Armbrusterite Yakovenchuk V N, Krivovichev S K, Pakhomovsky Y A, Ivanyuk G Y, Selivanova E A, Menshikov Y P, Britvin S N American Mineralogist 92 (2007) 416-423 Armbrusterite, K5Na6Mn3+Mn2+14[Si9O22]4(OH)10*4H2O, a new Mn hydrous heterophyllosilicate from the Khibiny alkaline massif, Kola Peninsula, Russia Locality: Khibiny alkaline massif, Kola Peninsula, Russia _database_code_amcsd 0004282 17.333 23.539 13.4895 90 115.069 90 C2/m atom x y z occ Uiso U(1,1) U(2,2) U(3,3) U(1,2) U(1,3) U(2,3) K1 .210 .9513 .4905 .30 .090 K2 .505 0 .6035 .28 .072 K3 0 0 .5 .16 .042 K5 .9725 .6967 .495 .20 .1 K6 .815 .6705 .490 .17 .1 K7 .854 .7263 .479 .17 .1 K10 .824 .560 .477 .11 .1 K11 .398 .0665 .485 .12 .1 Na1 .8465 .14408 .0470 .0294 .0225 .0192 .047 -.0010 .0151 .001 Na2 .5 .8511 0 .031 .026 .026 .048 0 .024 0 Mn2+1 0 .06931 0 .0223 .0162 .0150 .0381 0 .0139 0 Mn2+2 0 .21062 0 .0219 .0153 .0170 .0355 0 .0127 0 Mn2+3 .32397 .07102 .96233 .0223 .0168 .0157 .0388 -.0003 .0160 -.0005 Mn2+4 .84790 0 .04652 .0229 .0155 .0178 .0380 0 .0141 0 Mn3+5 .5 0 0 .0214 .0137 .0181 .0351 0 .0129 0 Mn2+6 .67138 .78453 .01290 .0230 .0174 .0173 .0395 .0008 .0170 .0011 Si1 .28669 .06392 .1804 .0203 .0150 .0156 .0345 -.0001 .0144 .0009 Si2 .85334 .86802 .7929 .0205 .0135 .0166 .0342 .0018 .0128 -.0003 Si3 .39902 .06387 .7713 .0213 .0138 .0181 .0354 -.0004 .0139 .0000 Si4 .85790 .74466 .7667 .0222 .0148 .0186 .0346 -.0014 .0117 -.0010 Si5 .01462 .06473 .2525 .0206 .0167 .0133 .0363 .0009 .0156 .0000 Si6 .02831 .75457 .7661 .0221 .0165 .0180 .0359 -.0014 .0151 .0008 Si7 .25042 .85840 .7343 .0209 .0130 .0170 .0340 .0005 .0113 .0006 Si8 .05700 .14539 .6269 .0206 .0125 .0198 .0319 -.0001 .0117 -.0015 Si9 .43999 .13157 .2007 .0201 .0124 .0150 .0354 -.0013 .0124 -.0004 O3 .2454 .0672 .0507 .0234 .018 .016 .041 -.001 .016 -.001 O5 .4031 .1383 .0717 .0243 .016 .018 .038 .002 .011 -.003 O6 .2603 .8580 .8579 .0269 .022 .028 .032 -.003 .012 -.002 O7 .9042 .7291 .8946 .0250 .018 .027 .033 -.004 .014 -.003 O8 .9465 .0659 .1274 .0238 .022 .016 .037 -.006 .016 -.004 O9 .9156 .8623 .9180 .0231 .016 .018 .037 -.001 .014 .001 O10 .4251 .0613 .8999 .0242 .016 .022 .039 .002 .017 -.001 O11 .0479 0 .2970 .0255 .025 .014 .044 0 .021 0 O12 .9007 .8973 .7236 .0271 .026 .020 .040 -.004 .019 -.003 O13 .8129 .8070 .7384 .0237 .019 .012 .038 -.004 .009 .000 O14 .4644 .1037 .7424 .0244 .023 .017 .035 -.003 .014 .001 O15 .0671 .7719 .8922 .0259 .019 .028 .032 .002 .012 -.002 O16 .0597 .6928 .7419 .0236 .022 .021 .033 .002 .017 .003 O17 .3033 .9103 .7082 .0245 .015 .021 .041 -.002 .015 -.001 O18 0 .1576 .5 .032 .022 .040 .035 0 .013 0 O19 .7830 .7004 .6985 .0252 .018 .017 .039 -.004 .011 .002 O20 .2999 0 .2285 .027 .031 .013 .039 0 .017 0 O21 .1529 .1329 .6433 .0274 .016 .030 .042 -.001 .017 -.005 O22 .0547 .1999 .6958 .0315 .030 .025 .044 .002 .021 -.005 O23 .3814 .0906 .2391 .0290 .018 .033 .035 -.010 .010 .000 O24 .3989 0 .7223 .0238 .023 .019 .037 0 .020 0 O26 .9254 .7478 .7106 .0284 .014 .038 .033 -.004 .010 -.002 O27 .7697 .9067 .7654 .0293 .022 .030 .035 .012 .012 .001 O28 .9767 .0893 .3356 .0284 .023 .022 .051 -.004 .027 -.001 OH1 .2409 0 .8736 .0265 .023 .022 .040 0 .018 0 OH2 .4119 0 .0649 .029 .021 .023 .049 0 .019 0 OH4 .0899 0 .0692 .027 .024 .022 .038 0 .016 0 OH25 .7508 .7120 .0734 .0270 .018 .024 .042 .002 .016 .003 Wat1 0 .652 .5 .35 .1 Wat2 0 .586 .5 .34 .1 Wat3 .878 .683 .434 .26 .1 Wat4 .824 .613 .478 .29 .1 Wat5 .243 0 .413 .26 .1 Wat6 .218 0 .509 .26 .1 Wat7 .8609 0 .3821 .70 .1