data_global
_chemical_name_mineral 'Henryite'
loop_
_publ_author_name
'Bindi L'
_journal_name_full 'Solid State Sciences'
_journal_volume 38 
_journal_year 2014
_journal_page_first 108
_journal_page_last 111
_publ_section_title
;
 Chemical and structural characterization of henryite, (Cu,Ag)3+xTe2 (x ~ 0.40):
 A new structure type in the (Ag)-Cu-Te system
;
_database_code_amcsd 0020215
_chemical_compound_source 'the Campbell orebody, Bisbee, Arizona, USA'
_chemical_formula_sum 'Cu1.918 Ag1.468 Fe.022 Te'
_cell_length_a 12.1987
_cell_length_b 12.1987
_cell_length_c 12.1987
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 90
_cell_volume 1815.267
_exptl_crystal_density_diffrn      5.987
_symmetry_space_group_name_H-M 'F d 3 c'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  'x,1/2+y,1/2+z'
  '1/2+x,y,1/2+z'
  '1/2+x,1/2+y,z'
  '3/4+z,3/4-x,3/4+y'
  '3/4+z,1/4-x,1/4+y'
  '1/4+z,3/4-x,1/4+y'
  '1/4+z,1/4-x,3/4+y'
  '1/2-y,1/2+z,-x'
  '1/2-y,+z,1/2-x'
  '-y,1/2+z,1/2-x'
  '-y,+z,-x'
  '1/4+x,1/4-y,3/4+z'
  '1/4+x,3/4-y,1/4+z'
  '3/4+x,1/4-y,1/4+z'
  '3/4+x,3/4-y,3/4+z'
  '1/2-z,x,1/2-y'
  '1/2-z,1/2+x,-y'
  '-z,x,-y'
  '-z,1/2+x,1/2-y'
  '3/4+y,1/4-z,1/4+x'
  '3/4+y,3/4-z,3/4+x'
  '1/4+y,1/4-z,3/4+x'
  '1/4+y,3/4-z,1/4+x'
  '-x,1/2+y,1/2-z'
  '-x,+y,-z'
  '1/2-x,1/2+y,-z'
  '1/2-x,+y,1/2-z'
  '1/2+x,-z,-y'
  '1/2+x,1/2-z,1/2-y'
  '+x,-z,1/2-y'
  '+x,1/2-z,-y'
  '3/4-z,1/4+y,3/4+x'
  '3/4-z,3/4+y,1/4+x'
  '1/4-z,1/4+y,1/4+x'
  '1/4-z,3/4+y,3/4+x'
  'y,1/2-x,-z'
  'y,-x,1/2-z'
  '1/2+y,1/2-x,1/2-z'
  '1/2+y,-x,-z'
  '1/4-x,1/4+z,1/4+y'
  '1/4-x,3/4+z,3/4+y'
  '3/4-x,1/4+z,3/4+y'
  '3/4-x,3/4+z,1/4+y'
  'z,-y,1/2-x'
  'z,1/2-y,-x'
  '1/2+z,-y,-x'
  '1/2+z,1/2-y,1/2-x'
  '3/4-y,3/4+x,1/4+z'
  '3/4-y,1/4+x,3/4+z'
  '1/4-y,3/4+x,3/4+z'
  '1/4-y,1/4+x,1/4+z'
  'x,1/2+z,y'
  'x,+z,1/2+y'
  '1/2+x,1/2+z,1/2+y'
  '1/2+x,+z,y'
  '1/4-z,1/4-y,1/4-x'
  '1/4-z,3/4-y,3/4-x'
  '3/4-z,1/4-y,3/4-x'
  '3/4-z,3/4-y,1/4-x'
  '1/2+y,x,z'
  '1/2+y,1/2+x,1/2+z'
  '+y,x,1/2+z'
  '+y,1/2+x,z'
  '3/4-x,1/4-z,3/4-y'
  '3/4-x,3/4-z,1/4-y'
  '1/4-x,1/4-z,1/4-y'
  '1/4-x,3/4-z,3/4-y'
  '1/2+z,1/2+y,1/2+x'
  '1/2+z,+y,+x'
  '+z,1/2+y,+x'
  '+z,+y,1/2+x'
  '1/4-y,3/4-x,3/4-z'
  '1/4-y,1/4-x,1/4-z'
  '3/4-y,3/4-x,1/4-z'
  '3/4-y,1/4-x,3/4-z'
  '3/4+z,1/4+x,1/4-y'
  '3/4+z,3/4+x,3/4-y'
  '1/4+z,1/4+x,3/4-y'
  '1/4+z,3/4+x,1/4-y'
  '1/2-y,1/2-z,x'
  '1/2-y,-z,1/2+x'
  '-y,1/2-z,1/2+x'
  '-y,-z,x'
  '1/4+x,3/4+y,1/4-z'
  '1/4+x,1/4+y,3/4-z'
  '3/4+x,3/4+y,3/4-z'
  '3/4+x,1/4+y,1/4-z'
  '1/2-z,-x,1/2+y'
  '1/2-z,1/2-x,+y'
  '-z,-x,+y'
  '-z,1/2-x,1/2+y'
  '3/4+y,3/4+z,3/4-x'
  '3/4+y,1/4+z,1/4-x'
  '1/4+y,3/4+z,1/4-x'
  '1/4+y,1/4+z,3/4-x'
  '-x,1/2-y,1/2+z'
  '-x,-y,+z'
  '1/2-x,1/2-y,+z'
  '1/2-x,-y,1/2+z'
  '1/4-z,3/4+x,1/4+y'
  '1/4-z,1/4+x,3/4+y'
  '3/4-z,3/4+x,3/4+y'
  '3/4-z,1/4+x,1/4+y'
  '1/2+y,-z,1/2-x'
  '1/2+y,1/2-z,-x'
  '+y,-z,-x'
  '+y,1/2-z,1/2-x'
  '3/4-x,1/4+y,1/4+z'
  '3/4-x,3/4+y,3/4+z'
  '1/4-x,1/4+y,3/4+z'
  '1/4-x,3/4+y,1/4+z'
  '1/2+z,1/2-x,-y'
  '1/2+z,-x,1/2-y'
  '+z,1/2-x,1/2-y'
  '+z,-x,-y'
  '1/4-y,1/4+z,3/4+x'
  '1/4-y,3/4+z,1/4+x'
  '3/4-y,1/4+z,1/4+x'
  '3/4-y,3/4+z,3/4+x'
  'x,-y,-z'
  'x,1/2-y,1/2-z'
  '1/2+x,-y,1/2-z'
  '1/2+x,1/2-y,-z'
  '1/2-x,1/2+z,1/2-y'
  '1/2-x,+z,-y'
  '-x,1/2+z,-y'
  '-x,+z,1/2-y'
  '1/4+z,1/4-y,1/4+x'
  '1/4+z,3/4-y,3/4+x'
  '3/4+z,1/4-y,3/4+x'
  '3/4+z,3/4-y,1/4+x'
  '-y,x,1/2-z'
  '-y,1/2+x,-z'
  '1/2-y,x,-z'
  '1/2-y,1/2+x,1/2-z'
  '3/4+x,1/4-z,3/4+y'
  '3/4+x,3/4-z,1/4+y'
  '1/4+x,1/4-z,1/4+y'
  '1/4+x,3/4-z,3/4+y'
  '-z,1/2+y,-x'
  '-z,+y,1/2-x'
  '1/2-z,1/2+y,1/2-x'
  '1/2-z,+y,-x'
  '1/4+y,3/4-x,3/4+z'
  '1/4+y,1/4-x,1/4+z'
  '3/4+y,3/4-x,1/4+z'
  '3/4+y,1/4-x,3/4+z'
  '-x,-z,1/2+y'
  '-x,1/2-z,+y'
  '1/2-x,-z,+y'
  '1/2-x,1/2-z,1/2+y'
  '3/4+z,1/4+y,3/4-x'
  '3/4+z,3/4+y,1/4-x'
  '1/4+z,1/4+y,1/4-x'
  '1/4+z,3/4+y,3/4-x'
  '1/2-y,1/2-x,1/2+z'
  '1/2-y,-x,+z'
  '-y,1/2-x,+z'
  '-y,-x,1/2+z'
  '1/4+x,1/4+z,1/4-y'
  '1/4+x,3/4+z,3/4-y'
  '3/4+x,1/4+z,3/4-y'
  '3/4+x,3/4+z,1/4-y'
  '1/2-z,-y,x'
  '1/2-z,1/2-y,1/2+x'
  '-z,-y,1/2+x'
  '-z,1/2-y,x'
  '3/4+y,3/4+x,1/4-z'
  '3/4+y,1/4+x,3/4-z'
  '1/4+y,3/4+x,3/4-z'
  '1/4+y,1/4+x,1/4-z'
  '1/4-z,1/4-x,3/4-y'
  '1/4-z,3/4-x,1/4-y'
  '3/4-z,1/4-x,1/4-y'
  '3/4-z,3/4-x,3/4-y'
  '1/2+y,z,1/2+x'
  '1/2+y,1/2+z,+x'
  '+y,z,+x'
  '+y,1/2+z,1/2+x'
  '3/4-x,3/4-y,3/4-z'
  '3/4-x,1/4-y,1/4-z'
  '1/4-x,3/4-y,1/4-z'
  '1/4-x,1/4-y,3/4-z'
  '1/2+z,1/2+x,y'
  '1/2+z,+x,1/2+y'
  '+z,1/2+x,1/2+y'
  '+z,+x,y'
  '1/4-y,3/4-z,1/4-x'
  '1/4-y,1/4-z,3/4-x'
  '3/4-y,3/4-z,3/4-x'
  '3/4-y,1/4-z,1/4-x'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
CuM1   0.12500   0.12500   0.12500   0.48400   0.06300
AgM1   0.12500   0.12500   0.12500   0.36600   0.06300
CuM2   0.87500   0.12500   0.12500   0.47500   0.06400
AgM2   0.87500   0.12500   0.12500   0.36800   0.06400
FeM2   0.87500   0.12500   0.12500   0.01100   0.06400
Te   0.00000   0.00000   0.00000   1.00000   0.06800
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
CuM1 0.06300 0.06300 0.06300 0.00000 0.00000 0.00000
AgM1 0.06300 0.06300 0.06300 0.00000 0.00000 0.00000
CuM2 0.06500 0.06300 0.06300 0.00000 0.00000 0.00000
AgM2 0.06500 0.06300 0.06300 0.00000 0.00000 0.00000
FeM2 0.06500 0.06300 0.06300 0.00000 0.00000 0.00000
Te 0.06800 0.06800 0.06800 -0.00100 -0.00100 -0.00100