data_global
_chemical_name_mineral 'Zincohogbomite-2N6S'
loop_
_publ_author_name
'Armbruster T'
'Bermanec V'
'Zebec V'
'Oberhansli R'
_journal_name_full 'Schweizerische Mineralogische und Petrographische Mitteilungen'
_journal_volume 78 
_journal_year 1998
_journal_page_first 469
_journal_page_last 477
_publ_section_title
;
 Titanium and iron poor zincohogbomite-16H, Zn14(Al,Fe3+,Ti,Mg)8Al24O62(OH)2,
 from Nezilovo, Macedonia: occurence and crystal structure of a new polysome
;
_database_code_amcsd 0019143
_chemical_compound_source 'Nezilovo, Macedonia'
_chemical_formula_sum 'Zn6.37 Al14.648 Mg.214 Fe Ti.78 O32 H'
_cell_length_a 5.729
_cell_length_b 5.729
_cell_length_c 37.097
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 120
_cell_volume 1054.453
_exptl_crystal_density_diffrn      4.482
_symmetry_space_group_name_H-M 'P 63 m c'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '-x,-x+y,1/2+z'
  'x-y,x,1/2+z'
  '-y,-x,z'
  '-y,x-y,z'
  'x-y,-y,1/2+z'
  '-x,-y,1/2+z'
  'x,x-y,z'
  '-x+y,-x,z'
  'y,x,1/2+z'
  'y,-x+y,1/2+z'
  '-x+y,y,z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
Zn1   0.66667   0.33333   0.27662   0.84000   0.00608
Al1   0.66667   0.33333   0.27662   0.10860   0.00608
Mg1   0.66667   0.33333   0.27662   0.05440   0.00608
Zn2   0.00000   0.00000   0.52706   0.95000   0.00608
Mg2   0.00000   0.00000   0.52706   0.01700   0.00608
Al2   0.00000   0.00000   0.52706   0.03390   0.00608
Zn3   0.66667   0.33333   0.55878   0.91000   0.00608
Mg3   0.66667   0.33333   0.55878   0.03060   0.00608
Al3   0.66667   0.33333   0.55878   0.06110   0.00608
Zn4   0.66667   0.33333   0.65229   0.95000   0.00608
Mg4   0.66667   0.33333   0.65229   0.01700   0.00608
Al4   0.66667   0.33333   0.65229   0.03390   0.00608
Zn5   0.33333   0.66667   0.68484   0.93000   0.00608
Mg5   0.33333   0.66667   0.68484   0.02380   0.00608
Al5   0.33333   0.66667   0.68484   0.04750   0.00608
Zn6   0.33333   0.66667   0.40084   0.88000   0.00608
Mg6   0.33333   0.66667   0.40084   0.04080   0.00608
Al6   0.33333   0.66667   0.40084   0.08140   0.00608
Zn7   0.00000   0.00000   0.43266   0.91000   0.00608
Mg7   0.00000   0.00000   0.43266   0.03060   0.00608
Al7   0.00000   0.00000   0.43266   0.06110   0.00608
Fe   0.33333   0.66667   0.30155   1.00000   0.00557
Ti  -0.16600  -0.33200   0.35345   0.26000   0.00646
Al8  -0.16600  -0.33200   0.35345   0.74000   0.00646
Al9   0.16650   0.33300   0.60593   1.00000   0.00545
Al10   0.00000   0.00000   0.66900   1.00000   0.00621
Al11   0.66667   0.33333   0.41760   1.00000   0.00709
Al12   0.50010   0.00020   0.48009   1.00000   0.00557
Al13  -0.16980  -0.33960   0.73135   1.00000   0.00608
Al14   0.33333   0.66667   0.54290   1.00000   0.00570
O1   0.33333   0.66667   0.63290   1.00000   0.01140
O2   0.66667   0.33333   0.50700   1.00000   0.01140
O3   0.18670   0.37340   0.51000   1.00000   0.00773
O4   0.00000   0.00000   0.37960   1.00000   0.01140
O5  -0.14690  -0.29380   0.63570   1.00000   0.00836
O6   0.51970   0.03940   0.38520   1.00000   0.00874
O7   0.48210   0.96420   0.26110   1.00000   0.01001
O8   0.14790   0.29580   0.70260   1.00000   0.00671
O9   0.48240   0.96480   0.57660   1.00000   0.00747
O10  -0.18380  -0.36760   0.45080   1.00000   0.00659
O-H11   0.00000   0.00000   0.75880   1.00000   0.00760
O12   0.16580   0.33160   0.32600   1.00000   0.00735
O13   0.00000   0.00000   0.58000   1.00000   0.00507
O14   0.33333   0.66667   0.45440   1.00000   0.00760
O15   0.66667   0.33333   0.32850   1.00000   0.01013
O16   0.33333   0.66667   0.20540   1.00000   0.00507