data_global _chemical_name_mineral 'Jordanite' loop_ _publ_author_name 'Biagioni C' 'Dini A' 'Orlandi P' 'Moelo Y' 'Pasero M' 'Zaccarini F' _journal_name_full 'Minerals' _journal_volume 6 _journal_year 2016 _journal_page_first _journal_page_last doi:10.3390 _publ_section_title ; Lead-antimony sulfosalts from Tuscany (Italy). XX. Members of the jordanite-geocronite series from the Pollone mine, Valdicastello Carducci: Occurrence and crystal structures Note: Sb-bearing jordanite ; _database_code_amcsd 0020593 _chemical_compound_source 'Pollone mine, Valdicastello Carducci, Pietrasanta, Tuscany, Italy' _chemical_formula_sum 'Pb14 Sb2.22 As3.78 S23' _cell_length_a 8.9338 _cell_length_b 31.891 _cell_length_c 8.4720 _cell_angle_alpha 90 _cell_angle_beta 117.943 _cell_angle_gamma 90 _cell_volume 2132.331 _exptl_crystal_density_diffrn 6.529 _symmetry_space_group_name_H-M 'P 1 21/m 1' loop_ _space_group_symop_operation_xyz 'x,y,z' 'x,1/2-y,z' '-x,1/2+y,-z' '-x,-y,-z' loop_ _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_occupancy _atom_site_U_iso_or_equiv Pb1 0.44561 0.05462 0.35038 1.00000 0.01942 Pb2 0.43700 0.05521 0.83810 0.50000 0.01722 Sb2 0.44250 0.04516 0.84880 0.50000 0.01722 Pb3 0.90402 0.04225 0.32112 1.00000 0.02051 Sb4 0.92012 0.04951 0.83273 0.61000 0.01598 As4 0.92012 0.04951 0.83273 0.39000 0.01598 Pb5 0.26298 0.14313 -0.00032 1.00000 0.02687 As6 0.27337 0.14343 0.50811 1.00000 0.01636 Pb7 0.78996 0.15103 0.01926 1.00000 0.01914 Pb8 0.79159 0.15065 0.51593 1.00000 0.01847 Pb9 0.12151 0.25000 0.17416 1.00000 0.02268 Pb10 0.12159 0.25000 0.69021 1.00000 0.02262 As11 0.61526 0.22585 0.17856 0.50000 0.01460 Pb12 0.55140 0.25000 0.64371 1.00000 0.03685 S1 0.30664 0.00315 0.01400 1.00000 0.01720 S2 0.30616 0.00468 0.54660 1.00000 0.01760 S3 0.05013 0.08685 0.11240 1.00000 0.01620 S4 0.05419 0.08617 0.68340 1.00000 0.01680 S5 0.65118 0.09760 0.20340 1.00000 0.01600 S6 0.66795 0.09141 0.70570 1.00000 0.01510 S7 0.40463 0.17750 0.37510 1.00000 0.02330 S8 0.40124 0.17828 0.76930 1.00000 0.02190 S9 0.02861 0.18000 0.38482 1.00000 0.01550 S10 0.99244 0.19304 0.86940 1.00000 0.01640 S11 0.37610 0.26193 0.05890 0.50000 0.01500 S12 0.75000 0.25000 0.03440 1.00000 0.02360 S13 0.74970 0.25000 0.45470 1.00000 0.02420 loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_12 _atom_site_aniso_U_13 _atom_site_aniso_U_23 Pb1 0.01994 0.01768 0.02124 0.00158 0.01016 0.00089 Pb2 0.01742 0.01620 0.01990 -0.00020 0.01029 -0.00120 Sb2 0.01742 0.01620 0.01990 -0.00020 0.01029 -0.00120 Pb3 0.01706 0.02084 0.02264 0.00203 0.00847 0.00075 Sb4 0.01530 0.01670 0.01760 0.00048 0.00907 -0.00030 As4 0.01530 0.01670 0.01760 0.00048 0.00907 -0.00030 Pb5 0.02334 0.03467 0.02428 0.00852 0.01255 0.00555 As6 0.01590 0.01340 0.02040 0.00260 0.00900 0.00070 Pb7 0.02086 0.01800 0.02147 0.00008 0.01233 -0.00022 Pb8 0.02072 0.01679 0.01946 -0.00109 0.01070 -0.00034 Pb9 0.02420 0.02263 0.02144 0.00000 0.01087 0.00000 Pb10 0.02434 0.02204 0.02593 0.00000 0.01548 0.00000 As11 0.01240 0.00850 0.02240 -0.00050 0.00770 -0.00040 Pb12 0.04190 0.02290 0.04710 0.00000 0.02200 0.00000 S1 0.01220 0.01810 0.02140 0.00080 0.00810 -0.00380 S2 0.01590 0.01420 0.02490 0.00070 0.01150 0.00080 S3 0.01540 0.01590 0.01910 0.00070 0.00950 0.00150 S4 0.01570 0.01760 0.01930 0.00160 0.01000 -0.00050 S5 0.01580 0.01560 0.01850 -0.00170 0.00970 -0.00110 S6 0.01410 0.01510 0.01680 -0.00160 0.00780 -0.00110 S7 0.01630 0.02930 0.02840 0.00140 0.01400 0.00150 S8 0.01610 0.02540 0.02180 0.00050 0.00700 -0.00070 S9 0.01220 0.01700 0.01820 0.00100 0.00770 0.00040 S10 0.02040 0.01230 0.01920 -0.00440 0.01150 -0.00200 S11 0.01020 0.01980 0.01570 0.00420 0.00650 0.00160 S12 0.01170 0.02870 0.03140 0.00000 0.01090 0.00000 S13 0.01210 0.03110 0.02450 0.00000 0.00450 0.00000