data_global
_chemical_name_mineral 'Carlinite'
loop_
_publ_author_name
'Man L I'
_journal_name_full 'Soviet Physics Crystallography'
_journal_volume 15 
_journal_year 1970
_journal_page_first 399
_journal_page_last 403
_publ_section_title
;
 Determination of the structure of Tl2S by the electron diffraction method
;
_database_code_amcsd 0015553
_chemical_compound_source 'Synthetic'
_chemical_formula_sum 'Tl2 S'
_cell_length_a 12.20
_cell_length_b 12.20
_cell_length_c 18.17
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 120
_cell_volume 2342.099
_exptl_crystal_density_diffrn      8.439
_symmetry_space_group_name_H-M 'R 3'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '2/3+x,1/3+y,1/3+z'
  '1/3+x,2/3+y,2/3+z'
  '-y,x-y,z'
  '2/3-y,1/3+x-y,1/3+z'
  '1/3-y,2/3+x-y,2/3+z'
  '-x+y,-x,z'
  '2/3-x+y,1/3-x,1/3+z'
  '1/3-x+y,2/3-x,2/3+z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
Tl1   0.11900   0.19100   0.95700   0.01064
Tl2   0.12200   0.20100   0.32100   0.01064
Tl3   0.11800   0.20900   0.65600   0.01064
Tl4   0.23300   0.10300   0.14000   0.01064
Tl5   0.22700   0.09300   0.47400   0.01064
Tl6   0.23300   0.09600   0.80800   0.01064
S1   0.00000   0.00000   0.19500   0.01064
S2   0.00000   0.00000   0.51900   0.01064
S3   0.00000   0.00000   0.85300   0.01064
S4   0.66500   0.65700   0.22600   0.01064
S5   0.33300   0.33700   0.19500   0.01064