Warikahnite Riffel H, Keller P, Hess H Tschermaks Mineralogische und Petrographische Mitteilungen 27 (1980) 187-199 Die kristallstruktur von warikahnit, Zn3[(H2O)2|(AsO4)2] Locality: Tsumeb mine, Namibia _database_code_amcsd 0015678 CELL PARAMETERS: 6.7100 8.9890 14.5330 105.590 93.440 108.680 SPACE GROUP: P-1 X-RAY WAVELENGTH: 1.541838 Cell Volume: 789.532 Density (g/cm3): 4.327 MAX. ABS. INTENSITY / VOLUME**2: 13.71903988 RIR: 1.032 RIR based on corundum from Acta Crystallographica A38 (1982) 733-739 2-THETA INTENSITY D-SPACING H K L Multiplicity 6.40 46.76 13.8178 0 0 1 2 10.91 37.75 8.1110 0 1 0 2 12.81 6.96 6.9089 0 0 2 2 14.08 11.76 6.2892 0 -1 2 2 14.11 46.32 6.2745 1 0 0 2 14.25 72.76 6.2170 0 1 1 2 14.51 22.86 6.1027 -1 1 0 2 15.44 5.57 5.7404 1 -1 1 2 16.30 2.00 5.4369 -1 1 1 2 16.42 1.23 5.3971 1 0 1 2 19.27 12.50 4.6059 0 0 3 2 19.94 4.99 4.4517 -1 -1 1 2 20.11 2.38 4.4158 -1 1 2 2 20.59 8.04 4.3139 1 0 2 2 20.71 2.44 4.2894 1 1 0 2 20.86 1.69 4.2575 0 -2 1 2 21.17 2.17 4.1973 1 -2 1 2 21.77 5.53 4.0820 0 -2 2 2 21.92 2.48 4.0555 0 2 0 2 22.04 3.04 4.0337 -1 0 3 2 23.32 9.14 3.8148 1 1 1 2 23.33 4.67 3.8135 1 -1 3 2 24.23 1.90 3.6735 -1 -1 3 2 24.43 13.86 3.6434 0 -2 3 2 24.69 13.80 3.6059 0 2 1 2 24.97 8.30 3.5660 0 1 3 2 25.06 5.71 3.5531 -1 1 3 2 25.76 18.16 3.4582 1 0 3 2 25.79 42.44 3.4544 0 0 4 2 25.87 22.71 3.4440 1 -2 3 2 27.13 3.07 3.2864 -2 1 1 2 27.34 7.67 3.2616 -1 2 2 2 27.41 6.67 3.2542 -1 0 4 2 27.71 2.03 3.2193 2 -1 1 2 28.14 41.79 3.1710 -2 0 1 2 28.45 27.30 3.1373 2 0 0 2 28.72 1.65 3.1085 0 2 2 2 28.75 41.95 3.1056 1 -1 4 2 28.84 1.71 3.0953 -1 -2 1 2 29.12 1.83 3.0665 -2 1 2 2 29.27 33.47 3.0514 -2 2 0 2 29.32 85.15 3.0460 -2 0 2 2 29.51 23.95 3.0267 2 -2 1 2 30.12 24.47 2.9672 1 -3 1 2 30.13 2.72 2.9656 1 2 0 2 30.15 8.46 2.9644 1 -2 4 2 30.20 9.16 2.9597 2 -1 2 2 30.21 10.82 2.9588 2 0 1 2 30.46 3.84 2.9346 -2 2 1 2 30.54 2.70 2.9275 1 -3 2 2 30.84 2.78 2.8993 0 -1 5 2 31.08 89.91 2.8779 0 1 4 2 31.10 3.29 2.8754 -1 3 0 2 31.16 13.75 2.8702 2 -2 2 2 31.50 9.52 2.8401 1 0 4 2 31.65 100.00 2.8268 0 -3 2 2 31.73 37.88 2.8201 0 -3 1 2 31.84 2.05 2.8107 -2 0 3 2 31.94 1.71 2.8020 -1 2 3 2 32.13 2.92 2.7856 1 1 3 2 32.35 5.86 2.7673 -2 1 3 2 32.91 1.89 2.7214 0 -3 3 2 32.95 15.18 2.7185 -2 2 2 2 33.21 8.63 2.6978 0 -2 5 2 33.27 2.41 2.6932 -1 0 5 2 33.38 1.05 2.6841 -1 3 1 2 33.44 1.54 2.6798 -1 -2 4 2 33.48 11.03 2.6763 -2 -1 2 2 33.49 27.99 2.6760 -1 -1 5 2 34.03 1.56 2.6344 2 -2 3 2 34.06 9.93 2.6325 2 1 0 2 35.10 3.77 2.5567 -2 -1 3 2 35.19 3.87 2.5502 1 -2 5 2 35.38 3.18 2.5368 0 -3 4 2 35.44 8.50 2.5330 -2 0 4 2 35.44 28.41 2.5326 -2 3 0 2 35.73 3.00 2.5131 0 3 1 2 36.19 1.17 2.4818 2 1 1 2 36.36 3.78 2.4710 1 2 2 2 36.50 4.38 2.4619 -2 2 3 2 36.53 3.81 2.4596 -2 1 4 2 37.17 2.93 2.4190 2 0 3 2 37.20 11.09 2.4168 -1 2 4 2 37.27 4.93 2.4124 -1 -2 5 2 37.61 1.31 2.3918 1 0 5 2 37.88 19.44 2.3751 2 -2 4 2 38.28 1.52 2.3511 2 -1 4 2 38.64 11.37 2.3304 0 -2 6 2 39.06 2.78 2.3059 0 2 4 2 39.07 13.45 2.3055 -1 -1 6 2 39.11 17.31 2.3030 0 0 6 2 39.13 9.52 2.3021 -1 -3 1 2 39.15 10.41 2.3012 1 -3 5 2 39.31 7.61 2.2920 0 3 2 2 39.34 1.32 2.2905 -1 -3 3 2 39.37 17.71 2.2888 2 1 2 2 39.77 1.34 2.2664 -2 3 2 2 40.17 2.74 2.2447 1 -4 2 2 40.42 4.63 2.2316 1 -4 1 2 40.70 2.89 2.2170 1 3 0 2 40.95 1.29 2.2037 -1 3 3 2 41.06 1.36 2.1985 -3 2 0 2 41.09 4.97 2.1965 -1 -3 4 2 41.43 4.92 2.1797 -2 1 5 2 41.49 1.83 2.1763 -2 -1 5 2 41.60 15.74 2.1708 -3 1 2 2 41.62 1.05 2.1701 3 -2 1 2 41.73 1.90 2.1646 3 -1 1 2 41.88 3.39 2.1569 2 0 4 2 42.46 4.62 2.1287 0 -4 2 2 42.67 3.09 2.1188 -3 0 1 2 42.92 1.35 2.1071 1 -4 4 2 43.07 6.73 2.1002 0 -4 1 2 43.15 4.26 2.0964 0 -3 6 2 43.26 5.73 2.0915 3 0 0 2 43.38 3.59 2.0861 -2 3 3 2 43.39 6.43 2.0856 2 1 3 2 43.40 2.79 2.0852 2 -1 5 2 43.49 1.74 2.0810 1 1 5 2 43.68 1.39 2.0723 0 3 3 2 43.83 5.53 2.0654 -1 -3 5 2 43.87 2.05 2.0638 3 -1 2 2 43.87 1.59 2.0637 -2 4 0 2 44.02 2.37 2.0569 0 1 6 2 44.27 1.39 2.0460 2 -4 3 2 44.47 3.49 2.0375 2 2 1 2 44.54 4.24 2.0342 3 -3 1 2 44.60 1.13 2.0317 2 -3 5 2 44.94 1.98 2.0169 -2 0 6 2 44.97 2.69 2.0159 0 2 5 2 45.55 1.26 1.9916 -3 3 1 2 45.76 1.46 1.9829 1 -4 5 2 45.76 2.26 1.9827 -2 4 1 2 46.65 2.16 1.9471 -3 1 4 2 46.71 4.72 1.9448 1 3 2 2 46.87 3.28 1.9384 -2 1 6 2 46.91 1.50 1.9367 3 -1 3 2 47.35 8.35 1.9199 1 -1 7 2 47.52 3.26 1.9135 3 -3 3 2 47.73 5.68 1.9056 -2 3 4 2 48.09 1.28 1.8919 2 1 4 2 49.05 4.02 1.8574 -3 2 4 2 49.09 2.70 1.8560 -1 2 6 2 49.41 4.86 1.8446 1 -4 6 2 49.57 2.30 1.8390 -1 1 7 2 49.68 16.67 1.8350 -2 -3 3 2 49.75 1.73 1.8329 1 1 6 2 50.07 1.26 1.8217 0 -4 6 2 50.08 1.30 1.8215 3 -4 1 2 50.32 2.21 1.8133 -3 0 5 2 50.42 1.20 1.8099 -3 1 5 2 50.53 2.39 1.8062 -2 0 7 2 50.56 4.54 1.8054 -3 4 0 2 50.57 1.00 1.8050 0 -1 8 2 50.63 12.99 1.8030 0 4 2 2 50.65 6.73 1.8022 1 0 7 2 50.74 2.76 1.7992 3 -1 4 2 50.75 1.11 1.7988 0 -2 8 2 50.83 3.51 1.7962 -2 -3 4 2 51.13 1.30 1.7864 1 -5 3 2 51.26 1.67 1.7821 -1 4 3 2 51.49 2.50 1.7749 1 2 5 2 51.65 2.04 1.7697 2 2 3 2 51.72 1.37 1.7674 -1 -3 7 2 52.14 1.27 1.7541 -2 4 3 2 52.18 1.18 1.7528 2 -5 2 2 52.53 1.28 1.7419 2 -5 1 2 52.73 5.60 1.7358 2 -5 3 2 52.77 1.91 1.7348 -2 1 7 2 52.87 2.16 1.7318 -3 -1 5 2 52.95 1.26 1.7291 2 0 6 2 53.13 1.01 1.7239 1 -2 8 2 53.15 2.06 1.7231 -3 2 5 2 53.19 1.18 1.7220 2 -4 6 2 53.33 7.32 1.7178 3 -2 5 2 53.56 1.93 1.7110 0 -3 8 2 53.77 2.10 1.7047 -2 5 0 2 53.95 2.23 1.6994 -2 -2 7 2 53.97 1.50 1.6989 3 -3 5 2 54.10 1.01 1.6952 3 -4 4 2 54.17 2.37 1.6933 2 -5 4 2 54.18 1.82 1.6928 -3 -2 2 2 54.21 3.31 1.6921 0 3 5 2 54.29 11.53 1.6898 1 -5 5 2 54.71 1.02 1.6777 1 -3 8 2 54.73 1.10 1.6771 0 4 3 2 54.83 1.25 1.6743 3 0 4 2 54.87 12.76 1.6732 -4 2 0 2 54.87 3.65 1.6731 -3 1 6 2 55.07 2.95 1.6677 -1 -4 6 2 55.25 1.94 1.6627 3 -1 5 2 55.31 1.57 1.6609 -4 1 1 2 55.55 2.49 1.6544 -1 5 1 2 55.63 1.48 1.6522 4 -2 1 2 55.65 8.16 1.6516 -4 1 0 2 55.71 2.26 1.6500 -2 -3 6 2 55.76 3.06 1.6487 -3 -2 4 2 55.86 8.59 1.6459 -2 5 1 2 55.96 2.86 1.6432 -4 2 2 2 56.33 1.05 1.6333 1 1 7 2 56.42 1.55 1.6308 -2 4 4 2 56.43 5.69 1.6306 2 -5 5 2 56.56 5.58 1.6271 -2 0 8 2 56.60 2.51 1.6261 -4 3 0 2 56.84 3.15 1.6197 4 -1 1 2 56.90 1.39 1.6182 4 -3 1 2 57.11 1.46 1.6128 3 -4 5 2 57.17 2.15 1.6113 -1 3 6 2 57.23 3.95 1.6096 4 -2 2 2 57.50 2.02 1.6029 2 3 2 2 57.57 19.95 1.6010 1 0 8 2 57.65 2.84 1.5990 3 -5 2 2 57.68 1.47 1.5982 3 -5 1 2 57.90 3.28 1.5927 -3 2 6 2 58.10 3.45 1.5877 3 -2 6 2 58.19 1.51 1.5855 -4 0 2 2 58.20 5.17 1.5852 -2 3 6 2 58.54 5.78 1.5768 -1 -4 7 2 58.73 4.26 1.5722 -1 5 2 2 58.87 1.08 1.5686 4 0 0 2 58.91 1.18 1.5677 -1 -2 9 2 59.10 3.64 1.5632 -4 0 3 2 59.14 1.23 1.5622 2 1 6 2 59.15 1.14 1.5619 2 0 7 2 59.29 1.44 1.5585 -2 -3 7 2 59.35 1.99 1.5572 0 5 1 2 59.47 1.68 1.5543 2 -5 6 2 59.47 1.78 1.5543 0 4 4 2 59.50 2.77 1.5536 0 -3 9 2 59.67 11.31 1.5497 -1 0 9 2 59.82 1.36 1.5461 1 -2 9 2 60.11 3.81 1.5392 -2 -4 4 2 60.20 1.26 1.5372 0 3 6 2 60.28 1.79 1.5353 0 0 9 2 60.37 8.33 1.5332 -4 2 4 2 60.43 4.13 1.5320 -3 -1 7 2 60.57 3.77 1.5288 4 -4 1 2 60.64 1.57 1.5272 -3 -2 6 2 60.65 2.30 1.5269 1 -5 7 2 60.73 1.96 1.5251 -4 3 3 2 60.87 5.65 1.5220 1 -3 9 2 61.08 1.88 1.5171 -1 -5 4 2 61.10 1.99 1.5166 -1 4 5 2 61.11 2.05 1.5164 3 1 4 2 61.25 3.71 1.5134 4 -4 2 2 61.52 3.32 1.5074 2 -1 8 2 61.52 1.15 1.5073 -2 -4 5 2 62.01 3.30 1.4966 0 -5 7 2 62.05 1.47 1.4957 1 4 3 2 62.32 1.62 1.4899 1 -6 3 2 62.38 2.05 1.4886 -1 2 8 2 62.50 2.97 1.4860 3 -5 5 2 62.60 4.35 1.4839 -3 -3 3 2 62.61 1.25 1.4838 -1 5 3 2 62.61 1.61 1.4836 2 -6 2 2 62.65 5.01 1.4828 2 4 0 2 62.69 3.17 1.4819 -1 -4 8 2 62.79 1.81 1.4799 4 -2 4 2 62.81 2.72 1.4794 4 0 2 2 62.83 5.32 1.4790 -4 -1 2 2 62.92 3.32 1.4772 1 -6 4 2 63.00 2.22 1.4754 -2 0 9 2 63.22 1.49 1.4708 2 -5 7 2 63.31 3.22 1.4690 -3 -3 4 2 63.34 1.48 1.4683 2 -6 1 2 63.43 3.52 1.4665 3 -2 7 2 63.54 2.21 1.4642 1 -6 1 2 63.58 1.07 1.4633 -3 -3 1 2 63.67 1.60 1.4616 -4 3 4 2 64.19 1.20 1.4510 -2 3 7 2 64.20 1.32 1.4507 -3 0 8 2 64.22 4.10 1.4503 1 -4 9 2 64.38 1.54 1.4471 -1 -5 6 2 64.53 1.70 1.4440 -4 -1 4 2 64.81 1.02 1.4386 -3 -3 5 2 64.84 6.00 1.4380 3 0 6 2 64.85 1.17 1.4377 -2 6 0 2 64.87 3.71 1.4374 1 -5 8 2 65.15 1.98 1.4319 4 -1 4 2 65.23 1.40 1.4303 3 -4 7 2 65.26 3.53 1.4298 2 4 1 2 65.51 3.93 1.4248 -3 1 8 2 65.64 2.74 1.4223 3 -5 6 2 65.81 2.73 1.4192 0 -6 3 2 65.96 1.57 1.4163 3 1 5 2 66.06 1.21 1.4144 2 -3 9 2 66.11 1.31 1.4134 0 -6 4 2 66.22 1.75 1.4113 4 1 1 2 66.29 1.85 1.4101 0 -6 2 2 66.53 1.67 1.4055 3 -6 2 2 66.54 1.74 1.4054 -4 0 6 2 66.55 1.64 1.4051 -4 -1 5 2 66.63 1.54 1.4036 4 -5 2 2 66.64 1.75 1.4035 4 -2 5 2 66.71 3.39 1.4021 0 5 3 2 66.87 1.23 1.3991 3 -6 3 2 66.96 10.03 1.3976 1 3 6 2 66.97 2.73 1.3972 -1 0 10 2 67.16 2.79 1.3938 -1 -5 7 2 67.21 1.03 1.3928 2 2 6 2 67.44 1.69 1.3886 1 -3 10 2 68.08 1.70 1.3772 -1 -3 10 2 68.39 4.18 1.3716 -3 -2 8 2 68.42 2.44 1.3711 -2 -3 9 2 68.65 1.84 1.3671 3 -3 8 2 69.04 4.90 1.3603 -3 2 8 2 69.33 1.05 1.3554 1 -6 7 2 69.42 1.90 1.3538 4 -5 4 2 69.48 3.65 1.3529 3 -5 7 2 69.78 3.67 1.3478 -3 5 4 2 69.86 1.07 1.3464 3 -6 5 2 70.04 4.27 1.3434 -3 -3 7 2 70.23 1.38 1.3401 -4 -2 1 2 70.25 3.75 1.3399 -1 3 8 2 70.26 3.89 1.3397 -4 5 2 2 70.29 1.00 1.3392 4 -3 6 2 70.31 1.33 1.3388 -4 1 7 2 70.37 1.00 1.3380 -2 -2 10 2 70.42 3.15 1.3371 -3 4 6 2 70.64 1.72 1.3334 -1 -5 8 2 70.82 2.45 1.3305 3 3 2 2 71.38 1.03 1.3214 3 1 6 2 71.70 3.18 1.3162 4 2 0 2 72.26 1.75 1.3075 -1 5 5 2 72.27 1.55 1.3074 0 6 1 2 72.30 1.28 1.3069 -3 -4 3 2 72.86 2.52 1.2982 -1 -6 3 2 72.88 1.31 1.2978 -1 -6 4 2 73.03 3.42 1.2956 -4 5 3 2 73.31 1.46 1.2913 5 -1 1 2 73.96 1.09 1.2816 3 -5 8 2 74.13 2.43 1.2791 4 -1 6 2 74.55 2.63 1.2728 -1 -3 11 2 75.15 1.27 1.2643 1 -5 10 2 75.67 1.95 1.2569 3 -2 9 2 76.82 1.45 1.2409 4 2 2 2 77.48 1.16 1.2319 2 5 1 2 77.98 1.44 1.2253 -1 5 6 2 78.15 1.07 1.2231 -2 6 4 2 78.42 1.45 1.2194 5 -2 4 2 78.58 1.19 1.2173 5 -5 2 2 79.07 1.39 1.2111 3 -5 9 2 79.46 2.62 1.2061 -3 5 6 2 82.04 1.74 1.1747 1 -6 10 2 82.10 1.20 1.1739 -4 3 8 2 82.42 1.09 1.1701 -5 -1 5 2 82.76 1.05 1.1662 -1 0 12 2 83.12 1.01 1.1621 -3 0 11 2 83.14 1.72 1.1618 -2 6 5 2 83.33 2.26 1.1597 4 -7 3 2 83.39 1.18 1.1589 4 3 1 2 83.41 1.07 1.1587 0 7 0 2 84.25 1.18 1.1493 3 3 5 2 84.36 2.16 1.1481 5 -5 5 2 84.70 1.20 1.1444 4 2 4 2 84.74 1.05 1.1439 -3 -2 11 2 85.19 1.29 1.1390 -1 3 10 2 85.32 1.29 1.1377 -1 -4 12 2 85.40 1.04 1.1367 -3 -5 6 2 88.48 1.09 1.1050 -5 6 2 2 89.85 1.31 1.0917 -4 -4 6 2 ================================================================================ XPOW Copyright 1993 Bob Downs, Ranjini Swaminathan and Kurt Bartelmehs For reference, see Downs et al. (1993) American Mineralogist 78, 1104-1107.