data_global _chemical_name_mineral 'Glikinite' loop_ _publ_author_name 'Nazarchuk E V' 'Siidra O I' 'Nekrasova D O' 'Shilovskikh V V' 'Borisov A S' 'Avdontseva E Y' _journal_name_full 'Mineralogical Magazine' _journal_volume 84 _journal_year 2020 _journal_page_first 563 _journal_page_last 567 _publ_section_title ; Glikinite, Zn3O(SO4)2, a new anhydrous zinc oxysulfate mineral structurally based on OZn4 tetrahedra ; _database_code_amcsd 0020988 _chemical_compound_source 'Arsenatnaya fumarole, Tolbachik volcano, Kamchatka Peninsula, Russia' _chemical_formula_sum 'Zn3 S2 O9' _cell_length_a 7.298 _cell_length_b 6.588 _cell_length_c 7.840 _cell_angle_alpha 90 _cell_angle_beta 117.15 _cell_angle_gamma 90 _cell_volume 335.408 _exptl_crystal_density_diffrn 4.003 _symmetry_space_group_name_H-M 'P 1 21/m 1' loop_ _space_group_symop_operation_xyz 'x,y,z' 'x,1/2-y,z' '-x,1/2+y,-z' '-x,-y,-z' loop_ _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv Zn1 0.50000 0.50000 0.00000 0.01540 Zn2 -0.12520 0.75000 0.25360 0.01640 Zn3 0.65950 0.75000 0.77080 0.01720 S1 0.35280 0.75000 0.30510 0.01140 S2 0.06240 0.75000 0.71810 0.01140 O1 0.62800 0.75000 0.00960 0.00900 O2 0.19640 0.93120 0.76360 0.01700 O3 -0.07900 0.75000 0.52120 0.02600 O4 0.38800 0.57000 0.21480 0.03200 O5 0.04600 0.75000 0.83120 0.03000 O6 0.13900 0.75000 0.26200 0.07700 O7 0.47900 0.75000 0.49700 0.09100 loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_12 _atom_site_aniso_U_13 _atom_site_aniso_U_23 Zn1 0.01940 0.01020 0.01800 -0.00220 0.00970 0.00040 Zn2 0.01810 0.01300 0.01230 0.00000 0.00210 0.00000 Zn3 0.02430 0.01500 0.01250 0.00000 0.00890 0.00000 S1 0.01500 0.00600 0.01100 0.00000 0.00390 0.00000 S2 0.01510 0.01100 0.00640 0.00000 0.00390 0.00000 O1 0.00700 0.00100 0.01300 0.00000 0.00100 0.00000 O2 0.01100 0.02100 0.01300 0.00100 0.00000 -0.00300 O3 0.04100 0.01000 0.01200 0.00000 -0.00100 0.00000 O4 0.07000 0.00600 0.04200 0.00400 0.04400 0.00200 O5 0.02300 0.05000 0.02700 0.00000 0.02100 0.00000 O6 0.04200 0.05500 0.17000 0.00000 0.07500 0.00000 O7 0.14000 0.05000 0.00900 0.00000 -0.03200 0.00000