data_global _chemical_name_mineral 'Ciriottiite' loop_ _publ_author_name 'Bindi L' 'Biagioni C' 'Martini B' 'Salvetti A' _journal_name_full 'Minerals' _journal_volume 6 _journal_year 2016 _journal_page_first _journal_page_last 8 _publ_section_title ; Ciriottiite, Cu(Cu,Ag)3Pb19(Sb,As)22(As2)S56, the Cu-analogue of sterryite from the Tavagnasco Mining District, Piedmont, Italy ; _database_code_amcsd 0020592 _chemical_compound_source 'Tavagnasco Mining District, Piedmont, Italy' _chemical_formula_sum 'Pb18.886 Bi.597 Sb17.344 As6.37 Cu2.733 Hg.47 Ag.4 S56' _cell_length_a 8.178 _cell_length_b 28.223 _cell_length_c 42.452 _cell_angle_alpha 90 _cell_angle_beta 93.55 _cell_angle_gamma 90 _cell_volume 9779.447 _exptl_crystal_density_diffrn 5.932 _symmetry_space_group_name_H-M 'P 1 21/n 1' loop_ _space_group_symop_operation_xyz 'x,y,z' '1/2+x,1/2-y,1/2+z' '1/2-x,1/2+y,1/2-z' '-x,-y,-z' loop_ _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_occupancy _atom_site_U_iso_or_equiv Pb1 0.72760 0.63972 0.19909 1.00000 0.02410 Pb2 0.22120 0.63595 0.19883 1.00000 0.02400 Pb3 0.68020 0.69994 0.10116 1.00000 0.02690 Pb4 0.17920 0.69920 0.10205 1.00000 0.02390 Pb5 0.68360 0.54813 0.11575 1.00000 0.02580 Pb6 0.18850 0.54779 0.11638 1.00000 0.02610 Pb7 0.67800 0.40762 0.10854 0.60000 0.02230 Bi7 0.67800 0.40762 0.10854 0.40000 0.02230 Pb8 0.18910 0.40363 0.11030 1.00000 0.02510 Sb9 0.53040 0.01038 0.29839 1.00000 0.02370 Sb10 0.47140 0.49977 0.19310 0.66000 0.01900 As10 0.47140 0.49977 0.19310 0.34000 0.01900 Sb11 0.49440 0.08153 0.22563 0.92000 0.02250 As11 0.49440 0.08153 0.22563 0.08000 0.02250 Sb12 -0.00060 0.09576 0.21928 0.42000 0.01940 As12 -0.00060 0.09576 0.21928 0.58000 0.01940 Pb13 0.73440 0.21611 0.21396 1.00000 0.02690 Pb14 0.23290 0.21040 0.20846 1.00000 0.02930 Sb15 0.95740 0.76197 0.17843 0.06000 0.01560 As15 0.95740 0.76197 0.17843 0.94000 0.01560 Sb16 0.43720 0.76734 0.17684 1.00000 0.02900 Sb17 0.90410 0.83807 0.09483 0.93000 0.02300 As17 0.90410 0.83807 0.09483 0.07000 0.02300 Sb18 0.42970 0.82691 0.09880 0.60000 0.02710 As18 0.42970 0.82691 0.09880 0.40000 0.02710 Sb19 0.89830 0.90901 0.02102 1.00000 0.03180 Sb20 0.38030 0.92087 0.01166 1.00000 0.02840 Sb21 0.33910 0.49772 0.43027 1.00000 0.03010 Pb22 0.85260 0.49910 0.43832 0.66000 0.03730 Sb22 0.85260 0.49910 0.43832 0.34000 0.03730 Pb23 0.18110 0.91581 0.14486 0.80000 0.03060 Sb23 0.18110 0.91581 0.14486 0.20000 0.03060 Sb24 0.70440 0.91745 0.15189 1.00000 0.02290 Cu25 0.26410 0.32813 0.26281 0.73000 0.04800 Hg25 0.26410 0.32813 0.26281 0.27000 0.04800 Sb26 0.73370 0.83420 0.23458 0.87000 0.02590 As26 0.73370 0.83420 0.23458 0.13000 0.02590 Pb27 0.00230 0.38051 0.19622 0.90600 0.02600 Sb27 -0.10300 0.38120 0.19570 0.09400 0.02600 Sb28 0.47740 0.36815 0.19262 0.53000 0.02690 As28 0.47740 0.36815 0.19262 0.47000 0.02690 Sb29 0.46060 0.95477 0.22201 1.00000 0.03590 Pb30 0.52090 0.46851 0.27376 1.00000 0.03360 Pb31 0.43950 0.04976 0.14234 1.00000 0.03070 Pb32 0.93610 0.05136 0.14039 1.00000 0.03390 Cu33 0.38410 0.11760 0.05710 0.80300 0.02500 Bi33 0.34000 0.12180 0.05480 0.19700 0.02500 Cu34 -0.08210 0.11893 0.05765 0.40000 0.04460 Hg34 -0.08210 0.11893 0.05765 0.20000 0.04460 Ag34 -0.08210 0.11893 0.05765 0.40000 0.04460 Pb35 0.64180 0.78366 0.01663 1.00000 0.02800 Pb36 0.13650 0.78663 0.01829 1.00000 0.03010 Sb37 0.89790 0.62006 0.03930 0.28000 0.02060 As37 0.89790 0.62006 0.03930 0.72000 0.02060 Sb38 0.39340 0.61321 0.03661 1.00000 0.02440 Sb39 0.89580 0.47000 0.03944 1.00000 0.02330 Sb40 0.39950 0.48376 0.04008 0.36000 0.01810 As40 0.39950 0.48376 0.04008 0.64000 0.01810 Pb41 0.90480 0.33711 0.03894 0.11000 0.02300 Sb41 0.90480 0.33711 0.03894 0.89000 0.02300 Sb42 0.38750 0.32990 0.03511 1.00000 0.02580 Cu43 0.64590 0.21280 0.05780 0.80000 0.03900 Pb44 0.67650 0.27445 0.11950 0.81000 0.02660 Sb44 0.71400 0.27320 0.11920 0.19000 0.02660 Pb45 0.18510 0.25812 0.10578 1.00000 0.03440 As46 0.85930 0.16428 0.13172 1.00000 0.02130 As47 0.53880 0.16031 0.13266 1.00000 0.02170 S1 0.95450 0.69110 0.15450 1.00000 0.01150 S2 0.44570 0.69120 0.15560 1.00000 0.01180 S3 0.92700 0.62290 0.09340 1.00000 0.01800 S4 0.42520 0.62330 0.09290 1.00000 0.01350 S5 0.95750 0.57290 0.16600 1.00000 0.01290 S6 0.45570 0.57180 0.16790 1.00000 0.01700 S7 0.49820 0.15590 0.25030 1.00000 0.01550 S8 0.49180 0.66450 0.24780 1.00000 0.02100 S9 0.91790 0.76290 0.07000 1.00000 0.01900 S10 0.41080 0.76080 0.06600 1.00000 0.02000 S11 0.92830 0.47830 0.09700 1.00000 0.02100 S12 0.41910 0.47680 0.09590 1.00000 0.02400 S13 0.68880 0.47390 0.16380 1.00000 0.01600 S14 0.22500 0.47230 0.16450 1.00000 0.02100 S15 0.77290 0.55160 0.23750 1.00000 0.02300 S16 0.21290 0.54860 0.23690 1.00000 0.02000 S17 -0.24440 0.11680 0.18990 1.00000 0.02500 S18 0.19640 0.12370 0.18490 1.00000 0.03300 S19 0.76960 0.74130 0.21290 1.00000 0.02300 S20 0.19660 0.75190 0.21110 1.00000 0.01900 S21 0.66260 0.80300 0.13180 1.00000 0.02600 S22 0.23800 0.79880 0.13420 1.00000 0.02100 S23 0.68690 0.87130 0.05720 1.00000 0.01900 S24 0.12820 0.87430 0.05470 1.00000 0.03300 S25 0.41350 0.04810 0.02380 1.00000 0.02600 S26 0.86080 0.04790 0.02010 1.00000 0.02200 S27 0.09600 0.46830 0.39620 1.00000 0.02500 S28 0.94820 0.96770 0.10410 1.00000 0.02800 S29 0.48520 0.88760 0.18490 1.00000 0.01040 S30 0.94590 0.88990 0.18580 1.00000 0.02000 S31 0.52970 0.80240 0.26690 1.00000 0.02600 S32 0.52240 0.30840 0.23080 1.00000 0.01900 S33 0.25160 0.32900 0.16760 1.00000 0.02000 S34 0.70240 0.34620 0.16340 1.00000 0.02300 S35 0.24720 0.41010 0.24880 1.00000 0.02300 S36 0.77390 0.41650 0.24190 1.00000 0.02100 S37 0.28870 0.49230 0.32050 1.00000 0.02400 S38 0.70530 0.99420 0.17560 1.00000 0.01340 S39 0.16770 0.07430 0.09570 1.00000 0.01310 S40 0.82440 0.57410 0.40280 1.00000 0.01410 S41 0.12940 0.15660 0.01440 1.00000 0.02400 S42 0.62370 0.15660 0.01020 1.00000 0.02100 S43 0.68400 0.67640 0.03440 1.00000 0.03500 S44 0.11200 0.67010 0.03140 1.00000 0.03400 S45 0.61320 0.53920 0.03890 1.00000 0.02700 S46 0.18610 0.54490 0.03880 1.00000 0.01800 S47 0.68040 0.41060 0.03930 1.00000 0.01500 S48 0.11710 0.40690 0.04030 1.00000 0.01900 S49 -0.06340 0.22760 0.16130 1.00000 0.00780 S50 0.57660 0.66590 -0.09330 1.00000 0.01600 S51 0.06150 0.69020 0.41320 1.00000 0.01900 S52 -0.06970 0.33460 0.09950 1.00000 0.02100 S53 0.01910 0.72400 0.33730 1.00000 0.01800 S54 -0.10420 0.19690 0.08380 1.00000 0.02300 S55 0.83050 0.72770 -0.03790 1.00000 0.02600 S56 0.38500 0.72240 -0.02580 1.00000 0.03600 loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_12 _atom_site_aniso_U_13 _atom_site_aniso_U_23 Pb1 0.01360 0.01990 0.03950 -0.00260 0.00720 -0.00330 Pb2 0.01360 0.02310 0.03580 0.00090 0.00570 -0.00030 Pb3 0.01160 0.03230 0.03730 0.00170 0.00500 0.00260 Pb4 0.01070 0.02200 0.03960 -0.00170 0.00650 0.00040 Pb5 0.01460 0.01380 0.04960 -0.00090 0.00660 -0.00310 Pb6 0.00990 0.02000 0.04910 0.00220 0.00770 -0.00260 Pb7 0.00750 0.02220 0.03750 0.00360 0.00490 -0.00300 Bi7 0.00750 0.02220 0.03750 0.00360 0.00490 -0.00300 Pb8 0.01040 0.02130 0.04440 -0.00100 0.00650 -0.00240 Sb9 0.03020 0.00500 0.03650 0.00700 0.00660 -0.00150 Sb10 0.01530 0.00460 0.03800 -0.00630 0.00640 0.00130 As10 0.01530 0.00460 0.03800 -0.00630 0.00640 0.00130 Sb11 0.02400 0.01560 0.02800 -0.00010 0.00380 -0.00510 As11 0.02400 0.01560 0.02800 -0.00010 0.00380 -0.00510 Sb12 0.01100 0.01020 0.03800 -0.00020 0.00820 0.00170 As12 0.01100 0.01020 0.03800 -0.00020 0.00820 0.00170 Pb13 0.01030 0.02650 0.04440 0.00250 0.00540 -0.00020 Pb14 0.01750 0.01480 0.05660 -0.00170 0.01170 -0.00120 Sb15 0.01000 0.01300 0.02400 0.00150 0.00500 0.00120 As15 0.01000 0.01300 0.02400 0.00150 0.00500 0.00120 Sb16 0.02680 0.02100 0.04000 -0.00220 0.00730 -0.00110 Sb17 0.01590 0.00670 0.04600 -0.00120 0.00060 -0.00710 As17 0.01590 0.00670 0.04600 -0.00120 0.00060 -0.00710 Sb18 0.00170 0.03800 0.04100 0.00020 0.00200 -0.00520 As18 0.00170 0.03800 0.04100 0.00020 0.00200 -0.00520 Sb19 0.01650 0.02290 0.05600 -0.00220 0.00230 -0.01090 Sb20 0.01310 0.02080 0.05100 -0.00460 0.00290 0.00150 Sb21 0.00480 0.01640 0.07000 -0.00130 0.01090 -0.00640 Pb22 0.01230 0.05460 0.04500 0.00220 0.00260 0.00220 Sb22 0.01230 0.05460 0.04500 0.00220 0.00260 0.00220 Pb23 0.01050 0.03670 0.04480 -0.00240 0.00240 0.00110 Sb23 0.01050 0.03670 0.04480 -0.00240 0.00240 0.00110 Sb24 0.01240 0.00830 0.04900 -0.00070 0.00690 0.00080 Cu25 0.04400 0.03000 0.07000 0.00300 0.01500 0.02300 Hg25 0.04400 0.03000 0.07000 0.00300 0.01500 0.02300 Sb26 0.01400 0.02600 0.03800 0.00350 0.00940 0.00220 As26 0.01400 0.02600 0.03800 0.00350 0.00940 0.00220 Pb27 0.01920 0.01970 0.04010 0.00460 0.00950 0.00190 Sb27 0.01920 0.01970 0.04010 0.00460 0.00950 0.00190 Sb28 0.01300 0.03500 0.03300 0.00220 0.00440 0.00710 As28 0.01300 0.03500 0.03300 0.00220 0.00440 0.00710 Sb29 0.03240 0.04200 0.03500 -0.00800 0.01530 -0.00410 Pb30 0.02480 0.02490 0.05160 0.00150 0.00510 -0.00260 Pb31 0.02100 0.02690 0.04470 -0.00260 0.00580 0.00090 Pb32 0.01870 0.02540 0.05850 0.00040 0.00950 0.00460 Cu34 0.06700 0.02300 0.04300 0.01300 0.00200 -0.00750 Hg34 0.06700 0.02300 0.04300 0.01300 0.00200 -0.00750 Ag34 0.06700 0.02300 0.04300 0.01300 0.00200 -0.00750 Pb35 0.01520 0.02960 0.03950 -0.00220 0.00520 0.00260 Pb36 0.01850 0.02880 0.04330 0.00340 0.00560 0.00280 Sb37 0.01900 0.01300 0.03000 -0.00110 0.00610 0.00580 As37 0.01900 0.01300 0.03000 -0.00110 0.00610 0.00580 Sb38 0.02720 0.02120 0.02510 0.00210 0.00340 0.00020 Sb39 0.00840 0.02640 0.03530 -0.00320 0.00310 0.00060 Sb40 0.00700 0.01600 0.03300 -0.00280 0.00720 0.00230 As40 0.00700 0.01600 0.03300 -0.00280 0.00720 0.00230 Pb41 0.01170 0.02180 0.03600 0.00060 0.00630 -0.00190 Sb41 0.01170 0.02180 0.03600 0.00060 0.00630 -0.00190 Sb42 0.01330 0.02220 0.04230 0.00210 0.00540 0.00060 Cu43 0.01300 0.07000 0.03300 0.00400 0.00500 0.02700 Pb44 0.00300 0.01940 0.05900 0.00380 0.01120 0.00730 Sb44 0.00300 0.01940 0.05900 0.00380 0.01120 0.00730 Pb45 0.01690 0.02760 0.05960 0.00300 0.01090 0.00900 As46 0.01200 0.00140 0.05200 0.00110 0.01200 -0.00200 As47 0.00790 0.02600 0.03200 -0.00280 0.00590 0.00200 S1 0.00700 0.01200 0.01600 0.00200 0.00000 0.00400 S2 0.01200 0.01000 0.01300 0.00200 -0.00500 -0.00200 S3 0.02200 0.01700 0.01600 -0.00200 0.00000 0.00200 S4 0.00900 0.01200 0.02000 -0.00500 0.00500 0.00100 S5 0.01400 0.01200 0.01300 0.00500 0.00100 0.00200 S6 0.02200 0.01300 0.01500 -0.00300 -0.00300 -0.00200 S7 0.01400 0.01500 0.01700 -0.00300 -0.00200 0.00200 S8 0.02200 0.01800 0.02300 0.00300 0.00000 0.00200 S9 0.01800 0.01700 0.02100 0.00100 -0.00100 0.00100 S10 0.01300 0.02700 0.02000 0.00000 0.00000 0.00400 S11 0.02400 0.01500 0.02500 -0.00200 -0.00300 -0.00100 S12 0.02500 0.02500 0.02200 -0.00100 -0.00100 0.00100 S13 0.01200 0.01700 0.01800 -0.00200 -0.00300 0.00100 S14 0.02200 0.01900 0.02300 -0.00500 -0.00600 0.00000 S15 0.02900 0.01900 0.02000 -0.00100 0.00200 0.00100 S16 0.02200 0.01600 0.02100 0.00200 0.00400 0.00000 S17 0.03700 0.01900 0.01800 -0.00500 -0.00100 -0.00200 S18 0.03000 0.02900 0.03800 0.01000 -0.00300 0.00200 S19 0.01800 0.02600 0.02600 0.00400 0.00800 -0.00200 S20 0.02900 0.01500 0.01300 0.00000 -0.00200 0.00100 S21 0.03800 0.01800 0.02200 -0.00200 0.00400 0.00000 S22 0.01500 0.02500 0.02200 0.00000 0.00200 -0.00200 S23 0.01600 0.01700 0.02500 -0.00400 0.00400 0.00000 S24 0.03700 0.03100 0.03000 0.00900 0.00300 0.00100 S25 0.04400 0.01400 0.01900 0.00400 0.00200 0.00100 S26 0.02500 0.02200 0.01700 0.00200 0.00000 -0.00200 S27 0.01900 0.02800 0.02700 0.00000 0.00600 0.00200 S28 0.04200 0.02000 0.02400 0.00200 0.00800 0.00100 S29 0.01800 0.00300 0.01000 0.00000 0.00100 -0.00300 S30 0.01600 0.02700 0.01900 0.00700 0.00300 0.00500 S31 0.03300 0.02400 0.02100 0.00600 0.00300 -0.00400 S32 0.02200 0.01700 0.01900 0.00000 0.00600 -0.00200 S33 0.00200 0.02600 0.03300 0.00100 -0.00600 0.00500 S34 0.03600 0.01400 0.02000 -0.00400 0.00700 0.00200 S35 0.03300 0.01400 0.02200 0.00700 0.00500 -0.00200 S36 0.00400 0.02400 0.03500 0.00100 0.00300 0.00000 S37 0.03300 0.01600 0.02400 0.00800 0.01100 0.00400 S38 0.01400 0.01500 0.01200 -0.00700 0.00600 0.00000 S39 0.00900 0.01500 0.01500 -0.00100 -0.00200 -0.00400 S40 0.01000 0.01500 0.01700 -0.00200 -0.00100 -0.00200 S41 0.02100 0.02400 0.02800 0.00300 0.00000 0.00400 S42 0.02500 0.02200 0.01600 0.00300 -0.00300 -0.00300 S43 0.04100 0.03600 0.02700 0.00000 0.00400 0.00400 S44 0.04100 0.03000 0.03200 -0.00100 0.00200 -0.00600 S45 0.02900 0.03400 0.01900 0.00100 0.00600 0.00200 S46 0.01500 0.01300 0.02500 -0.00500 -0.00300 -0.00100 S47 0.00700 0.02000 0.01800 -0.00200 0.00200 0.00100 S48 0.03300 0.00800 0.01600 -0.00100 0.00000 -0.00100 S49 0.00800 0.00500 0.01100 0.00300 0.00200 -0.00300 S50 0.01600 0.01500 0.01600 0.00200 0.00200 0.00100 S51 0.02100 0.02000 0.01500 0.00100 0.00000 0.00100 S52 0.02300 0.01600 0.02300 0.00100 0.00100 0.00300 S53 0.02000 0.01700 0.01500 0.00200 0.00000 -0.00200 S54 0.02400 0.02300 0.02300 -0.00600 0.00500 0.00000 S55 0.03400 0.02000 0.02500 -0.00200 0.00200 0.00500 S56 0.04900 0.02700 0.03300 0.00200 0.00000 0.00200