data_global
_chemical_name_mineral 'Magnesiozippeite'
loop_
_publ_author_name
'Burns P C'
'Deely K M'
'Hayden L A'
_journal_name_full 'The Canadian Mineralogist'
_journal_volume 41 
_journal_year 2003
_journal_page_first 687
_journal_page_last 706
_publ_section_title
;
 The crystal chemistry of the zippeite group
 Sample: Magnesium-zippeite
;
_database_code_amcsd 0005851
_chemical_formula_sum 'U4 S2 Mg2 O27 H14'
_cell_length_a 8.6514
_cell_length_b 14.1939
_cell_length_c 17.7211
_cell_angle_alpha 90
_cell_angle_beta 104.131
_cell_angle_gamma 90
_cell_volume 2110.251
_exptl_crystal_density_diffrn      4.756
_symmetry_space_group_name_H-M 'C 1 2/m 1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2+y,z'
  'x,-y,z'
  '1/2+x,1/2-y,z'
  '-x,y,-z'
  '1/2-x,1/2+y,-z'
  '-x,-y,-z'
  '1/2-x,1/2-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
U(1)   0.66710   0.23240   0.33490   0.00900
U(2)   0.33290   0.26740   0.16510   0.01000
S(1)   0.00000   0.26000   0.00000   0.00600
S(2)   0.00000   0.25520   0.50000   0.01100
Mg(1)   0.68980   0.50000   0.37830   0.02700
Mg(2)   0.30700   0.00000   0.12900   0.01900
O(1)   0.87910   0.18830   0.45090   0.02000
O(2)  -0.11980   0.31680  -0.05050   0.01400
O(3)   0.39600   0.23990   0.29440   0.00700
O(4)  -0.07570   0.19600   0.04750   0.01500
O(5)   0.93390   0.31300   0.55150   0.01600
O(6)   0.60100   0.24230   0.20520   0.01100
O(7)   0.65580   0.10830   0.31860   0.01700
O(8)   0.34200   0.39360   0.18130   0.02000
O(9)   0.31560   0.14380   0.13690   0.02100
O(10)   0.68550   0.35680   0.36330   0.01600
Wat(11)   0.70230   0.50000   0.48840   0.02800
Wat(12)   0.34600   0.00000   0.01030   0.04600
Wat(13)   0.55220   0.00000   0.15640   0.03400
Wat(14)   0.46020   0.50000   0.32100   0.03100
Wat(15)   0.93200   0.50000   0.38730   0.02900
Wat(16)   0.17130   0.00000   0.23840   0.04600
Wat(17)   0.06610   0.00000   0.07490   0.03300