data_global _chemical_name_mineral 'Ambrinoite' loop_ _publ_author_name 'Biagioni C' 'Bonaccorsi E' 'Pasero M' 'Moelo Y' 'Ciriotti M E' 'Bersani D' 'Callegari A M' 'Boiocchi M' _journal_name_full 'American Mineralogist' _journal_volume 96 _journal_year 2011 _journal_page_first 878 _journal_page_last 887 _publ_section_title ; Ambrinoite, (K,NH4)2(As,Sb)8S13*H2O, a new mineral from Upper Susa Valley, Piedmont, Italy: The first natural (K,NH4)-hydrated sulfosalt ; _database_code_amcsd 0019096 _chemical_compound_source 'Upper Susa Valley, Piedmont, Italy' _chemical_formula_sum 'K1.61 N.39 H3.56 Sb1.64 As6.36 S13 O' _cell_length_a 9.704 _cell_length_b 11.579 _cell_length_c 12.102 _cell_angle_alpha 112.82 _cell_angle_beta 103.44 _cell_angle_gamma 90.49 _cell_volume 1211.642 _exptl_crystal_density_diffrn 3.237 _symmetry_space_group_name_H-M 'P -1' loop_ _space_group_symop_operation_xyz 'x,y,z' '-x,-y,-z' loop_ _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_occupancy _atom_site_U_iso_or_equiv K1 0.66800 0.33310 0.67910 0.83000 0.06500 N1 0.66800 0.33310 0.67910 0.17000 0.06500 H1 0.66800 0.33310 0.67910 0.68000 0.06500 K2 0.92420 0.75920 0.47740 0.78000 0.07300 N2 0.92420 0.75920 0.47740 0.22000 0.07300 H2 0.92420 0.75920 0.47740 0.88000 0.07300 SbM1 0.39230 0.64339 0.83575 0.54000 0.03440 AsM1 0.39230 0.64339 0.83575 0.46000 0.03440 SbM2 0.01055 0.14677 0.83795 0.57000 0.03690 AsM2 0.01055 0.14677 0.83795 0.43000 0.03690 AsM3 0.66142 0.98014 0.71276 1.00000 0.03090 AsM4 0.66440 0.70477 0.70910 1.00000 0.03020 AsM5 0.24245 0.92642 0.96400 0.92000 0.03540 SbM5 0.24245 0.92642 0.96400 0.08000 0.03540 AsM6 0.00896 0.64686 0.82178 0.80000 0.03580 SbM6 0.00896 0.64686 0.82178 0.20000 0.03580 AsM7 0.38933 0.14671 0.82502 0.75000 0.03620 SbM7 0.38933 0.14671 0.82502 0.25000 0.03620 AsM8 0.23678 0.42874 0.94031 1.00000 0.03650 S1 0.61610 0.78140 0.55760 1.00000 0.03230 S2 0.37860 0.34010 0.80690 1.00000 0.04040 S3 0.82040 0.05990 0.64370 1.00000 0.03210 S4 0.39740 0.85100 0.83820 1.00000 0.03710 S5 0.47230 0.56200 0.64320 1.00000 0.03140 S6 0.01140 0.34390 0.81690 1.00000 0.03670 S7 0.82200 0.57190 0.63620 1.00000 0.03230 S8 0.46940 0.06300 0.64080 1.00000 0.03480 S9 0.16110 0.05730 0.69910 1.00000 0.03680 S10 0.15870 0.56250 0.69310 1.00000 0.03450 S11 0.01920 0.84850 0.82580 1.00000 0.03920 S12 0.26370 0.29920 0.03500 1.00000 0.03980 S13 0.25780 0.77630 0.03810 1.00000 0.03480 Wat 0.21720 0.74960 0.52860 1.00000 0.06600 loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_12 _atom_site_aniso_U_13 _atom_site_aniso_U_23 K1 0.04800 0.05800 0.09500 0.00300 0.00700 0.04400 N1 0.04800 0.05800 0.09500 0.00300 0.00700 0.04400 H1 0.04800 0.05800 0.09500 0.00300 0.00700 0.04400 K2 0.08800 0.06100 0.07500 0.00700 0.04400 0.02000 N2 0.08800 0.06100 0.07500 0.00700 0.04400 0.02000 H2 0.08800 0.06100 0.07500 0.00700 0.04400 0.02000 SbM1 0.03610 0.02780 0.04250 0.00300 0.01540 0.01420 AsM1 0.03610 0.02780 0.04250 0.00300 0.01540 0.01420 SbM2 0.03410 0.02980 0.05000 0.00230 0.01090 0.01920 AsM2 0.03410 0.02980 0.05000 0.00230 0.01090 0.01920 AsM3 0.03740 0.02800 0.02940 0.00250 0.00710 0.01430 AsM4 0.03690 0.02690 0.02800 0.00120 0.00620 0.01350 AsM5 0.03960 0.02920 0.03500 0.00180 0.00880 0.01080 SbM5 0.03960 0.02920 0.03500 0.00180 0.00880 0.01080 AsM6 0.03270 0.02850 0.04510 0.00240 0.00870 0.01430 SbM6 0.03270 0.02850 0.04510 0.00240 0.00870 0.01430 AsM7 0.03570 0.03020 0.04760 0.00600 0.01530 0.01800 SbM7 0.03570 0.03020 0.04760 0.00600 0.01530 0.01800 AsM8 0.04090 0.02820 0.03770 0.00140 0.00910 0.01100 S1 0.04400 0.02700 0.02700 0.00100 0.00500 0.01400 S2 0.04700 0.03300 0.05400 0.00600 0.02300 0.02400 S3 0.03100 0.03500 0.03100 -0.00200 0.00600 0.01500 S4 0.04400 0.03100 0.04500 0.00400 0.01700 0.02100 S5 0.03700 0.02900 0.02800 -0.00200 0.01000 0.01000 S6 0.03600 0.03200 0.04500 0.00400 0.00500 0.02100 S7 0.03300 0.02900 0.03100 0.00400 0.00500 0.01000 S8 0.03800 0.04100 0.03000 0.01100 0.01000 0.01800 S9 0.03500 0.03000 0.04000 0.00200 0.01200 0.01000 S10 0.03300 0.03200 0.03500 0.00100 0.00900 0.00800 S11 0.03900 0.03000 0.04900 0.00300 0.00100 0.02100 S12 0.04000 0.05300 0.03100 0.00500 0.00700 0.02300 S13 0.04200 0.03300 0.03000 0.00400 0.00900 0.01400 Wat 0.08700 0.04600 0.05000 0.00800 -0.00400 0.01400