Astrophyllite Piilonen P C, McDonald A M, Lalonde A E The Canadian Mineralogist 41 (2003) 27-54 Insights into astrophyllite-group minerals II: Crystal chemistry Sample: MSH33a Locality: aplite/pegmatite at Mont Saint-Hilaire, Quebec, Canada _database_code_amcsd 0005818 5.418 11.933 11.742 112.962 94.620 103.123 P-1 atom x y z occ Uiso U(1,1) U(2,2) U(3,3) U(1,2) U(1,3) U(2,3) Mn(1) .8500 .20625 .48069 1.001 .0121 .0081 .0127 .0168 .0035 .0034 .0070 Fe(2) .2807 .06813 .48939 .960 .0124 .0092 .0127 .0168 .0035 .0045 .0069 Fe(3) .4231 .35255 .48621 .954 .0127 .0101 .0123 .0179 .0045 .0051 .0073 Fe(4) 0 .5 .5 .438 .0104 .0077 .0088 .0142 .0019 .0017 .0045 Mg(4) 0 .5 .5 .062 .0104 .0077 .0088 .0142 .0019 .0017 .0045 Ti .0787 .08663 .19725 .462 .0110 .0064 .0113 .0168 .0029 .0033 .0069 Zr .0787 .08663 .19725 .538 .0110 .0064 .0113 .0168 .0029 .0033 .0069 Si(1) .6784 .2739 .2325 .0111 .0119 .0072 .0130 .0012 .0031 .0040 Si(2) .8140 .5474 .2543 .0127 .0118 .0119 .0153 .0034 .0020 .0068 Si(3) .3778 .6744 .2564 .0130 .0115 .0130 .0164 .0043 .0033 .0074 Si(4) .5059 .9305 .2363 .0117 .0109 .0107 .0129 .0017 .0026 .0051 K .1360 .2704 .9956 .87 .0585 .0867 .0512 .0301 .0130 .0069 .0137 Na .1360 .2704 .9956 .13 .0417 .0517 .0434 .0247 .0102 .0047 .0113 Na .5 0 0 .36 .0166 .0241 .0128 .0112 .0037 .0031 .0041 Ca .5 0 0 .14 .0166 .0241 .0128 .0112 .0037 .0031 .0041 O(1) .7260 .3186 .3842 .0130 .0104 .0149 .0121 .0039 .0026 .0038 O(2) .1467 .1626 .3756 .0151 .0065 .0185 .0199 .0044 .0025 .0072 O(3) .1275 .3918 .5926 .0135 .0083 .0145 .0144 .0018 .0037 .0033 OH(4) .2995 .4637 .4027 .0160 .0147 .0104 .0152 .0013 .0016 -.0011 OH(5) .9921 .1170 .5934 .0160 .0173 .0178 .0178 .0072 .0018 .0115 O(6) .5611 .2578 .5888 .0133 .0109 .0115 .0156 .0028 .0035 .0037 O(7) .5721 .0136 .3879 .0129 .0112 .0118 .0154 .0043 .0022 .0048 O(8) .0718 .5908 .2021 .0269 .0195 .0305 .0203 -.0036 .0049 .0055 O(9) .2513 .0419 .8271 .0447 .0288 .0503 .0199 -.0216 .0153 -.0053 O(10) .4292 .4142 .7977 .0274 .0310 .0339 .0177 .0179 .0025 .0067 O(11) .1318 .8058 .8311 .0461 .0776 .0680 .0235 .0644 .0242 .0238 O(12) .2672 .9570 .1727 .0463 .0584 .0450 .0227 .0387 -.0173 -.0073 O(13) .2656 .6056 .8045 .0314 .0575 .0140 .0203 .0013 .0072 .0095 O(14) .5728 .2208 .8008 .0347 .0581 .0213 .0229 .0061 .0070 .0104 O(15) .3863 .1933 .1680 .0431 .0329 .0503 .0244 -.0264 -.0062 .0166 F(16) 0 0 0 .50 .0190 .0172 .0219 .0193 .0076 .0030 .0089 H(1) .20 .407 .318 .0150 H(2) .868 .139 .546 .0150