data_global
_chemical_name_mineral 'Galkhaite'
loop_
_publ_author_name
'Chen T T'
'Szymanski J T'
_journal_name_full 'The Canadian Mineralogist'
_journal_volume 19 
_journal_year 1981
_journal_page_first 571
_journal_page_last 581
_publ_section_title
;
 The structure and chemistry of galkhaite, a mercury sulfosalt containing
 Cs and Tl
;
_database_code_amcsd 0005182
_chemical_compound_source 'Getchell mine, Humboldt County, Nevada, USA'
_chemical_formula_sum 'Hg4.224 Cu.864 Zn.528 Tl.304 Fe.03 Cs.595 (As3.932 Sb.068) S12'
_cell_length_a 10.365
_cell_length_b 10.365
_cell_length_c 10.365
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 90
_cell_volume 1113.545
_exptl_crystal_density_diffrn      5.271
_symmetry_space_group_name_H-M 'I -4 3 m'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2+y,1/2+z'
  '-z,x,-y'
  '1/2-z,1/2+x,1/2-y'
  '-y,z,-x'
  '1/2-y,1/2+z,1/2-x'
  '-x,y,-z'
  '1/2-x,1/2+y,1/2-z'
  'x,-z,-y'
  '1/2+x,1/2-z,1/2-y'
  'z,-y,-x'
  '1/2+z,1/2-y,1/2-x'
  'y,-x,-z'
  '1/2+y,1/2-x,1/2-z'
  'x,z,y'
  '1/2+x,1/2+z,1/2+y'
  'z,y,x'
  '1/2+z,1/2+y,1/2+x'
  'y,x,z'
  '1/2+y,1/2+x,1/2+z'
  '-z,-x,y'
  '1/2-z,1/2-x,1/2+y'
  '-y,-z,x'
  '1/2-y,1/2-z,1/2+x'
  '-x,-y,z'
  '1/2-x,1/2-y,1/2+z'
  'z,-x,-y'
  '1/2+z,1/2-x,1/2-y'
  'y,-z,-x'
  '1/2+y,1/2-z,1/2-x'
  'x,-y,-z'
  '1/2+x,1/2-y,1/2-z'
  '-x,z,-y'
  '1/2-x,1/2+z,1/2-y'
  '-z,y,-x'
  '1/2-z,1/2+y,1/2-x'
  '-y,x,-z'
  '1/2-y,1/2+x,1/2-z'
  '-x,-z,y'
  '1/2-x,1/2-z,1/2+y'
  '-z,-y,x'
  '1/2-z,1/2-y,1/2+x'
  '-y,-x,z'
  '1/2-y,1/2-x,1/2+z'
  'z,x,y'
  '1/2+z,1/2+x,1/2+y'
  'y,z,x'
  '1/2+y,1/2+z,1/2+x'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
Hg   0.25000   0.50000   0.00000   0.70400
Cu   0.25000   0.50000   0.00000   0.14400
Zn   0.25000   0.50000   0.00000   0.08800
Tl   0.25000   0.50000   0.00000   0.01400
Fe   0.25000   0.50000   0.00000   0.00500
Cs   0.00000   0.00000   0.00000   0.59500
Tl   0.00000   0.00000   0.00000   0.22000
As   0.24530   0.24530   0.24530   0.98300
Sb   0.24530   0.24530   0.24530   0.01700
S   0.38830   0.38830   0.16250   1.00000
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
Hg 0.06010 0.02290 0.02290 0.00000 0.00000 0.00000
Cu 0.06010 0.02290 0.02290 0.00000 0.00000 0.00000
Zn 0.06010 0.02290 0.02290 0.00000 0.00000 0.00000
Tl 0.06010 0.02290 0.02290 0.00000 0.00000 0.00000
Fe 0.06010 0.02290 0.02290 0.00000 0.00000 0.00000
Cs 0.04820 0.04820 0.04820 0.00000 0.00000 0.00000
Tl 0.04820 0.04820 0.04820 0.00000 0.00000 0.00000
As 0.01950 0.01950 0.01950 -0.00260 -0.00260 -0.00260
Sb 0.01950 0.01950 0.01950 -0.00260 -0.00260 -0.00260
S 0.02870 0.02870 0.02320 -0.01000 0.00110 0.00110