data_global
_chemical_name_mineral 'Phlogopite'
loop_
_publ_author_name
'Brigatti M F'
'Medici L'
'Poppi L'
'Vaccaro C'
_journal_name_full 'The Canadian Mineralogist'
_journal_volume 39 
_journal_year 2001
_journal_page_first 1333
_journal_page_last 1345
_publ_section_title
;
 Crystal chemistry of trioctahedral micas - 1M from the Alto Paranaiba
 Igneous Province, Southeastern Brazil
 Sample: Tpp16-6a
;
_database_code_amcsd 0005744
_chemical_compound_source 'Alto Paranaiba Igneous Province, Southeastern Brazil'
_chemical_formula_sum 'O11.88 (F.12 Si2.8) Al1.04 Fe.37 Mg2.73 Ti.06 Na.01 K.98 H1.88'
_cell_length_a 5.330
_cell_length_b 9.239
_cell_length_c 10.305
_cell_angle_alpha 90
_cell_angle_beta 99.89
_cell_angle_gamma 90
_cell_volume 499.917
_exptl_crystal_density_diffrn      2.853
_symmetry_space_group_name_H-M 'C 1 2/m 1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2+y,z'
  'x,-y,z'
  '1/2+x,1/2-y,z'
  '-x,y,-z'
  '1/2-x,1/2+y,-z'
  '-x,-y,-z'
  '1/2-x,1/2-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
O1   0.01430   0.00000   0.16980   1.00000   0.01963
O2   0.32800   0.22770   0.17060   1.00000   0.01912
O3   0.12990   0.16740   0.39100   1.00000   0.00798
O-H4   0.13300   0.50000   0.39760   0.94000   0.00697
F4   0.13300   0.50000   0.39760   0.06000   0.00697
SiT   0.07600   0.16674   0.22814   0.70000   0.00684
AlT   0.07600   0.16674   0.22814   0.26000   0.00684
FeT   0.07600   0.16674   0.22814   0.04000   0.00684
MgM1   0.00000   0.00000   0.50000   0.91000   0.00684
FeM1   0.00000   0.00000   0.50000   0.07000   0.00684
TiM1   0.00000   0.00000   0.50000   0.02000   0.00684
MgM2   0.00000   0.33220   0.50000   0.91000   0.00659
FeM2   0.00000   0.33220   0.50000   0.07000   0.00659
TiM2   0.00000   0.33220   0.50000   0.02000   0.00659
NaA   0.00000   0.50000   0.00000   0.01000   0.03002
KA   0.00000   0.50000   0.00000   0.98000   0.03002
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
O1 0.02235 0.01989 0.01619 0.00000 0.00243 0.00000
O2 0.01732 0.02465 0.01566 -0.00197 0.00378 -0.00238
O3 0.00419 0.00649 0.01410 0.00074 0.00297 -0.00048
O-H4 0.00517 0.00432 0.01149 0.00000 0.00108 0.00000
F4 0.00517 0.00432 0.01149 0.00000 0.00108 0.00000
SiT 0.00447 0.00605 0.01044 0.00049 0.00135 0.00000
AlT 0.00447 0.00605 0.01044 0.00049 0.00135 0.00000
FeT 0.00447 0.00605 0.01044 0.00049 0.00135 0.00000
MgM1 0.00405 0.00389 0.01305 0.00000 0.00270 0.00000
FeM1 0.00405 0.00389 0.01305 0.00000 0.00270 0.00000
TiM1 0.00405 0.00389 0.01305 0.00000 0.00270 0.00000
MgM2 0.00405 0.00432 0.01149 0.00000 0.00108 0.00000
FeM2 0.00405 0.00432 0.01149 0.00000 0.00108 0.00000
TiM2 0.00405 0.00432 0.01149 0.00000 0.00108 0.00000
NaA 0.03408 0.03287 0.02245 0.00000 0.00378 0.00000
KA 0.03408 0.03287 0.02245 0.00000 0.00378 0.00000