data_global
_amcsd_formula_title 'Li3Na3P6O18(H2O)12'
loop_
_publ_author_name
'Averbuch-Pouchot M'
_journal_name_full 'Zeitschrift fur Anorganische und Allgemeine Chemie'
_journal_volume 574 
_journal_year 1989
_journal_page_first 225
_journal_page_last 234
_publ_section_title
;
 On the existence of two new mixed-alkali cyclohexaphosphates Li3Na3P6O18(H2O)12
 and Li3K3P6O18(H2O)
 _cod_database_code 1008848
;
_database_code_amcsd 0016714
_chemical_formula_sum 'Na Li P2 O10 H8'
_cell_length_a 10.474
_cell_length_b 10.474
_cell_length_c 41.67999
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 120
_cell_volume 3959.892
_exptl_crystal_density_diffrn      1.962
_symmetry_space_group_name_H-M 'R -3 c'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '2/3+x,1/3+y,1/3+z'
  '1/3+x,2/3+y,2/3+z'
  'x,x-y,1/2+z'
  '2/3+x,1/3+x-y,5/6+z'
  '1/3+x,2/3+x-y,1/6+z'
  'y,x,1/2-z'
  '2/3+y,1/3+x,5/6-z'
  '1/3+y,2/3+x,1/6-z'
  '-x+y,y,1/2+z'
  '2/3-x+y,1/3+y,5/6+z'
  '1/3-x+y,2/3+y,1/6+z'
  '-x,-x+y,1/2-z'
  '2/3-x,1/3-x+y,5/6-z'
  '1/3-x,2/3-x+y,1/6-z'
  '-y,-x,1/2+z'
  '2/3-y,1/3-x,5/6+z'
  '1/3-y,2/3-x,1/6+z'
  'x-y,-y,1/2-z'
  '2/3+x-y,1/3-y,5/6-z'
  '1/3+x-y,2/3-y,1/6-z'
  'y,-x+y,-z'
  '2/3+y,1/3-x+y,1/3-z'
  '1/3+y,2/3-x+y,2/3-z'
  '-x+y,-x,z'
  '2/3-x+y,1/3-x,1/3+z'
  '1/3-x+y,2/3-x,2/3+z'
  '-x,-y,-z'
  '2/3-x,1/3-y,1/3-z'
  '1/3-x,2/3-y,2/3-z'
  '-y,x-y,z'
  '2/3-y,1/3+x-y,1/3+z'
  '1/3-y,2/3+x-y,2/3+z'
  'x-y,x,-z'
  '2/3+x-y,1/3+x,1/3-z'
  '1/3+x-y,2/3+x,2/3-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
Na1   0.00000   0.00000   0.13218
Na2   0.00000   0.00000   0.25000
Li1   0.49790   0.00000   0.25000
P1   0.81310   0.10869   0.48666
O1   0.56400   0.62870   0.21224
O2   0.45170   0.12910   0.34690
O3   0.13300   0.21770   0.16463
O4   0.36350   0.85890   0.07523
O5   0.56240   0.12120   0.04933
H1   0.21800   0.73600   0.24200
H2   0.52100   0.58500   0.06730
H3   0.79900   0.27800   0.13200
H4   0.19300   0.95800   0.28920