data_global
_chemical_name_mineral 'Hlousekite'
loop_
_publ_author_name
'Plasil J'
'Sejkora J'
'Skoda R'
'Novak M'
'Kasatkin A V'
'Skacha P'
'Veselovsky F'
'Fejfarova K'
'Ondrus P'
_journal_name_full 'Mineralogical Magazine'
_journal_volume 78 
_journal_year 2014
_journal_page_first 1341
_journal_page_last 1353
_publ_section_title
;
 Hlousekite, (Ni,Co)Cu4(AsO4)2(AsO3OH)2(H2O)9, a new member of the lindackerite
 supergroup from Jachymov, Czech Republic
;
_database_code_amcsd 0020584
_chemical_compound_source 'Geister vein, Rovnost mine, Jachymov, Western Bohemia, Czech Republic'
_chemical_formula_sum '(Ni.75 Co.25) Cu4 As4 O25 H20'
_cell_length_a 6.4010
_cell_length_b 8.0041
_cell_length_c 10.3969
_cell_angle_alpha 85.824
_cell_angle_beta 79.873
_cell_angle_gamma 84.655
_cell_volume 521.232
_exptl_crystal_density_diffrn      3.290
_symmetry_space_group_name_H-M 'P -1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '-x,-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
Ni   0.00000   0.00000   0.00000   0.75000   0.02090
Co   0.00000   0.00000   0.00000   0.25000   0.02090
Cu1   0.10770   0.63571   0.55777   1.00000   0.02040
Cu2  -0.39958   0.07595   0.59897   1.00000   0.01660
As1   0.42207   0.38306   0.36377   1.00000   0.01670
As2   0.07807   0.01392   0.66670   1.00000   0.01410
O1   0.10280   0.08170   0.81000   1.00000   0.01600
O2   0.51210   0.51930   0.24520   1.00000   0.03100
O3   0.02000   0.81060   0.68570   1.00000   0.01900
Wat4  -0.49810   0.16100   0.77300   1.00000   0.01800
O5   0.17880   0.43810   0.44830   1.00000   0.01850
O-H6   0.38540   0.20440   0.28760   1.00000   0.02200
O7  -0.11280   0.13400   0.60280   1.00000   0.01570
O8   0.31230   0.03740   0.56580   1.00000   0.01330
O9   0.58960   0.32680   0.46720   1.00000   0.01800
Wat10   0.95550   0.53880   0.20060   1.00000   0.07400
Wat11   0.12100   0.75190   0.96130   0.50000   0.03000
Wat12   0.55100   0.62300   0.98300   0.50000   0.05300
Wat13  -0.28000   0.94000   0.94680   0.50000   0.03000
Wat14   0.30900   0.87200   0.00160   0.50000   0.03800
Wat15  -0.10200   0.77100   0.95960   0.50000   0.03600
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
Ni 0.01400 0.02020 0.02990 -0.00700 -0.00450 -0.00120
Co 0.01400 0.02020 0.02990 -0.00700 -0.00450 -0.00120
Cu1 0.00820 0.01220 0.04360 -0.00330 -0.00800 -0.00870
Cu2 0.00720 0.01410 0.02990 -0.00510 -0.00470 -0.00280
As1 0.01010 0.00830 0.03320 -0.00200 -0.00640 -0.00260
As2 0.00730 0.00890 0.02720 -0.00430 -0.00400 -0.00180
O1 0.01100 0.01400 0.02300 -0.00500 -0.00500 0.00200
O2 0.03000 0.01300 0.04900 -0.01300 -0.00500 0.00500
O3 0.02000 0.00900 0.02800 -0.00800 -0.00200 -0.00500
Wat4 0.01200 0.01900 0.02500 -0.01000 -0.00300 0.00000
O-H6 0.02000 0.01200 0.03700 -0.00300 -0.00900 -0.01000
O9 0.00900 0.00700 0.04000 0.00100 -0.00800 -0.01000
Wat10 0.06700 0.03800 0.12600 0.00800 -0.04000 -0.01900