data_global
_chemical_name_mineral 'Phyllotungstite-Pb'
loop_
_publ_author_name
'Grey I E'
'Mumme W G'
'MacRae C M'
_journal_name_full 'Mineralogical Magazine'
_journal_volume 77 
_journal_year 2013
_journal_page_first 57
_journal_page_last 67
_publ_section_title
;
 Lead-bearing phyllotungstite from the Clara mine, Germany with an ordered
 pyrochlore-hexagonal tungsten bronze intergrowth structure
;
_database_code_amcsd 0019817
_chemical_compound_source 'Clara mine, Germany'
_chemical_formula_sum '(W5.28 Fe1.72) Pb1.146 Cs.214 O23 H6.129'
_cell_length_a 7.298
_cell_length_b 12.640
_cell_length_c 19.582
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 90
_cell_volume 1806.375
_exptl_crystal_density_diffrn      6.276
_symmetry_space_group_name_H-M 'C m c m'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2+y,z'
  'x,-y,1/2+z'
  '1/2+x,1/2-y,1/2+z'
  '-x,y,1/2-z'
  '1/2-x,1/2+y,1/2-z'
  '-x,y,z'
  '1/2-x,1/2+y,z'
  'x,-y,-z'
  '1/2+x,1/2-y,-z'
  'x,y,1/2-z'
  '1/2+x,1/2+y,1/2-z'
  '-x,-y,1/2+z'
  '1/2-x,1/2-y,1/2+z'
  '-x,-y,-z'
  '1/2-x,1/2-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
W1   0.00000   0.00000   0.00000   0.88000   0.03600
Fe1   0.00000   0.00000   0.00000   0.12000   0.03600
W2A   0.00000  -0.16920   0.15680   0.80000   0.02700
Fe2A   0.00000  -0.16920   0.15680   0.20000   0.02700
W2B   0.25050   0.08210   0.15480   0.70000   0.02900
Fe2B   0.25050   0.08210   0.15480   0.30000   0.02900
Pb1B   0.25000   0.25000   0.00000   0.22800   0.03500
Pb2   0.00000   0.33780   0.14440   0.34500   0.03000
Cs   0.00000   0.34700   0.25000   0.21400   0.06100
O1A   0.00000  -0.13060   0.05950   0.85100   0.00600
O-H1A   0.00000  -0.13060   0.05950   0.14900   0.00600
O1B   0.18250   0.06170   0.05640   0.85100   0.02300
O-H1B   0.18250   0.06170   0.05640   0.14900   0.02300
O2A   0.00000  -0.45570   0.12890   0.85100   0.01700
O-H2A   0.00000  -0.45570   0.12890   0.14900   0.01700
O2B   0.68760   0.22380   0.13890   0.85100   0.02100
O-H2B   0.68760   0.22380   0.13890   0.14900   0.02100
O3A   0.00000  -0.87700   0.16600   0.85100   0.04200
O-H3A   0.00000  -0.87700   0.16600   0.14900   0.04200
O3B   0.81190  -0.06660   0.17090   0.85100   0.01100
O-H3B   0.81190  -0.06660   0.17090   0.14900   0.01100
O4A   0.00000   0.80790   0.25000   0.85100   0.01300
O-H4A   0.00000   0.80790   0.25000   0.14900   0.01300
O4B   0.68300   0.09690   0.25000   0.85100   0.01600
O-H4B   0.68300   0.09690   0.25000   0.14900   0.01600
WatX   0.00000   0.31600   0.03950   0.75000   0.06700
OX   0.00000   0.31600   0.03950   0.25000   0.06700
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
W1 0.04300 0.03800 0.02590 0.00000 0.00000 0.00570
Fe1 0.04300 0.03800 0.02590 0.00000 0.00000 0.00570
W2A 0.02400 0.02000 0.03590 0.00000 0.00000 -0.00010
Fe2A 0.02400 0.02000 0.03590 0.00000 0.00000 -0.00010
W2B 0.01290 0.01600 0.06000 -0.00110 0.00050 0.00160
Fe2B 0.01290 0.01600 0.06000 -0.00110 0.00050 0.00160
Pb1B 0.05400 0.01900 0.03100 0.00400 0.00200 -0.00100
Pb2 0.01900 0.03500 0.03800 0.00000 0.00000 0.00400