data_global
_chemical_name_mineral 'Phlogopite'
loop_
_publ_author_name
'Brigatti M F'
'Medici L'
'Poppi L'
'Vaccaro C'
_journal_name_full 'The Canadian Mineralogist'
_journal_volume 39 
_journal_year 2001
_journal_page_first 1333
_journal_page_last 1345
_publ_section_title
;
 Crystal chemistry of trioctahedral micas - 1M from the Alto Paranaiba
 Igneous Province, Southeastern Brazil
 Sample: Tpp16-6b, ferroan tetra-ferriphlogopite
;
_database_code_amcsd 0005750
_chemical_compound_source 'Alto Paranaiba Igneous Province, Southeastern Brazil'
_chemical_formula_sum 'O11.98 F.02 Si3.04 Al.08 Fe1.51 Mg2.37 K H1.9'
_cell_length_a 5.360
_cell_length_b 9.293
_cell_length_c 10.314
_cell_angle_alpha 90
_cell_angle_beta 100.01
_cell_angle_gamma 90
_cell_volume 505.925
_exptl_crystal_density_diffrn      3.036
_symmetry_space_group_name_H-M 'C 1 2/m 1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2+y,z'
  'x,-y,z'
  '1/2+x,1/2-y,z'
  '-x,y,-z'
  '1/2-x,1/2+y,-z'
  '-x,-y,-z'
  '1/2-x,1/2-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
O1   0.00300   0.00000   0.17010   1.00000   0.02470
O2   0.33360   0.22340   0.17020   1.00000   0.02609
O3   0.13040   0.16680   0.39090   1.00000   0.00811
O-H4   0.13270   0.50000   0.39780   0.95000   0.00760
F4   0.13270   0.50000   0.39780   0.01000   0.00760
O4   0.13270   0.50000   0.39780   0.04000   0.00760
SiT   0.07580   0.16661   0.22669   0.76000   0.00950
AlT   0.07580   0.16661   0.22669   0.02000   0.00950
FeT   0.07580   0.16661   0.22669   0.22000   0.00950
MgM1   0.00000   0.00000   0.50000   0.79000   0.00836
FeM1   0.00000   0.00000   0.50000   0.21000   0.00836
MgM2   0.00000   0.33270   0.50000   0.79000   0.00823
FeM2   0.00000   0.33270   0.50000   0.21000   0.00823
KA   0.00000   0.50000   0.00000   1.00000   0.02812
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
O1 0.02964 0.02538 0.01672 0.00000 -0.00299 0.00000
O2 0.02851 0.03194 0.01777 -0.00348 0.00625 -0.00526
O3 0.00734 0.00569 0.01150 0.00025 0.00163 0.00000
O-H4 0.00678 0.00700 0.00888 0.00000 0.00109 0.00000
F4 0.00678 0.00700 0.00888 0.00000 0.00109 0.00000
O4 0.00678 0.00700 0.00888 0.00000 0.00109 0.00000
SiT 0.00833 0.00831 0.01202 0.00000 0.00190 0.00000
AlT 0.00833 0.00831 0.01202 0.00000 0.00190 0.00000
FeT 0.00833 0.00831 0.01202 0.00000 0.00190 0.00000
MgM1 0.00649 0.00613 0.01254 0.00000 0.00190 0.00000
FeM1 0.00649 0.00613 0.01254 0.00000 0.00190 0.00000
MgM2 0.00635 0.00569 0.01254 0.00000 0.00217 0.00000
FeM2 0.00635 0.00569 0.01254 0.00000 0.00217 0.00000
KA 0.03261 0.03063 0.02091 0.00000 0.00435 0.00000