0001 .0002 Si3 .1252 .73230 .87103 .0081 .0110 .0074 .0057 .0009 -.0009 .0008 Si4 .1249 .95336 .87138 .0088 .0124 .0087 .0054 .0016 .0004 .0010 Si5 .1043 .23368 .87155 .0082 .0128 .0064 .0054 -.0007 .0009 .0004 Si6 .6051 .95443 .87165 .0080 .0119 .0079 .0047 -.0002 -.0006 .0026 Si7 .2495 .92056 .61625 .0079 .0102 .0069 .0064 .0005 -.0008 .0009 Si8 .24927 .13881 .61685 .0074 .0079 .0071 .0073 .0012 .0005 .0017 BaAP1 .87372 .36887 .98145 .01629 .0088 .0290 .0106 -.00086 .00029 .0020 BaAP2 .12668 .12888 .01671 .01072 .0090 .0140 .0089 .00063 -.00020 .00113 BaAP3 .5 0 .5 .72 .0054 .0088 .004 .0039 -.0003 -.0008 .0011 KAP3 .5 0 .5 .28 .0054 .0088 .004 .0039 -.0003 -.0008 .0011 BaAP4A .0005 .0389 .4996 .25 .0252 .0218 .038 .0153 -.0024 -.0038 .005 KAP4B -.0067 -.0046 .4886 .20 .0252 .0218 .038 .0153 -.0024 -.0038 .005 NaBP1 .25 .25 .5 .86 .0172 .025 .022 .004 -.0067 .0010 .0007 CaBP1 .25 .25 .5 .14 .0172 .025 .022 .004 -.0067 .0010 .0007 NaBP2 .25 0 .5 .86 .0165 .026 .017 .006 .0098 -.0013 .0001 CaBP2 .25 0 .5 .14 .0165 .026 .017 .006 .0098 -.0013 .0001 O1 .2684 .4287 .6933 .0098 .013 .009 .007 .000 -.000 -.000 O2 .1274 .1562 .4143 .0163 .013 .025 .011 .002 -.000 .004 O3 .1326 .3953 .5851 .0174 .011 .027 .014 -.005 -.004 .002 O4 .1827 .9762 .4038 .0156 .017 .013 .017 .002 .001 .001 O5 .2705 .6668 .6924 .0082 .008 .011 .007 -.001 .000 .003 O6 .3671 .8528 .4148 .0157 .008 .027 .011 .006 -.004 .001 O7 .1267 .8021 .4157 .0177 .012 .028 .013 -.002 -.001 .003 O8 .0070 .2758 .0986 .0192 .013 .024 .018 -.004 .004 -.003 O9 .2659 .8198 1.0919 .0194 .012 .032 .014 .004 .001 .003 O10 .1159 .6980 .7953 .0097 .010 .011 .008 .001 .002 -.001 O11 .6770 .3464 .8842 .0173 .019 .013 .019 -.003 -.006 .002 O12 .2350 .0255 .9066 .0192 .014 .027 .017 -.003 .000 .004 O13 .1136 .9481 .7954 .0119 .014 .017 .005 .001 .001 .003 O14 .0064 .0201 .0981 .0176 .007 .032 .016 .008 .006 .007 O15 .1025 .2010 .7950 .0108 .013 .014 .005 -.002 -.002 -.000 O16 .2415 .2225 .9005 .0200 .008 .031 .017 .004 -.005 -.005 O17 -.0004 .1800 .9064 .0187 .011 .029 .014 -.005 .001 -.001 O18 .0553 .3478 .8856 .0164 .020 .014 .016 .000 .002 .003 O19 .2595 .0199 1.0965 .0200 .013 .032 .017 -.008 -.005 .011 O20 .5013 .0276 .9076 .0189 .011 .026 .018 .003 -.002 .002 O21 .6052 .9498 .7955 .0101 .011 .012 .008 .002 -.002 .006 O22 .3812 .8948 .5850 .0174 .010 .028 .015 .006 .001 .006 O23 .2611 .9298 .6928 .0099 .009 .012 .009 .001 .001 .000 O24 .1414 .8439 .5844 .0161 .013 .022 .013 .000 .003 -.001 O25 .1985 .0251 .5971 .0167 .018 .016 .016 .001 .001 .001 O26 .2590 .1696 .6934 .0100 .014 .011 .005 -.002 .001 .001 O27 .3821 .1473 .5865 .0160 .009 .024 .013 -.004 .003 -.001 O28 .1418 .1984 .5841 .0166 .014 .021 .015 .005 .001 .003 O29 .9803 .2138 .3156 .0116 .009 .017 .007 -.002 -.002 -.003 O30 .1434 .9299 .1931 .0123 .009 .021 .009 -.002 -.002 .007 O31 .9820 .6939 .3168 .0150 .010 .026 .011 .003 -.001 .008 O32 .3567 .0831 .8051 .0125 .009 .021 .007 .002 .000 -.000 OHXOA1 .5121 .0515 .7001 .57 .0143 .016 .018 .008 -.001 .000 .000 FXOA1 .5121 .0515 .7001 .43 .0143 .016 .018 .008 -.001 .000 .000 OHXOA2 .0120 .0493 .7020 .57 .0126 .012 .017 .009 .001 -.000 .004 FXOA2 .0120 .0493 .7020 .43 .0126 .012 .017 .009 .001 -.000 .004 OHXOA3 .3609 .8231 .7847 .57 .0118 FXOA3 .3609 .8231 .7847 .43 .0118 OHXOA4 .3603 .3200 .7866 .57 .0187 .014 .026 .016 .004 .002 .003 FXOA4 .3603 .3200 .7866 .43 .0187 .014 .026 .016 .004 .002 .003 OHXPM1 .1272 .8999 .0105 .57 .0145 FXPM1 .1272 .8999 .0105 .43 .0145 OHXPM2 .3751 .1522 .9888 .57 .0135 .012 .023 .003 .001 -.001 -.003 FXPM2 .3751 .1522 .9888 .43 .0135 .012 .023 .003 .001 -.001 -.003 OHXPM3 .0010 .2744 .4996 .57 .0095 .014 .010 .005 .001 -.003 .002 FXPM3 .0010 .2744 .4996 .43 .0095 .014 .010 .005 .001 -.003 .002