data_global
_chemical_name_mineral 'Gladite'
loop_
_publ_author_name
'Synecek V'
'Hybler J'
_journal_name_full 'Neues Jahrbuch fur Mineralogie, Monatshefte'
_journal_volume 1974 
_journal_year 1974
_journal_page_first 541
_journal_page_last 560
_publ_section_title
;
 The crystal structures of krupkaite, CuPbBi3S6, and of gladite, CuPbBi5S9,
 and the classification of superstructures in the bismuthinite-aikinite group,
;
_database_code_amcsd 0014751
_chemical_compound_source 'Krupka, Ore Mountains, NW-Bohemia'
_chemical_formula_sum 'Bi5 Pb S9 Cu'
_cell_length_a 33.62
_cell_length_b 11.48
_cell_length_c 4.00
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 90
_cell_volume 1543.830
_exptl_crystal_density_diffrn      6.902
_symmetry_space_group_name_H-M 'P b n m'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  'x,y,1/2-z'
  '-x,-y,1/2+z'
  '1/2+x,1/2-y,1/2+z'
  '1/2-x,1/2+y,1/2-z'
  '1/2-x,1/2+y,z'
  '1/2+x,1/2-y,-z'
  '-x,-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
Bi(Al)   0.22800   0.02000   0.25000
Bi(A2)   0.05700   0.48000   0.75000
Bi(A3)   0.39200   0.48500   0.75000
Bi(B1)   0.15500   0.35200   0.25000
Bi(B2)   0.48700   0.34300   0.25000
Pb(B3)   0.33400   0.18500   0.75000
S(1,1)   0.04600   0.50400   0.25000
S(1,2)   0.21300   0.46000   0.75000
S(1,3)   0.37900   0.05800   0.25000
S(2,1)   0.01700   0.36400   0.25000
S(2,2)   0.18500   0.12900   0.75000
S(2,3)   0.34800   0.38200   0.25000
S(3,1)   0.10400   0.27500   0.75000
S(3,2)   0.27400   0.23300   0.25000
S(3,3)   0.43800   0.28000   0.75000
Cu   0.23500   0.28000   0.75000