data_global
_chemical_name_mineral 'Friedelite'
loop_
_publ_author_name
'Kato T'
'Watanabe I'
_journal_name_full 'Yamaguchi University, College of Arts Bulletin'
_journal_volume 26 
_journal_year 1992
_journal_page_first 51
_journal_page_last 63
_publ_section_title
;
 The crystal structures of schallerite and friedelite
;
_database_code_amcsd 0015711
_chemical_compound_source 'Aderville, France'
_chemical_formula_sum 'Mn8 Si6 O24 Cl H9'
_cell_length_a 23.28
_cell_length_b 13.44
_cell_length_c 7.428
_cell_angle_alpha 90
_cell_angle_beta 104.98
_cell_angle_gamma 90
_cell_volume 2245.115
_exptl_crystal_density_diffrn      3.067
_symmetry_space_group_name_H-M 'C 1 2/m 1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2+y,z'
  'x,-y,z'
  '1/2+x,1/2-y,z'
  '-x,y,-z'
  '1/2-x,1/2+y,-z'
  '-x,-y,-z'
  '1/2-x,1/2-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
Mn1   0.00000   0.12360   0.00000   0.00595
Mn2   0.00000   0.37110   0.00000   0.01343
Mn3   0.12760   0.00000   0.01940   0.00887
Mn4   0.12680   0.24860   0.01000   0.00975
Mn5   0.12570   0.50000  -0.01320   0.01254
Mn6   0.25210   0.12460   0.01810   0.00798
Si1   0.20740   0.38660   0.37280   0.02710
Si2   0.32170   0.26740   0.37690   0.02305
Si3   0.44340   0.38250   0.36910   0.02685
O1   0.00000   0.16570   0.50000   0.10183
O2   0.06250   0.00000   0.57000   0.21708
O3   0.11470   0.16470   0.58600   0.15667
O4   0.16560   0.32870   0.49500   0.13058
O5   0.22500   0.16700   0.55300   0.09195
O6   0.28660   0.00000   0.58000   0.26723
O7   0.17870   0.37310   0.15530   0.00304
O8   0.30640   0.25040   0.15500   0.01127
O9   0.42670   0.37830   0.14450   0.00139
O-H1   0.05700   0.00000   0.17570   0.01393
O-H2   0.05650   0.24770   0.15960   0.00747
Cl3   0.06030   0.50000   0.22070   0.00747
O-H4   0.17670   0.12600   0.15010   0.00266
O-H5   0.30360   0.00000   0.15800   0.00963
O-H6   0.30510   0.50000   0.15710   0.00469
O-H7   0.42720   0.12570   0.14460   0.00532