data_global
_amcsd_formula_title 'K1.4 O50 P4 W14'
loop_
_publ_author_name
'Domenges B'
'Goreaud M'
'Labbe P'
'Raveau B'
_journal_name_full 'Journal of Solid State Chemistry'
_journal_volume 50 
_journal_year 1983
_journal_page_first 173
_journal_page_last 179
_publ_section_title
;
 K1.4 P4 W14 O50: An Odd-m Member (m=7) of the Monophosphate
 Tungsten Bronze Series Kx P4 O8 (W O3)2m
 _cod_database_code 1001252
;
_database_code_amcsd 0013514
_chemical_formula_sum 'K.7 P2 W7 O25'
_cell_length_a 6.660
_cell_length_b 5.3483
_cell_length_c 27.06
_cell_angle_alpha 90
_cell_angle_beta 97.20
_cell_angle_gamma 90
_cell_volume 956.268
_exptl_crystal_density_diffrn      6.169
_symmetry_space_group_name_H-M 'A 1 2/m 1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  'x,1/2+y,1/2+z'
  '-x,y,-z'
  '-x,1/2+y,1/2-z'
  'x,-y,z'
  'x,1/2-y,1/2+z'
  '-x,-y,-z'
  '-x,1/2-y,1/2-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
K1   0.36300   0.00000   0.24980   0.35000
P1   0.19700   0.50000   0.29280   1.00000
W1   0.00000   0.00000   0.00000   1.00000
W2   0.70062   0.50000   0.05464   1.00000
W3   0.40226   0.00000   0.11184   1.00000
W4   0.09390   0.50000   0.16777   1.00000
O1   0.50000   0.50000   0.00000   1.00000
O2   0.84600   0.24900   0.02780   1.00000
O3   0.19700   0.00000   0.06020   1.00000
O4   0.54600   0.25300   0.08850   1.00000
O5   0.90600   0.50000   0.11370   1.00000
O6   0.25000   0.25300   0.14880   1.00000
O7   0.59200   0.00000   0.17670   1.00000
O8   0.92000   0.23800   0.19770   1.00000
O9   0.23700   0.50000   0.23830   1.00000
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
W1 0.00390 0.00300 0.00500 0.00000 -0.00120 0.00000
W2 0.00380 0.00290 0.00430 0.00000 -0.00128 0.00000
W3 0.00360 0.00270 0.00370 0.00000 -0.00119 0.00000
W4 0.00410 0.00270 0.00320 0.00000 -0.00137 0.00000