data_global _chemical_name_mineral 'Fassinaite' loop_ _publ_author_name 'Bindi L' 'Nestola F' 'Kolitsch U' 'Guastoni A' 'Zorzi F' _journal_name_full 'Mineralogical Magazine' _journal_volume 75 _journal_year 2011 _journal_page_first 2721 _journal_page_last 2732 _publ_section_title ; Fassinaite, Pb22+(S2O3)(CO3), the first mineral with coexisting thiosulphate and carbonate groups: description and crystal structure Note: Sample ID FAS-01 ; _database_code_amcsd 0018571 _chemical_compound_source 'Trentini mine, Mount Naro, Vicenza Province, Veneto, Italy' _chemical_formula_sum 'Pb2 S2 C O6' _cell_length_a 16.320 _cell_length_b 8.7616 _cell_length_c 4.5809 _cell_angle_alpha 90 _cell_angle_beta 90 _cell_angle_gamma 90 _cell_volume 655.020 _exptl_crystal_density_diffrn 5.948 _symmetry_space_group_name_H-M 'P n m a' loop_ _space_group_symop_operation_xyz 'x,y,z' 'x,1/2-y,z' '-x,1/2+y,-z' '1/2-x,1/2+y,1/2+z' '1/2+x,1/2-y,1/2-z' '1/2+x,y,1/2-z' '1/2-x,-y,1/2+z' '-x,-y,-z' loop_ _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv Pb 0.13583 0.48701 0.58420 0.02130 S1 0.00310 0.25000 0.06900 0.01400 C 0.71300 0.25000 0.38700 0.01900 O1 0.06200 0.25000 0.82800 0.02100 O2 0.27570 0.62300 0.50100 0.02100 O3 0.01390 0.11100 0.25100 0.02100 O4 0.18700 0.25000 0.38800 0.02300 S2 0.88500 0.25000 0.92900 0.02000 loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_12 _atom_site_aniso_U_13 _atom_site_aniso_U_23 Pb 0.01780 0.01970 0.02650 -0.00100 -0.00150 -0.00090 S1 0.01500 0.01900 0.00800 0.00000 -0.00900 0.00000 C 0.01000 0.02000 0.03000 0.00000 -0.01000 0.00000 O1 0.00400 0.04000 0.02000 0.00000 0.00800 0.00000 O2 0.02300 0.02800 0.01200 -0.01900 0.01200 -0.01100 O3 0.02000 0.02100 0.02300 0.00100 -0.00800 -0.00200 O4 0.03000 0.02000 0.02000 0.00000 -0.01000 0.00000 S2 0.01300 0.02500 0.02000 0.00000 -0.00300 0.00000