data_global _chemical_name_mineral 'Polylithionite' loop_ _publ_author_name 'Brigatti M F' 'Mottana A' 'Malferrari D' 'Cibin G' _journal_name_full 'American Mineralogist' _journal_volume 92 _journal_year 2007 _journal_page_first 1395 _journal_page_last 1400 _publ_section_title ; Crystal structure and chemical composition of Li-, Fe-, and Mn-rich micas Sample: Mokrusha ; _database_code_amcsd 0004417 _chemical_compound_source 'Mokrusha mine, Yuzhakova village, Murzinka region, Russia' _chemical_formula_sum 'Si3.32 Al1.68 Li1.32 Fe.36 Mn.16 Mg.16 K.94 Na.04 Ca.01 O10.1 (F1.9 H.1)' _cell_length_a 5.297 _cell_length_b 9.133 _cell_length_c 10.168 _cell_angle_alpha 90 _cell_angle_beta 100.78 _cell_angle_gamma 90 _cell_volume 483.222 _exptl_crystal_density_diffrn 2.862 _symmetry_space_group_name_H-M 'C 1 2 1' loop_ _space_group_symop_operation_xyz 'x,y,z' '1/2+x,1/2+y,z' '-x,y,-z' '1/2-x,1/2+y,-z' loop_ _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_occupancy _atom_site_U_iso_or_equiv SiT1 0.07540 0.16930 0.22960 0.83000 0.01300 AlT1 0.07540 0.16930 0.22960 0.17000 0.01300 SiT11 0.58590 0.33320 0.22910 0.83000 0.01100 AlT11 0.58590 0.33320 0.22910 0.17000 0.01100 LiM1 0.00000 0.99200 0.50000 0.66000 0.01500 FeM1 0.00000 0.99200 0.50000 0.17000 0.01500 MnM1 0.00000 0.99200 0.50000 0.16000 0.01500 MgM1 0.00000 0.99200 0.50000 0.01000 0.01500 AlM2 0.00000 0.32260 0.50000 1.00000 0.01400 LiM3 0.50000 0.16200 0.50000 0.66000 0.00900 FeM3 0.50000 0.16200 0.50000 0.19000 0.00900 MgM3 0.50000 0.16200 0.50000 0.15000 0.00900 KA 0.00000 0.50100 0.00000 0.94000 0.02900 NaA 0.00000 0.50100 0.00000 0.04000 0.02900 CaA 0.00000 0.50100 0.00000 0.01000 0.02900 O1 0.03010 1.00260 0.17170 1.00000 0.02300 O2 0.32060 0.23700 0.16970 1.00000 0.02700 O22 0.81970 0.26350 0.16330 1.00000 0.02100 O3 0.12030 0.17700 0.39370 1.00000 0.01700 O33 0.66020 0.32880 0.39310 1.00000 0.02100 O-H4 0.11160 0.47490 0.40010 0.05000 0.01900 F4 0.11160 0.47490 0.40010 0.95000 0.01900 loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_12 _atom_site_aniso_U_13 _atom_site_aniso_U_23 SiT1 0.00900 0.01000 0.02300 0.00400 0.00600 0.00100 AlT1 0.00900 0.01000 0.02300 0.00400 0.00600 0.00100 SiT11 0.01300 0.00800 0.01100 0.00300 0.00000 0.00200 AlT11 0.01300 0.00800 0.01100 0.00300 0.00000 0.00200 LiM1 0.01100 0.01000 0.02500 0.00000 0.00500 0.00000 FeM1 0.01100 0.01000 0.02500 0.00000 0.00500 0.00000 MnM1 0.01100 0.01000 0.02500 0.00000 0.00500 0.00000 MgM1 0.01100 0.01000 0.02500 0.00000 0.00500 0.00000 AlM2 0.00500 0.00900 0.02800 0.00000 0.00600 0.00000 LiM3 0.00800 0.00800 0.00800 0.00000 -0.00300 0.00000 FeM3 0.00800 0.00800 0.00800 0.00000 -0.00300 0.00000 MgM3 0.00800 0.00800 0.00800 0.00000 -0.00300 0.00000 KA 0.02800 0.02300 0.03500 0.00000 0.00300 0.00000 NaA 0.02800 0.02300 0.03500 0.00000 0.00300 0.00000 CaA 0.02800 0.02300 0.03500 0.00000 0.00300 0.00000 O1 0.02300 0.01800 0.02500 0.00500 0.00000 -0.01100 O2 0.02000 0.03700 0.02300 -0.00600 0.00500 -0.00800 O22 0.01900 0.02300 0.02300 0.00700 0.01000 -0.00300 O3 0.01800 0.02100 0.01000 0.00900 -0.00100 -0.00200 O33 0.02700 0.00800 0.02800 0.01000 0.00400 0.00200 O-H4 0.01900 0.01700 0.02100 -0.00500 0.00200 -0.00100 F4 0.01900 0.01700 0.02100 -0.00500 0.00200 -0.00100