Cu H8 Na4 O22 P6 Durif A, Averbuch-Pouchot M Zeitschrift fur Anorganische und Allgemeine Chemie 514 (1984) 85-91 Preparation and Crystal Structure of Copper Tetrasodium Trimetaphosphate Tetrahydrate: Cu Na4 (P3 O9)2 (H2O)4 _cod_database_code 1007134 _database_code_amcsd 0015789 CELL PARAMETERS: 7.8970 8.3610 7.1150 102.550 97.850 84.000 SPACE GROUP: P-1 X-RAY WAVELENGTH: 1.541838 Cell Volume: 452.896 Density (g/cm3): 2.571 MAX. ABS. INTENSITY / VOLUME**2: 4.969148963 RIR: 0.629 RIR based on corundum from Acta Crystallographica A38 (1982) 733-739 2-THETA INTENSITY D-SPACING H K L Multiplicity 11.34 72.87 7.7995 1 0 0 2 12.84 1.10 6.8971 0 0 1 2 15.03 5.07 5.8944 0 -1 1 2 15.11 100.00 5.8618 1 1 0 2 16.13 33.02 5.4965 -1 0 1 2 17.38 35.28 5.1017 -1 -1 1 2 18.14 8.66 4.8899 1 0 1 2 18.50 39.55 4.7963 0 1 1 2 20.25 20.29 4.3844 1 -1 1 2 21.40 12.12 4.1527 -1 1 1 2 22.10 19.61 4.0216 1 1 1 2 22.80 1.26 3.8998 2 0 0 2 22.98 32.52 3.8705 0 -2 1 2 23.87 1.14 3.7274 1 2 0 2 24.20 43.31 3.6773 -1 -2 1 2 24.54 23.44 3.6279 2 1 0 2 24.88 32.44 3.5793 -2 0 1 2 25.34 20.23 3.5150 -2 -1 1 2 25.47 2.13 3.4978 -1 2 0 2 25.84 1.13 3.4485 0 0 2 2 25.90 20.35 3.4400 0 -1 2 2 26.09 3.63 3.4152 -2 1 0 2 26.71 51.59 3.3374 -1 -1 2 2 27.02 3.03 3.3004 -1 0 2 2 27.11 11.50 3.2892 1 -2 1 2 27.56 41.43 3.2360 2 0 1 2 28.99 71.47 3.0805 -2 1 1 2 29.37 2.17 3.0410 2 -1 1 2 29.52 1.01 3.0255 1 0 2 2 29.91 34.33 2.9874 1 2 1 2 29.92 38.89 2.9867 1 -1 2 2 30.05 13.16 2.9739 2 1 1 2 30.05 22.31 2.9737 -1 2 1 2 30.16 33.08 2.9633 0 1 2 2 30.33 1.41 2.9472 0 -2 2 2 30.71 1.20 2.9115 -1 -2 2 2 31.51 17.62 2.8394 -1 1 2 2 32.01 11.90 2.7958 -2 -1 2 2 32.58 4.80 2.7483 -2 0 2 2 32.90 29.52 2.7224 0 -3 1 2 33.03 19.56 2.7123 -2 2 0 2 33.03 2.28 2.7122 0 3 0 2 33.11 4.64 2.7057 1 1 2 2 33.49 5.41 2.6756 -1 -3 1 2 34.15 25.18 2.6256 1 3 0 2 34.16 9.09 2.6246 1 -2 2 2 34.50 11.59 2.5998 3 0 0 2 35.18 10.89 2.5509 -2 -2 2 2 35.42 5.26 2.5340 3 1 0 2 36.02 3.26 2.4934 2 2 1 2 36.27 27.51 2.4765 1 -3 1 2 37.36 10.16 2.4071 2 -1 2 2 37.50 2.95 2.3981 0 2 2 2 37.74 3.08 2.3839 0 -3 2 2 38.43 2.95 2.3423 0 -1 3 2 38.53 1.26 2.3364 -1 -1 3 2 38.95 1.70 2.3121 2 3 0 2 39.51 5.39 2.2810 2 1 2 2 39.54 2.87 2.2794 1 3 1 2 39.54 4.27 2.2789 -1 0 3 2 39.72 8.82 2.2694 1 2 2 2 40.03 1.19 2.2523 3 -1 1 2 40.04 17.36 2.2520 3 1 1 2 40.16 1.02 2.2451 -1 3 1 2 40.76 3.63 2.2139 -1 -2 3 2 40.92 4.37 2.2057 0 -2 3 2 40.95 9.76 2.2040 -3 0 2 2 41.18 1.59 2.1922 2 -2 2 2 41.22 2.93 2.1903 1 -3 2 2 41.34 4.55 2.1841 -2 -3 2 2 42.02 3.74 2.1500 -2 3 0 2 42.09 6.08 2.1468 -2 -1 3 2 42.63 9.56 2.1211 -3 -2 2 2 42.70 2.90 2.1176 -3 2 0 2 43.28 8.08 2.0907 -2 0 3 2 43.59 5.31 2.0764 -2 2 2 2 43.61 5.52 2.0756 -1 1 3 2 43.72 4.97 2.0703 0 -4 1 2 43.95 3.16 2.0601 -1 -4 1 2 44.37 5.83 2.0414 1 -2 3 2 44.61 3.92 2.0310 3 -2 1 2 44.62 6.76 2.0306 3 2 1 2 44.92 2.01 2.0177 -3 2 1 2 45.83 2.77 1.9800 -1 -3 3 2 46.48 6.09 1.9539 3 3 0 2 46.58 9.02 1.9499 4 0 0 2 46.73 1.99 1.9440 -4 -1 1 2 46.76 3.46 1.9427 -1 -4 2 2 46.85 9.01 1.9392 3 -1 2 2 46.91 3.94 1.9368 -4 0 1 2 46.95 1.89 1.9353 0 -4 2 2 47.03 10.23 1.9322 -1 4 0 2 47.08 3.06 1.9304 4 1 0 2 47.30 5.79 1.9217 -2 1 3 2 47.31 4.24 1.9215 -2 -4 1 2 48.07 1.40 1.8928 -1 3 2 2 48.21 3.80 1.8876 3 1 2 2 48.25 1.05 1.8861 2 0 3 2 48.48 2.12 1.8776 -3 -1 3 2 48.51 1.76 1.8765 -2 -3 3 2 48.87 1.65 1.8637 2 4 0 2 49.39 9.93 1.8453 0 2 3 2 49.77 1.57 1.8322 -3 0 3 2 49.85 1.23 1.8294 -4 1 1 2 50.12 3.10 1.8200 -1 2 3 2 50.12 1.09 1.8199 1 -4 2 2 50.30 1.20 1.8141 3 -2 2 2 50.47 2.31 1.8082 -3 3 0 2 50.86 1.05 1.7952 -3 2 2 2 51.13 17.03 1.7864 2 1 3 2 51.18 14.38 1.7849 -1 4 1 2 51.20 3.76 1.7841 4 1 1 2 51.53 1.15 1.7736 3 -3 1 2 51.56 3.05 1.7724 1 2 3 2 51.59 1.44 1.7715 -1 -1 4 2 52.31 9.63 1.7489 -2 4 0 2 52.86 2.34 1.7320 3 2 2 2 53.03 5.02 1.7268 -1 0 4 2 53.11 3.68 1.7243 -1 -4 3 2 53.66 3.72 1.7081 0 -4 3 2 54.02 1.07 1.6975 2 4 1 2 54.42 2.13 1.6861 -4 1 2 2 55.13 2.43 1.6659 3 4 0 2 55.34 1.24 1.6602 -2 -4 3 2 55.66 1.48 1.6513 4 -2 1 2 55.70 5.73 1.6502 -2 0 4 2 55.90 1.03 1.6447 4 3 0 2 56.10 7.99 1.6395 3 -3 2 2 56.33 1.64 1.6334 -4 -3 2 2 56.82 1.93 1.6204 0 1 4 2 56.91 8.36 1.6180 4 0 2 2 56.93 1.57 1.6174 -1 1 4 2 57.01 1.62 1.6154 -4 -1 3 2 57.06 1.64 1.6142 -1 -5 2 2 57.42 11.33 1.6049 0 -5 2 2 57.66 1.61 1.5988 0 3 3 2 57.92 2.54 1.5920 -2 -5 1 2 58.35 1.25 1.5814 -4 0 3 2 58.39 1.94 1.5804 -2 -3 4 2 58.51 4.39 1.5774 -1 3 3 2 58.52 1.12 1.5771 4 1 2 2 58.95 1.14 1.5667 3 -2 3 2 59.19 6.21 1.5610 -3 -1 4 2 59.47 4.14 1.5544 5 1 0 2 59.71 2.35 1.5486 -3 2 3 2 59.86 1.02 1.5451 -3 4 0 2 60.12 2.49 1.5391 -3 -4 3 2 60.23 1.15 1.5364 3 -4 1 2 60.39 1.54 1.5328 1 -5 2 2 60.75 1.53 1.5247 4 3 1 2 60.85 11.24 1.5223 -5 -2 1 2 60.93 1.43 1.5205 4 -2 2 2 61.15 2.07 1.5156 0 5 1 2 61.38 3.19 1.5105 -5 1 0 2 61.48 1.49 1.5081 -5 -1 2 2 61.55 2.45 1.5068 -4 -3 3 2 61.82 1.01 1.5008 1 5 1 2 61.87 4.15 1.4996 4 -3 1 2 62.16 2.65 1.4933 2 -2 4 2 62.26 2.22 1.4911 -1 -4 4 2 62.46 1.11 1.4869 -2 4 2 2 62.71 2.42 1.4817 0 2 4 2 62.88 5.09 1.4779 -3 -3 4 2 62.90 1.77 1.4775 -5 -2 2 2 63.09 1.11 1.4736 0 -4 4 2 63.11 1.07 1.4732 2 -5 1 2 63.52 6.19 1.4645 3 2 3 2 63.64 2.06 1.4621 -2 5 0 2 63.84 2.46 1.4580 3 -4 2 2 63.95 7.04 1.4558 -2 -5 3 2 64.31 1.78 1.4485 2 1 4 2 64.91 1.30 1.4366 1 2 4 2 65.13 2.31 1.4322 -5 -3 1 2 66.57 1.34 1.4048 -5 -3 2 2 67.47 1.54 1.3881 0 4 3 2 67.64 1.86 1.3852 -2 -1 5 2 67.84 1.57 1.3816 5 -2 1 2 67.96 1.56 1.3794 0 0 5 2 68.26 1.07 1.3740 3 -1 4 2 68.66 1.04 1.3670 0 5 2 2 68.69 1.14 1.3665 -3 4 2 2 68.92 2.08 1.3625 -1 -3 5 2 68.99 1.30 1.3612 0 -6 2 2 69.04 1.51 1.3603 4 -2 3 2 69.29 1.77 1.3561 0 6 0 2 70.11 4.94 1.3423 -1 5 2 2 70.41 1.29 1.3372 3 -4 3 2 70.74 2.37 1.3318 1 0 5 2 71.01 2.62 1.3273 -4 -5 2 2 71.40 2.31 1.3211 2 -5 3 2 71.51 1.33 1.3194 -1 1 5 2 71.67 2.02 1.3169 -4 4 1 2 71.77 1.96 1.3152 -2 4 3 2 72.40 2.48 1.3052 1 3 4 2 72.58 1.05 1.3025 -1 -6 3 2 72.59 3.49 1.3024 4 2 3 2 72.90 1.81 1.2976 2 5 2 2 72.91 1.27 1.2974 5 -2 2 2 73.11 1.04 1.2944 1 -3 5 2 73.64 4.32 1.2864 5 -3 1 2 73.82 1.96 1.2837 -3 5 1 2 73.89 1.63 1.2826 -2 5 2 2 73.91 1.59 1.2824 -3 0 5 2 74.38 3.72 1.2754 -4 -4 4 2 74.96 1.47 1.2670 -2 -4 5 2 75.00 1.49 1.2664 -6 0 2 2 75.01 1.26 1.2662 -6 1 1 2 75.06 2.41 1.2655 2 -6 1 2 75.12 1.84 1.2646 -6 -2 2 2 75.80 1.35 1.2550 2 0 5 2 76.08 1.32 1.2510 6 0 1 2 77.14 1.17 1.2365 2 6 1 2 77.56 1.14 1.2308 -5 0 4 2 77.88 1.87 1.2266 4 -1 4 2 78.81 1.42 1.2145 -3 3 4 2 79.07 1.60 1.2110 2 1 5 2 79.52 1.51 1.2054 -1 -6 4 2 79.64 1.13 1.2038 3 -4 4 2 79.94 1.51 1.2001 1 5 3 2 80.13 1.70 1.1977 4 -4 3 2 80.87 1.09 1.1887 -4 -6 1 2 83.17 1.20 1.1615 -5 -5 3 2 83.26 1.03 1.1604 -6 2 2 2 83.65 2.33 1.1561 4 6 0 2 84.65 2.92 1.1449 -4 1 5 2 85.25 1.17 1.1384 -6 3 0 2 85.25 1.05 1.1383 2 7 0 2 86.09 2.50 1.1295 -3 -2 6 2 86.28 1.25 1.1275 3 -3 5 2 86.73 1.98 1.1227 -3 -7 1 2 86.82 1.25 1.1218 -6 -1 4 2 87.01 1.26 1.1198 -6 -4 3 2 87.90 1.61 1.1108 1 -3 6 2 87.99 1.95 1.1098 -7 -1 2 2 88.04 1.76 1.1094 0 7 1 2 88.58 1.08 1.1040 -3 4 4 2 88.70 1.11 1.1028 0 -4 6 2 89.06 1.25 1.0993 -5 0 5 2 89.35 1.12 1.0965 7 2 0 2 89.49 1.03 1.0951 -5 -6 2 2 89.52 1.62 1.0948 -2 1 6 2 89.61 1.16 1.0940 -7 1 1 2 ================================================================================ XPOW Copyright 1993 Bob Downs, Ranjini Swaminathan and Kurt Bartelmehs For reference, see Downs et al. (1993) American Mineralogist 78, 1104-1107.