data_global
_chemical_name_mineral 'Mineevite-(Y)'
loop_
_publ_author_name
'Yamonva N A'
'Pushcharovskii D Y'
'Vyatkin S V'
'Khomyakov A P'
_journal_name_full 'Soviet Physics Crystallography'
_journal_volume 37 
_journal_year 1992
_journal_page_first 753
_journal_page_last 756
_publ_section_title
;
 Crystal structure of the new native sulfate-carbonate
 Na25BaTR2(CO3)11(HCO3)4(SO4)2F2Cl
 Note: OH occupancies chosen to reproduce chemical formula
;
_database_code_amcsd 0015592
_chemical_compound_source 'Lovozero pegmatites, Kola peninsula, Russia'
_chemical_formula_sum 'Na25 Ba (Y1.1 Gd.5 Dy.4) C15 S2 O53 F2 Cl H4'
_cell_length_a 8.811
_cell_length_b 8.811
_cell_length_c 37.03
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 120
_cell_volume 2489.629
_exptl_crystal_density_diffrn      2.832
_symmetry_space_group_name_H-M 'P 63/m'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '-x+y,-x,1/2-z'
  'x-y,x,1/2+z'
  'y,-x+y,-z'
  '-y,x-y,z'
  'x,y,1/2-z'
  '-x,-y,1/2+z'
  'x-y,x,-z'
  '-x+y,-x,z'
  '-y,x-y,1/2-z'
  'y,-x+y,1/2+z'
  '-x,-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
Na1   0.09950   0.44780   0.03330   1.00000   0.00633
Na2   0.09890   0.44970   0.32490   1.00000   0.01393
Na3   0.33333   0.66667   0.69160   1.00000   0.00380
Na4   0.11230   0.67070   0.60640   1.00000   0.01140
Na5   0.35700   0.37700   0.25000   1.00000   0.01013
Na6   0.00000   0.00000   0.39740   1.00000   0.00887
Ba   0.00000   0.00000   0.00000   1.00000   0.00608
Y   0.00000   0.00000   0.19842   0.55000   0.00633
Gd   0.00000   0.00000   0.19842   0.25000   0.00633
Dy   0.00000   0.00000   0.19842   0.20000   0.00633
C1   0.07700   0.34800   0.54650   1.00000   0.00380
C2   0.35500   0.07200   0.25000   1.00000   0.00253
C3   0.06900   0.31600   0.66280   1.00000   0.00253
S   0.33333   0.66667   0.39300   1.00000   0.00127
O1   0.25100   0.11300   0.05940   0.75000   0.00887
O-H1   0.25100   0.11300   0.05940   0.25000   0.00887
O2   0.22400   0.08800   0.15090   1.00000   0.00127
O3   0.09200   0.65600   0.72020   1.00000   0.01140
O4   0.10900   0.46600   0.64930   1.00000   0.00633
O5   0.18600   0.02500   0.25000   0.66667   0.00887
O-H5   0.18600   0.02500   0.25000   0.33333   0.00887
O6   0.33200   0.03800   0.52300   1.00000   0.00507
O7   0.15000   0.51000   0.55910   0.75000   0.00380
O-H7   0.15000   0.51000   0.55910   0.25000   0.00380
O8   0.24800   0.29200   0.31060   1.00000   0.00127
O9   0.18700   0.49600   0.40580   1.00000   0.01140
O10   0.33333   0.66667   0.35190   1.00000   0.00253
F   0.33333   0.66667   0.50220   1.00000   0.00253
Cl   0.33333   0.66667   0.25000   1.00000   0.01140