data_global
_chemical_name_mineral 'Phlogopite'
loop_
_publ_author_name
'Redhammer G J'
'Roth G'
_journal_name_full 'American Mineralogist'
_journal_volume 87 
_journal_year 2002
_journal_page_first 1464
_journal_page_last 1476
_publ_section_title
;
 Single-crystal structure refinements and crystal chemistry of
 synthetic trioctahedral micas KM3(Al,Si)4O10(OH)2, where
 M = Ni, Mg, Co, Fe, Al
 Sample: Coni1.8#2 - Co
;
_database_code_amcsd 0002919
_chemical_formula_sum '(Al1.08 Si2.92) (Co1.68 Ni1.32) K O12 H2'
_cell_length_a 5.3225
_cell_length_b 9.2195
_cell_length_c 10.3125
_cell_angle_alpha 90
_cell_angle_beta 99.949
_cell_angle_gamma 90
_cell_volume 498.433
_exptl_crystal_density_diffrn      3.470
_symmetry_space_group_name_H-M 'C 1 2/m 1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2+y,z'
  'x,-y,z'
  '1/2+x,1/2-y,z'
  '-x,y,-z'
  '1/2-x,1/2+y,-z'
  '-x,-y,-z'
  '1/2-x,1/2-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
AlT   0.57637   0.16674   0.22848   0.27000   0.00811
SiT   0.57637   0.16674   0.22848   0.73000   0.00811
CoM1   0.00000   0.50000   0.50000   0.56000   0.00874
NiM1   0.00000   0.50000   0.50000   0.44000   0.00874
CoM2   0.00000   0.83190   0.50000   0.56000   0.00887
NiM2   0.00000   0.83190   0.50000   0.44000   0.00887
K   0.00000   0.00000   0.00000   1.00000   0.03318
O1   0.82794   0.22891   0.17079   1.00000   0.02128
O2   0.51410   0.00000   0.17080   1.00000   0.02140
O3   0.63136   0.16663   0.39129   1.00000   0.01039
O4   0.13362   0.00000   0.39809   1.00000   0.01102
H   0.11100   0.00000   0.28800   1.00000   0.02976
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
AlT 0.00730 0.00760 0.00940 -0.00010 0.00110 0.00010
SiT 0.00730 0.00760 0.00940 -0.00010 0.00110 0.00010
CoM1 0.00670 0.00600 0.01330 0.00000 0.00210 0.00000
NiM1 0.00670 0.00600 0.01330 0.00000 0.00210 0.00000
CoM2 0.00690 0.00630 0.01320 0.00000 0.00170 0.00000
NiM2 0.00690 0.00630 0.01320 0.00000 0.00170 0.00000
K 0.03590 0.03540 0.02800 0.00000 0.00450 0.00000
O1 0.01810 0.02790 0.01870 -0.00920 0.00530 -0.00410
O2 0.02820 0.01360 0.02060 0.00000 -0.00090 0.00000
O3 0.01340 0.01050 0.00740 -0.00040 0.00280 0.00010
O4 0.01260 0.01310 0.00770 0.00000 0.00220 0.00000